Regenerative recovery of sulfur dioxide from effluent gases
First Claim
1. A process for selectively removing and recovering sulfur dioxide from a sulfur dioxide-containing effluent gas, comprising:
- contacting the effluent gas comprising the effluent gas and oxygen with a buffered aqueous absorption solution comprising a salt of a polyprotic carboxylic acid and an oxidation inhibitor selected from the group consisting of ascorbic acid, ethylenediaminetetraacetic acid, p-phenylenediamine, hydroquinone and mixtures thereof in a sulfur dioxide absorber, thereby absorbing sulfur dioxide from the effluent gas into the absorption solution and producing an exhaust gas from which sulfur dioxide has been removed and a sulfur dioxide-enriched absorption solution;
heating the sulfur dioxide-enriched absorption solution in a sulfur dioxide stripper to desorb sulfur dioxide and thereby produce a regenerated sulfur dioxide absorption solution and a sulfur dioxide-enriched stripper gas; and
reintroducing the regenerated sulfur dioxide absorption solution to the sulfur dioxide absorber;
immediately following the step of heating the sulfur dioxide-enriched absorption solution in the sulfur dioxide stripper producing the regenerated sulfur dioxide absorption solution and the sulfur dioxide-enriched stripper gas comprising water vapor and before reintroducing the regenerated sulfur dioxide absorption solution to the sulfur dioxide absorber, the process further comprises;
increasing the pressure of the sulfur dioxide-enriched stripper gas;
cooling the pressurized sulfur dioxide-enriched stripper gas by transfer of heat to the regenerated sulfur dioxide absorption solution in a reboiler of the sulfur dioxide stripper to condense water vapor and produce a reboiler gas effluent comprising sulfur dioxide and water vapor and an aqueous condensate comprising sulfur dioxide;
heating the aqueous condensate from the reboiler in a condensate stripper to desorb sulfur dioxide and produce a condensate stripper gas comprising water vapor and sulfur dioxide desorbed from the aqueous condensate; and
cooling the condensate stripper gas and reboiler gas effluent in a low temperature condenser to condense water vapor and produce a recovered sulfur dioxide stream comprising sulfur dioxide obtained in the aqueous condensate and in the reboiler gas effluent and a stripped condensate effluent depleted in sulfur dioxide.
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Accused Products
Abstract
This invention relates to processes for selective removal of contaminants from effluent gases. A sulfur dioxide absorption/desorption process for selective removal and recovery of sulfur dioxide from effluent gases utilizes a buffered aqueous absorption solution comprising weak inorganic or organic acids or salts thereof, to selectively absorb sulfur dioxide from the effluent gas. Absorbed sulfur dioxide is subsequently stripped to regenerate the absorption solution and produce a sulfur dioxide-enriched gas. A process for simultaneous removal of sulfur dioxide and nitrogen oxides (NOx) from effluent gases and recovery of sulfur dioxide utilizes a buffered aqueous absorption solution including a metal chelate to absorb sulfur dioxide and NOx from the gas and subsequently reducing absorbed NOx to form nitrogen. A process to control sulfate salt contaminant concentration in the absorption solution involves partial crystallization and removal of sulfate salt crystals.
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Citations
26 Claims
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1. A process for selectively removing and recovering sulfur dioxide from a sulfur dioxide-containing effluent gas, comprising:
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contacting the effluent gas comprising the effluent gas and oxygen with a buffered aqueous absorption solution comprising a salt of a polyprotic carboxylic acid and an oxidation inhibitor selected from the group consisting of ascorbic acid, ethylenediaminetetraacetic acid, p-phenylenediamine, hydroquinone and mixtures thereof in a sulfur dioxide absorber, thereby absorbing sulfur dioxide from the effluent gas into the absorption solution and producing an exhaust gas from which sulfur dioxide has been removed and a sulfur dioxide-enriched absorption solution; heating the sulfur dioxide-enriched absorption solution in a sulfur dioxide stripper to desorb sulfur dioxide and thereby produce a regenerated sulfur dioxide absorption solution and a sulfur dioxide-enriched stripper gas; and reintroducing the regenerated sulfur dioxide absorption solution to the sulfur dioxide absorber; immediately following the step of heating the sulfur dioxide-enriched absorption solution in the sulfur dioxide stripper producing the regenerated sulfur dioxide absorption solution and the sulfur dioxide-enriched stripper gas comprising water vapor and before reintroducing the regenerated sulfur dioxide absorption solution to the sulfur dioxide absorber, the process further comprises; increasing the pressure of the sulfur dioxide-enriched stripper gas; cooling the pressurized sulfur dioxide-enriched stripper gas by transfer of heat to the regenerated sulfur dioxide absorption solution in a reboiler of the sulfur dioxide stripper to condense water vapor and produce a reboiler gas effluent comprising sulfur dioxide and water vapor and an aqueous condensate comprising sulfur dioxide; heating the aqueous condensate from the reboiler in a condensate stripper to desorb sulfur dioxide and produce a condensate stripper gas comprising water vapor and sulfur dioxide desorbed from the aqueous condensate; and cooling the condensate stripper gas and reboiler gas effluent in a low temperature condenser to condense water vapor and produce a recovered sulfur dioxide stream comprising sulfur dioxide obtained in the aqueous condensate and in the reboiler gas effluent and a stripped condensate effluent depleted in sulfur dioxide. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8)
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9. A process for selectively removing and recovering sulfur dioxide from a sulfur dioxide-containing effluent gas, comprising:
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contacting the effluent gas comprising the effluent gas and oxygen with a buffered aqueous absorption solution comprising a salt of a polyprotic carboxylic acid and an oxidation inhibitor selected from the group consisting of ascorbic acid, ethylenediaminetetraacetic acid, p-phenylenediamine, hydroquinone and mixtures thereof in a sulfur dioxide absorber, thereby absorbing sulfur dioxide from the effluent gas into the absorption solution and producing an exhaust gas from which sulfur dioxide has been removed and a sulfur dioxide-enriched absorption solution; heating the sulfur dioxide-enriched absorption solution in a sulfur dioxide stripper to desorb sulfur dioxide and thereby produce a regenerated sulfur dioxide absorption solution and a sulfur dioxide-enriched stripper gas; diverting at least a portion of the regenerated sulfur dioxide absorption solution exiting the stripper as a slip stream; evaporating water from the slip stream of the regenerated sulfur dioxide absorption solution at a temperature of at least about 40°
C. to produce a concentrated absorption solution supersaturated in the sulfate salt;precipitating sulfate salt crystals from the concentrated absorption solution to form a crystallization slurry comprising precipitated sulfate salt crystals and a mother liquor; separating the sulfate salt crystals from the mother liquor to form a treated absorption solution comprising the polyprotic carboxylic acid salt; and combining the treated absorption solution with the remainder of the regenerated sulfur dioxide absorption solution, which is reintroduced to the sulfur dioxide absorber. - View Dependent Claims (10, 11, 12, 13, 14, 15, 16, 17, 18, 19)
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20. A process for selectively removing and recovering sulfur dioxide from a sulfur dioxide-containing effluent gas, the process comprising:
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contacting the effluent gas with a buffered aqueous absorption solution comprising sodium malate in a sulfur dioxide absorber, thereby absorbing sulfur dioxide from the effluent gas into the absorption solution and producing an exhaust gas from which sulfur dioxide has been removed and a sulfur dioxide-enriched absorption solution; heating the sulfur dioxide-enriched absorption solution in a sulfur dioxide stripper to desorb sulfur dioxide and thereby produce a regenerated sulfur dioxide absorption solution and a sulfur dioxide-enriched stripper gas; diverting at least a portion of the regenerated sulfur dioxide absorption solution exiting the stripper as a slip stream; evaporating water from the slip stream of the regenerated sulfur dioxide absorption solution at a temperature of at least about 40°
C. to produce a concentrated absorption solution supersaturated in a sulfate salt;precipitating sulfate salt crystals from the concentrated absorption solution to form a crystallization slurry comprising precipitated sulfate salt crystals and a mother liquor; separating the sulfate salt crystals from the mother liquor to form a treated absorption solution comprising the sodium malate; and combining the treated absorption solution with the remainder of the regenerated sulfur dioxide absorption solution, which is reintroduced to the sulfur dioxide absorber. - View Dependent Claims (21, 22, 23, 24, 25, 26)
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Specification