Heat transfer compositions

• US 10,266,736 B2
• Filed: 09/11/2015
• Issued: 04/23/2019
• Est. Priority Date: 06/25/2010
• Status: Active Grant

• Current Assignee: Mexichem, S.A.B. De C.V. (Orbia Advance Corporation, S.A.B. de C.V.)
• Original Assignee: Mexichem, S.A.B. De C.V. (Orbia Advance Corporation, S.A.B. de C.V.)
• Inventors: Low, Robert E.
• Primary Examiner(s): Hardee, John R
• Application Number:
  US14/851,030
• Publication Number:
  US 20160002519A1
• Time in Patent Office: 1,320 Days
• CPC Class Codes: B01D 11/0288 Applications, solvents
• CPC Class Codes: B01D 11/0492 Applications, solvents used
• CPC Class Codes: C08J 2203/14 Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
• CPC Class Codes: C08J 2203/142 Halogenated saturated hydrocarbons, e.g. H3C-CF3
• CPC Class Codes: C08J 2203/16 Unsaturated hydrocarbons
• CPC Class Codes: C08J 2203/162 Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
• CPC Class Codes: C08J 2203/202 of physical blowing agents
• CPC Class Codes: C08J 2325/06 Polystyrene
• CPC Class Codes: C08J 2363/00 Characterised by the use of epoxy resins; Derivatives of epoxy resins
• CPC Class Codes: C08J 2375/04 Polyurethanes
• CPC Class Codes: C08J 9/146 only fluorine as halogen atoms
• CPC Class Codes: C08J 9/149 Mixtures of blowing agents covered by more than one of the groups C08J9/141 - C08J9/143
• CPC Class Codes: C09K 2205/12 Hydrocarbons
• CPC Class Codes: C09K 2205/122 Halogenated hydrocarbons
• CPC Class Codes: C09K 2205/126 Unsaturated fluorinated hydrocarbons
• CPC Class Codes: C09K 2205/22 All components of a mixture being fluoro compounds
• CPC Class Codes: C09K 3/30 for aerosols aerosol containers B65D83/14
• CPC Class Codes: C09K 5/045 containing only fluorine as halogen
• CPC Class Codes: C11D 7/5018 Halogenated solvents
• CPC Class Codes: F03C 99/00 Subject matter not provided for in other groups of this subclass
• CPC Class Codes: G06Q 30/018 : Certifying business or products
• CPC Class Codes: Y02A 40/963 : Off-grid food refrigeration
• CPC Class Codes: Y10T 29/49716 : Converting

Abstract

The invention provides a heat transfer composition comprising:

• • (i) trans-1,3,3,3-tetrafluoropropene (R-1234ze(E));
  • (ii) a second component selected from difluoromethane (R-32), propene (R-1270) propane (R290) and mixtures thereof;
  • (iii) a third component selected from pentafluoroethane (R-125), 1,1,1,2-tetrafluoroethane (R-134a), and mixtures thereof; and optionally
  • (iv) a fourth component selected from fluoroethane (R-161), 1,1-difluoroethane (R-152a) and mixtures thereof.

Claims

1. A heat transfer composition comprising:

from about 5% to about 40% by weight of R-1234ze(E);

from about 20% to about 35% by weight R-32;

from about 15% to about 30% by weight R-125; and

from about 12% to about 50% by weight R-134a,

wherein the composition has a volumetric refrigeration capacity within about 10% of R-407C.

2. A composition according to claim 1, wherein the composition has a GWP of less than 1800.

3. A composition according to claim 2, wherein the composition has a GWP of less than 1700.

4. A composition according to claim 2, wherein the composition has a GWP of less than 1500.

5. A composition according to claim 2, wherein the composition has a GWP of less than 1400.

6. A composition according to claim 5, wherein the composition has a GWP of less than 1300.

7. A composition according to claim 1, wherein the temperature glide is less than about 15 k.

8. A composition according to claim 7, wherein the temperature glide is less than about 10 K.

9. A composition according to claim 1, wherein the composition is less flammable than R-32 alone.

10. A composition according to claim 9 wherein the composition has:

(a) a higher flammable limit;

(b) a higher ignition energy; and

/or

(c) a lower flame velocity

compared to R-32 alone.

11. A composition according to claim 9 is non-flammable.

12. A composition comprising a lubricant and a composition according to claim 1.

13. A composition according to claim 12, wherein the lubricant is selected from mineral oil, silicone oil, polyalkyl benzenes (PABs), polyol esters (POEs), polyalkylene glycols (PAGs), polyalkylene glycol esters (PAG esters), polyvinyl ethers (PVEs), poly (alpha-olefins) and combinations thereof.

14. A composition according to claim 12 further comprising a stabiliser.

15. A composition according to claim 14, wherein the stabiliser is selected from diene-based compounds, phosphates, phenol compounds and epoxides, and mixtures thereof.

16. A composition comprising a flame retardant and a composition according to claim 1.

17. A composition according to claim 7, wherein the additional flame retardant is selected from the group consisting of tri-(2-chloroethyl)-phosphate, (chloropropyl) phosphate, tri-(2,3-dibromopropyl)-phosphate, tri-(1,3-dichloropropyl)-phosphate, diammonium phosphate, antimony oxide, aluminium trihydrate, polyvinyl chloride, a fluorinated iodocarbon, a fluorinated bromocarbon, trifluoro iodomethane, perfluoroalkyl amines, bromo-fluoroalkyl amines and mixtures thereof.

18. A composition according to claim 1, which is a refrigerant composition.

19. A heat transfer device containing a composition as defined in claim 1.

20. A method for preparing a composition for use in a heat transfer device as defined in claim 19, which composition or heat transfer device contains R-134a, the method comprising introducing R-1243ze(E), R-32, R-125, R-134a, and optionally a lubricant, a stabiliser and/or an additional flame retardant, into a heat transfer device containing an existing heat transfer fluid which is R-134a.

21. A method according to claim 20, comprising the step of removing at least some of the existing R-134a from the heat transfer device before introducing the R-1243ze(E), R-32, R-125, R-134a, and optionally the lubricant, the stabiliser and/or the additional flame retardant.

22. A heat transfer device according to claim 19 which is a refrigeration device.

23. A heat transfer device according to claim 22 which is selected from group consisting of automotive air conditioning systems, residential air conditioning systems, commercial air conditioning systems, residential refrigerator systems, residential freezer systems, commercial refrigerator systems, commercial freezer systems, chiller air conditioning systems, chiller refrigeration systems, and commercial or residential heat pump systems.

24. A heat transfer device according to claim 22 contains a compressor.

25. A blowing agent comprising a composition as defined in claim 1.

26. A foamable composition comprising one or more components capable of forming foam and a composition as defined in claim 1, wherein the one or more components capable of forming foam are selected from polyurethanes, thermoplastic polymers and resins, such as polystyrene, and epoxy resins, and mixtures thereof.

27. A foam obtainable from the foamable composition of claim 26.

28. A foam comprising a composition according to claim 27.

29. A sprayable composition comprising material to be sprayed and a propellant comprising a composition as defined in claim 1.

30. A method for cooling an article which comprises condensing a composition defined in claim 1 and thereafter evaporating the composition in the vicinity of the article to be cooled.

31. A method for heating an article which comprises condensing a composition as defined in claim 1 in the vicinity of the article to be heated and thereafter evaporating the composition.

32. A method for extracting a substance from biomass comprising contacting biomass with a solvent comprising a composition as defined in claim 1, and separating the substance from the solvent.

33. A method of cleaning an article comprising contacting the article with a solvent comprising a composition as defined in claim 1.

34. A method of extracting a material from an aqueous solution comprising contacting the aqueous solution with a solvent comprising a composition as defined in claim 1, and separating the substance from the solvent.

35. A method for extracting a material from a particulate solid matrix comprising contacting the particulate solid matrix with a solvent comprising a composition as defined in claim 1, and separating the material from the solvent.

36. A mechanical power generation device containing a composition as defined in claim 1.

37. A mechanical power generating device according to claim 36 which is adapted to use a Rankine Cycle or modification thereof to generate work from heat.

38. A method of retrofitting a heat transfer device comprising the step of removing an existing heat transfer fluid, and introducing a composition as defined in claim 1.

39. A method of claim 38 wherein the heat transfer device is a refrigeration device.

40. A method according to claim 39 wherein the heat transfer device is an air conditioning system.

41. A method for reducing the environmental impact arising from the operation of a product comprising an existing compound or composition, the method comprising replacing at least partially the existing compound or composition with a composition as defined in claim 1.

42. A method according to claim 41 wherein the product is selected from a heat transfer device, a blowing agent, a foamable composition, a sprayable composition, a solvent or a mechanical power generation device.

43. A method according to claim 42 wherein the product is a heat transfer device.

44. A method according to claim 41 wherein the existing compound or composition is a heat transfer composition.

45. A method for generating greenhouse gas emission credit comprising (i) replacing an existing compound or composition with a composition as defined in claim 1, wherein the composition has a lower GWP than the existing compound or composition;

and (ii) obtaining greenhouse gas emission credit for said replacing step.

46. A method of claim 45 wherein the use of the composition of the invention results in a lower Total Equivalent Warming Impact, and/or a lower Life-Cycle Carbon Production than is be attained by use of the existing compound or composition.

47. A method of claim 45 carried out on a product from the fields of air-conditioning, refrigeration, heat transfer, blowing agents, aerosols or sprayable propellants, gaseous dielectrics, cryosurgery, veterinary procedures, dental procedures, fire extinguishing, flame suppression, solvents, cleaners, air horns, pellet guns, topical anesthetics, and expansion applications.

48. A method according to claim 44 wherein the heat transfer composition is a refrigerant selected from R-22, R-410A, R-407A, R-407B, R-407C, R507 and R-404a.

49. A composition according to claim 1 consisting essentially of about 20% by weight R-1234ze(E), from about 30% by weight R-32, about 25% by weight R-125 and about 25% by weight R-134a.

50. A composition according to claim 1, wherein the composition further comprises 2,3,3,3-tetrafluoropropene (1234yf).

51. A composition according to claim 1, wherein the composition has a volumetric refrigeration capacity within about 5% of R-407C.

52. A composition according to claim 1, wherein the composition has a volumetric refrigeration capacity within about 5% of R-404A.