Composite shaped abrasive particles and method of forming same

• US 10,280,350 B2
• Filed: 05/16/2014
• Issued: 05/07/2019
• Est. Priority Date: 12/30/2011
• Status: Active Grant

• Current Assignee: Saint-Gobain Ceramics & Plastics Incorporated (Compagnie De Saint-Gobain)
• Original Assignee: Saint-Gobain Ceramics & Plastics Incorporated (Compagnie De Saint-Gobain)
• Inventors: Yener, Doruk O., Braun, Paul
• Primary Examiner(s): Olsen, Kaj K
• Assistant Examiner(s): Christie, Ross J
• Application Number:
  US14/279,531
• Publication Number:
  US 20140250797A1
• Time in Patent Office: 1,817 Days
• Field of Search: None
• CPC Class Codes: C04B 2235/3244 Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
• CPC Class Codes: C04B 2235/94 Products characterised by their shape
• CPC Class Codes: C04B 2235/96 Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
• CPC Class Codes: C04B 35/1115 Minute sintered entities, e.g. sintered abrasive grains or shaped particles such as platelets abrasives C09K3/14
• CPC Class Codes: C04B 35/64 Burning or sintering processes C04B33/32 takes precedence ; powder metallurgy B22F
• CPC Class Codes: C09K 3/1409 Abrasive particles per se preparation of diamond C01B32/25
• CPC Class Codes: C09K 3/1436 Composite particles, e.g. coated particles

Abstract

A method of forming a shaped abrasive particle includes forming a first mixture and a second mixture in a single forming process into an integral precursor shaped abrasive particle, wherein the first mixture has a different composition than a composition of the second mixture.

Claims

1. A particulate material comprising:

a shaped abrasive particle having a body comprising;

a first layer;

a second layer overlying the first layer; and

a diffusion interface disposed between the first layer and the second layer,

wherein the second layer comprises a dopant;

wherein the diffusion interface defines a step function difference in a concentration of the dopant in the second layer compared to a concentration of the dopant in the first layer; and

wherein the diffusion interface separates a region of the first layer having a first dopant concentration (D1c) and a region of the second layer having a second dopant concentration (D2c).

2. The particulate material of claim 1, wherein the diffusion interface extends for an entire area between the first layer and the second layer.

3. The particulate material of claim 1, wherein the diffusion interface extends for an entire length of the body.

4. The particulate material of claim 1, wherein the diffusion interface extends for an entire width of the body.

5. The particulate material of claim 1, wherein the difference between the first dopant concentration and the second dopant concentration is a dopant concentration difference (Δ

Dc) of at least about 0.2 wt %.

6. The particulate material of claim 5, wherein the dopant concentration difference (Δ

Dc) is not greater than about 30 wt %.

7. The particulate material of claim 1, wherein the first layer comprises the dopant.

8. The particulate material of claim 1, wherein the dopant is selected from the group consisting of alkali elements, alkaline earth elements, rare-earth elements, hafnium (Hf), zirconium (Zr), niobium (Nb), tantalum (Ta), molybdenum (Mo), and a combination thereof.

9. The particulate material of claim 1, wherein the first layer and the second layer differ in composition by at least a dopant material selected from the group consisting of lithium (Li), sodium (Na), potassium (K), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), scandium (Sc), yttrium (Y), lanthanum (La), cesium (Ce), praseodymium (Pr), niobium (Nb), hafnium (Hf), zirconium (Zr), niobium (Nb), tantalum (Ta), molybdenum (Mo), and a combination thereof.

10. The particulate material of claim 1, wherein the first layer comprises a first thickness and the second layer comprises a second thickness, wherein the first thickness and the second thickness are substantially the same.

11. The particulate material of claim 1, wherein the first layer comprises a first thickness and the second layer comprises a second thickness, and wherein the first thickness and the second thickness are different from each other by at least about 5%.

12. The particulate material of claim 1, wherein the dopant comprises zirconium.

13. The particulate material of claim 1, wherein the first layer defines a first two-dimensional shape as viewed in a plane defined by a length and a width of the body selected from the group consisting of polygons, ellipsoids, numerals, Greek alphabet characters, Latin alphabet characters, Russian alphabet characters, complex shapes having a combination of polygonal shapes, and a combination thereof.

14. The particulate material of claim 13, wherein the second layer defines a second two-dimensional shape as viewed in a plane defined by a length and a width of the body selected from the group consisting of polygons, ellipsoids, numerals, Greek alphabet characters, Latin alphabet characters, Russian alphabet characters, complex shapes having a combination of polygonal shapes, and a combination thereof.

15. The particulate material of claim 14, wherein the second two-dimensional shape is different than the first two-dimensional shape.

16. The particulate material of claim 1, further comprising an intermediate layer disposed between the first layer and the second layer, wherein the diffusion interface is disposed between the second layer and the intermediate layer, and further comprising an intermediate diffusion layer disposed at an interface of the first layer and the intermediate layer.

17. The particulate material of claim 1, wherein the first layer is essentially free of the dopant.