Method for activation of chromium containing catalyst precursor for polymerization and the resulting polymerization catalyst

• US 10,253,113 B2
• Filed: 11/29/2011
• Issued: 04/09/2019
• Est. Priority Date: 11/30/2010
• Status: Active Grant

• Current Assignee: Basell Polyolefine GmbH (Lyondellbasell Industries NV)
• Original Assignee: Basell Polyolefine GmbH (Lyondellbasell Industries NV)
• Inventors: De Lange, Paulus, Hecker, Manfred
• Primary Examiner(s): Lee, Rip A
• Application Number:
  US13/990,618
• Publication Number:
  US 20130245209A1
• Time in Patent Office: 2,688 Days
• Field of Search: 422139, 422146
• CPC Class Codes: B01J 2208/00212 Plates; Jackets; Cylinders
• CPC Class Codes: B01J 23/26 Chromium
• CPC Class Codes: B01J 38/32 Indirectly heating or cooling material within regeneration zone or prior to entry into regeneration zone
• CPC Class Codes: B01J 8/1836 Heating and cooling the reactor B01J8/42 takes precedence
• CPC Class Codes: B01J 8/22 gas being introduced into the liquid
• CPC Class Codes: C08F 10/00 Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
• CPC Class Codes: C08F 4/24 Oxides
• CPC Class Codes: Y02P 20/584 Recycling of catalysts

Abstract

Method for activation of chromium containing catalyst precursor for polymerization and improved polymerization catalyst resulting The instant invention relates to an activation of a polymerization catalyst precursor by heat treatment comprising a support material and a catalyst precursor deposited thereon in a fluidized bed activator and to the use of the activated polymerization catalyst in the manufacture of polyolefins. The Method is performed in a cylindrical activator (1) arranged vertically comprising tubular activator walls, a fluidization gas inlet (2) near the bottom, a fluidization gas outlet (3) near the top and a heat exchange jacket (4) outside the tubular activator walls, wherein the heating jacket covers the complete outer surface of the walls of the activator. The catalyst prepared by that method is improved with respect to its minor content of impurities and causes less interruptions during gas-phase polymerization or slurry polymerization either in stirred vessel or loop.

Claims

1. A method for preparing a Cr-containing polymerization catalyst comprising:

heat-treating a reaction mixture, wherein the reaction mixture comprises a chromium containing catalyst precursor and residual liquid in a fluidized bed, wherein the chromium catalyst precursor comprises a support material, wherein the heat-treating step is performed in an activator in the presence of oxygen at a temperature in the range of from 300 to 1000°

C. over a time period of from 0.5 to 48 hours, wherein the activator has an inner activator chamber surrounded by generally-vertically shaped metallic walls having an inner surface and an outer surface, a fluidization gas inlet near the bottom portion of the activator, and a fluidization gas outlet near the top portion of the activator, the outer surface of the metallic walls are completely covered by a heating jacket, and the heating jacket has a heating medium inlet and a heating medium outlet, and

feeding a heating medium to the heating medium inlet of the heating jacket, wherein the heating medium inlet is near the top portion of the activator, and recovering the heating medium from the heating medium outlet of the heating jacket, wherein the heating medium outlet is near the bottom portion of the activator.

2. The method of claim 1, wherein the heating jacket is a double heating jacket.

3. The method of claim 1, wherein the resulting Cr-containing polymerization catalyst does not comprise Cr₂O₃.

4. The method of claim 3, wherein the Cr-containing polymerization catalyst is used in a gas-phase polymerization or a slurry polymerization in a stirred vessel or loop reactor.

5. The method of claim 4, further comprising a step of polymerizing olefins in a gas-phase or a slurry polymerization process.

6. The method of claim 5, wherein the olefins are selected from the group consisting of ethylene, propylene, butene, pentene, hexene and mixtures thereof.

7. The method of claim 1, wherein fluidization gas is fed to the fluidization gas inlet in a gaseous state, the fluidization gas flows up to the fluidization gas outlet, and the fluidization gas remains in the gaseous state while in the activator.

8. The method of claim 7, wherein the activator is free of residual liquid.

9. The method of claim 7, wherein the fluidization gas is air.

10. The method of claim 7, wherein the resulting Cr-containing polymerization catalyst does not comprise Cr₂O₃.

11. The method of claim 9, wherein air is used to oxidize Cr(III) to Cr(VI).