Apparatus with flow-through capacitors for the purification of a liquid and process for the purification of said liquid

• US 10,287,191 B2
• Filed: 11/15/2013
• Issued: 05/14/2019
• Est. Priority Date: 11/15/2012
• Status: Active Grant

• Current Assignee: Idropan Dell'Orto Depuratori SRL
• Original Assignee: Idropan Dell'Orto Depuratori SRL
• Inventors: Servida, Tullio
• Primary Examiner(s): Jain, Salil
• Application Number:
  US14/442,730
• Publication Number:
  US 20150315040A1
• Time in Patent Office: 2,006 Days
• CPC Class Codes: C02F 1/4691 Capacitive deionisation
• CPC Class Codes: C02F 2101/12 Halogens or halogen-containing compounds
• CPC Class Codes: C02F 2103/08 Seawater, e.g. for desalination
• CPC Class Codes: C02F 2201/46 Apparatus for electrochemical processes
• CPC Class Codes: C02F 2201/46135 Voltage
• CPC Class Codes: H02J 7/0016 using shunting, discharge or bypass circuits

Abstract

Apparatus with flow-through capacitors for the purification of a liquid, which comprises: at least one cell (2) provided with at least one flow-through capacitor (4) provided with two or more electrodes facing each other, between which a liquid to be treated is susceptible to flow; electrical power supply means (13) adapted to supply a direct supply voltage (V_A); a modulation circuit (14) connected in input to the electrical power supply means (13) in order to receive the supply voltage (V_A) and provided with switches (22′, 22″; 23′, 23″) actuatable to apply at least one operating voltage between the facing electrodes of each capacitor (4). In addition, the present apparatus comprises a control circuit (24) which is connected to the switches (22′, 22″; 23′, 23″) of the modulation circuit (14), and is provided with a control module with pulse width modulation (PWM), which drives the switching of the switches (22′, 22″; 23′, 23″) by power supplying the facing electrodes of each capacitor (4) by means of a pulsed voltage having average value proportional to the aforesaid operating voltage.

Claims

1. Apparatus with flow-through capacitors for the purification of a liquid, such apparatus comprising:

at least one cell which is provided with at least one flow-through capacitor provided with two or more electrodes facing each other, between which a liquid to be treated containing ionized particles is susceptible to flow;

an electrical power supply adapted to supply a direct current supply voltage (V_A);

a modulation circuit electrically connected in input to said electrical power supply in order to receive said direct current supply voltage (V_A), electrically connected in output to said at least one flow-through capacitor and provided with at least one switch actuatable to apply at least one operating voltage between the facing electrodes of said at least one flow-through capacitor;

a control circuit connected to said at least one switch and provided with a control module with pulse width modulation (PWM), wherein said control circuit drives the switching of said at least one switch so that said at least one switch supplies power to said facing electrodes with at least one pulsed voltage having average value proportional to said operating voltage;

wherein said pulsed voltage has rectangular waveform having a duty cycle adjustable by said control circuit, so that said pulsed voltage having rectangular waveform is applied to said at least one flow-through capacitor;

wherein said pulsed voltage has a frequency greater than about 30 Hz.

2. Apparatus with flow-through capacitors for the purification of a liquid according to claim 1, wherein said modulation circuit comprises an H-bridge electrically connected in input to said electrical power supply and electrically connected in output to said at least one flow-through capacitor, and said at least one switch comprises at least two pairs of switches of said H-bridge actuatable by said control circuit in order to alternately apply operating voltages with opposite polarities between the facing electrodes of said at least one flow-through capacitor.

3. Apparatus with flow-through capacitors for the purification of a liquid according to claim 2, wherein said H-bridge comprises a first pair of switches actuatable for applying, between the facing electrodes of said at least one flow-through capacitor, a first pulsed voltage susceptible to attract the ionized particles of said liquid on said electrodes, and a second pair of switches actuatable for applying, between said facing electrodes, a second pulsed voltage having average value with polarity opposite the polarity of the average value of said first pulsed voltage and susceptible to move the ionized particles away from said electrodes;

said control module with pulse width modulation (PWM) being connected to at least one first switch of said first pair of switches and to at least one second switch of said second pair of switches, and being adapted to drive the switching of said first and said second switch in order to respectively modulate said first and said second pulsed voltage respectively with a first and with a second duty cycle proportional to the ratio between the average value of the corresponding said pulsed voltage to be applied to said at least one flow-through capacitor and said direct current supply voltage (V_A).

4. Apparatus with flow-through capacitors for the purification of a liquid according to claim 1, wherein said at least one switch of said modulation circuit comprises at least one semiconductor electronic device.

5. Apparatus with flow-through capacitors for the purification of a liquid according to claim 1, wherein said cell is provided with two connection terminals and comprises at least two said flow-through capacitors, which are susceptible to be traversed by said liquid to be treated containing ionized particles and are electrically connected in series, by means of their power supply nodes, between the connection terminals of said cell;

wherein said cell comprises at least one first adjustment switch connected in parallel to the power supply nodes of each said flow-through capacitor;

wherein said control circuit is provided with;

detection means connected to the power supply nodes of each flow-through capacitor of said cell for detecting values of the operating voltage between the power supply nodes of each said flow-through capacitor,

a command module adapted to actuate said first adjustment switch to switch between a first closed position, in which said first adjustment switch allows the passage of current between two first terminals thereof, and a first open position, in which said first adjustment switch prevents the passage of current between said first terminals;

wherein the command module of said control circuit is configured to actuate said first adjustment switch to switch in said first closed position at at least one value of said operating voltage, measured by said detection means, greater in absolute value than a predetermined threshold value, in order to bring said operating voltage to said threshold value.

6. Apparatus with flow-through capacitors for the purification of a liquid according to claim 5, wherein said command module actuates said first adjustment switch to switch in said first closed position with said liquid to be treated which flows through said flow-through capacitor.

7. Apparatus with flow-through capacitors for the purification of a liquid according to claim 5, wherein said command module drives said first adjustment switch to cyclically switch between said first closed position and said first open position.

8. Apparatus with flow-through capacitors for the purification of a liquid according to claim 5, wherein, at values of said operating voltage greater in absolute value than said threshold value, the switching of said first adjustment switch driven by said command module is pulsed.

9. Apparatus with flow-through capacitors for the purification of a liquid according to claim 7, wherein, at values of said operating voltage greater in absolute value than said threshold value, the switching of said first adjustment switch driven by said command module is pulsed and wherein said command module comprises a pulsed signal generator which, at values of said operating voltage greater in absolute value than said threshold value, is enabled to send to said first adjustment switch at least one sequence of control pulses that drive said first adjustment switch to cyclically switch between said first closed position and said first open position, in order to bring said operating voltage to said threshold value.

11. Apparatus with flow-through capacitors for the purification of a liquid according to claim 5, wherein each said adjustment switch comprises a semiconductor electronic device.

12. Apparatus with flow-through capacitors for the purification of a liquid according to claim 5, wherein said detection means of said control circuit comprise a processing unit adapted to calculate the average value of said pulsed voltage and to compare said pulsed voltage with said threshold value.

13. Apparatus with flow-through capacitors for the purification of a liquid according to claim 1, wherein said pulsed voltage has a frequency greater than about 100 Hz.

14. Apparatus with flow-through capacitors for the purification of a liquid according to claim 4, wherein said at least one switch of said modulation circuit comprises a metal-oxide-semiconductor field-effect transistor (MOSFET).

10. Apparatus with flow-through capacitors for the purification of a liquid, such apparatus comprising:

at least one cell which is provided with at least one flow-through capacitor provided with two or more electrodes facing each other, between which a liquid to be treated containing ionized particles is susceptible to flow;

an electrical power supply adapted to supply a direct current supply voltage (V_A);

a modulation circuit electrically connected in input to said electrical power supply in order to receive said direct current supply voltage (V_A), electrically connected in output to said at least one flow-through capacitor and provided with at least one switch actuatable to apply at least one operating voltage between the facing electrodes of said at least one flow-through capacitor;

a control circuit connected to said at least one switch and provided with a control module with pulse width modulation (PWM), wherein said control circuit drives the switching of said at least one switch so that said at least one switch supplies power to said facing electrodes with at least one pulsed voltage having average value proportional to said operating voltage;

wherein said cell is provided with two connection terminals and comprises at least two said flow-through capacitors, which are susceptible to be traversed by said liquid to be treated containing ionized particles and are electrically connected in series, by means of their power supply nodes, between the connection terminals of said cell;

wherein said cell comprises at least one first adjustment switch connected in parallel to the power supply nodes of each said flow-through capacitor;

wherein said control circuit is provided with;

detection means connected to the power supply nodes of each flow-through capacitor of said cell for detecting values of the operating voltage between the power supply nodes of each said flow-through capacitor,

a command module adapted to actuate said first adjustment switch to switch between a first closed position, in which said first adjustment switch allows the passage of current between two first terminals thereof, and a first open position, in which said first adjustment switch prevents the passage of current between said first terminals;

wherein the command module of said control circuit is configured to actuate said first adjustment switch to switch in said first closed position at at least one value of said operating voltage, measured by said detection means, greater in absolute value than a predetermined threshold value, in order to bring said operating voltage to said threshold value;

wherein said cell comprises at least one second adjustment switch connected in series to each corresponding said flow-through capacitor, and actuatable by said command module to switch between a second closed position, in which said second adjustment switch allows the passage of current between two second terminals thereof, and a second open position, in which said second adjustment switch prevents the passage of current between said second terminals;

said command module actuating said second adjustment switch to switch in said second open position at at least one value of said operating voltage greater in absolute value than said threshold value.