Three-stage energy-integrated product gas generation system

• US 10,287,519 B2
• Filed: 09/19/2018
• Issued: 05/14/2019
• Est. Priority Date: 03/25/2016
• Status: Active Grant

• Current Assignee: Thermochem Recovery International, Inc.
• Original Assignee: Thermochem Recovery International, Inc.
• Inventors: Chandran, Ravi, Burciaga, Daniel A., Leo, Daniel Michael, Freitas, Shawn Robert, Newport, Dave G., Miller, Justin Kevin, Harrington, Kaitlin Emily, Attwood, Brian Christopher
• Primary Examiner(s): Robinson, Renee
• Application Number:
  US16/135,069
• Publication Number:
  US 20190016961A1
• Time in Patent Office: 237 Days
• CPC Class Codes: B09B 3/40 involving thermal treatment, e.g. evaporation processes using mineral binders involving a melting or softening step B09B3/29; involving radiation B09B3/50
• CPC Class Codes: B09B 3/45 Steam treatment, e.g. supercritical water gasification or oxidation
• CPC Class Codes: C10B 27/06 Conduit details, e.g. valves
• CPC Class Codes: C10B 3/02 with heat-exchange devices
• CPC Class Codes: C10B 47/04 in shaft furnaces
• CPC Class Codes: C10B 47/18 with moving charge
• CPC Class Codes: C10B 49/16 with moving solid heat-carriers in divided form
• CPC Class Codes: C10B 51/00 Destructive distillation of solid carbonaceous materials by combined direct and indirect heating
• CPC Class Codes: C10B 53/07 of solid raw materials consisting of synthetic polymeric materials, e.g. tyres waste in general, e.g. household waste C10B53/00; recovery or working-up of waste materials of organic macromolecular compounds or compositions based thereon by dry-heat treatment for obtaining partially depolymerised materials C08J11/10; production of liquid hydrocarbon mixtures from rubber or rubber waste C10G1/10
• CPC Class Codes: C10J 2200/00 Details of gasification apparatus
• CPC Class Codes: C10J 2200/15 Details of feeding means
• CPC Class Codes: C10J 2300/0913 Carbonaceous raw material
• CPC Class Codes: C10J 2300/094 Char
• CPC Class Codes: C10J 2300/0956 Air or oxygen enriched air
• CPC Class Codes: C10J 2300/0959 Oxygen
• CPC Class Codes: C10J 2300/1223 by burners
• CPC Class Codes: C10J 2300/1253 by injecting hot gas
• CPC Class Codes: C10J 2300/1861 Heat exchange between at least two process streams
• CPC Class Codes: C10J 2300/1892 with one stream being water/steam
• CPC Class Codes: C10J 3/48 Apparatus; Plants
• CPC Class Codes: C10J 3/503 : for gasifiers with stationary fluidised bed
• CPC Class Codes: C10J 3/54 : Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
• CPC Class Codes: C10J 3/66 : by introducing them into the gasification zone
• CPC Class Codes: C10J 3/721 : Multistage gasification, e.g. plural parallel or serial gasification stages
• CPC Class Codes: C10J 3/86 : combined with waste-heat boilers
• CPC Class Codes: Y02E 20/16 : Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
• CPC Class Codes: Y02E 50/10 : Biofuels, e.g. bio-diesel
• CPC Class Codes: Y02E 50/30 : Fuel from waste, e.g. synthetic alcohol or diesel

Abstract

A multi-stage product gas generation system converts a carbonaceous material, such as municipal solid waste, into a product gas which may subsequently be converted into a liquid fuel or other material. One or more reactors containing bed material may be used to conduct reactions to effect the conversions. Unreacted inert feedstock contaminants present in the carbonaceous material may be separated from bed material using a portion of the product gas. A heat transfer medium collecting heat from a reaction in one stage may be applied as a reactant input in another, earlier stage.

Claims

1. A three-stage energy-integrated product gas generation system (1001) configured to produce a product gas from a carbonaceous material (102), the system comprising:

(a) a first reactor (100) having a first interior (101) and comprising;

a first reactor carbonaceous material input (104) to the first interior (101);

a first reactor reactant input (108) to the first interior (101), and

a first reactor product gas output (124);

(b) a second reactor (200) having a second interior (201) and comprising;

a second reactor char input (204) to the second interior (201), in fluid communication with the first reactor product gas output (124);

a second reactor oxygen-containing gas input (220) to the second interior (201);

a second reactor product gas output (224); and

a second reactor heat exchanger (HX-B) in thermal contact with the second interior (201), the second reactor heat exchanger comprising a second reactor heat transfer medium inlet (212) and a second reactor heat transfer medium outlet (216), the second reactor heat transfer medium outlet (216) being in fluid communication with the first reactor reactant input (108); and

(c) a third reactor (300) having a third interior (301) and comprising;

one or more product gas inputs (303, 304, 305) to the third interior (301), in fluid communication with the first and second product gas outputs (124, 224);

a third reactor oxygen-containing gas input (320) to the third interior (301);

a third reactor product gas output (336); and

a third reactor heat exchanger (HX-C) in thermal contact with the third interior (301), the third reactor heat exchanger comprising a third reactor heat transfer medium inlet (312) and a third reactor heat transfer medium outlet (316), the third heat transfer medium outlet (316) being in fluid communication with the second reactor heat transfer medium inlet (212);

wherein;

the third reactor heat exchanger (HX-C) is configured to receive a heat transfer medium (310) at a third reactor inlet temperature (T0) via the third reactor heat transfer medium inlet (312); and

a first portion of the heat transfer medium (310) passes through the third reactor heat exchanger (HX-C) and then the second reactor heat exchanger (HX-B) before being introduced, into the first interior (101) via the first reactor reactant input (108), as a reactant (100) at a first reactor reactant temperature (TR1), the first reactor reactant temperature (TR1) being higher than the third reactor inlet temperature (T0).

2. The three-stage product gas generation system (1001) according to claim 1, further comprising:

a second reactor reactant input (208) to the second interior (201);

wherein;

the second reactor reactant input (208) is in fluid communication with the second reactor heat transfer medium outlet (216) and is configured to introduce at least a portion (206A) of said heat transfer medium (310) into the second interior (201) as a reactant of the second reactor (200).

3. The three-stage energy-integrated product gas generation system (1001) according to claim 1, further comprising:

a first reactor oxygen-containing gas input (120, 120A, 120B, 120C) to the first interior (101) and configured to receive a first reactor oxygen-containing gas (118).

4. The three-stage energy-integrated product gas generation system (1001) according to claim 1, further comprising a first solids separation device (150) having:

a first separation input (152) in fluid communication with the first reactor product gas output (124);

a first separation char output (154) in fluid communication with the second reactor char input (204); and

,

a first separation gas output (156).

5. The three-stage energy-integrated product gas generation system (1001) according to claim 4, further comprising a second solids separation device (250) having:

a second separation input (252) in fluid communication with the second reactor product gas output (224);

a second separation solids output (254) in fluid communication with a solids transfer conduit (234); and

,

a second separation gas output (256).

6. The three-stage energy-integrated product gas generation system (1001) according to claim 5, further comprising:

a combined reactor product gas conduit (230) in fluid communication with both the first separation gas output (156) and the second separation gas output (256) and configured to combine product gas created by both the first reactor (100) and the second reactor (200).

7. The three-stage energy-integrated product gas generation system (1001) according to claim 1, wherein the first interior comprises:

a first reactor dense bed zone (AZ-A);

a first reactor feed zone (AZ-B) located above the first reactor dense bed zone; and

, a first reactor splash zone (AZ-C) located above the first reactor feed zone.

8. The three-stage energy-integrated product gas generation system (1001) according to claim 7, further comprising:

a first reactor dense bed zone reactant input (108A) configured to receive a first reactor dense bed zone reactant (106A) into the first reactor dense bed zone (AZ-A);

a first reactor feed zone reactant input (108B) configured to receive a first reactor feed zone reactant (106B) into the first reactor feed zone (AZ-B); and

a first reactor splash zone reactant input (108C) configured to receive a first reactor splash zone reactant (106C) into the first reactor splash zone (AZ-C).

9. The three-stage energy-integrated product gas generation system (1001) according to claim 8, further comprising:

at least three first reactor feed zone reactant inputs; and

,

at least three first reactor splash zone reactant inputs.

10. The three-stage energy-integrated product gas generation system (1001) according to claim 7, further comprising:

a first reactor dense bed zone oxygen-containing gas input (120A) configured to receive a first reactor oxygen-containing gas (118A) into the first reactor dense bed zone (AZ-A);

a first reactor feed zone oxygen-containing gas input (120B) configured to receive a first reactor feed zone oxygen-containing gas (118B) into the first reactor feed zone (AZ-B); and

a first reactor splash zone oxygen-containing gas input (120C) configured to receive a first reactor splash zone oxygen-containing gas (118C) into the first reactor splash zone (AZ-C).

11. The three-stage energy-integrated product gas generation system (1001) according to claim 10, comprising:

at least three first reactor feed zone oxygen-containing gas inputs; and

,

at least three first reactor splash zone oxygen-containing gas inputs.

12. The three-stage energy-integrated product gas generation system (1001) according to claim 1, wherein the second interior comprises:

a second reactor dense bed zone (BZ-A);

a second reactor feed zone (BZ-B) located above the second reactor dense bed zone; and

,

a second reactor splash zone (BZ-C) located above the second reactor feed zone.

13. The three-stage energy-integrated product gas generation system (1001) according to claim 12, further comprising:

a second reactor dense bed zone reactant input (208A) configured to receive a second reactor dense bed zone reactant (206A) into the second reactor dense-bed zone (BZ-A);

a second reactor feed zone reactant input (208B) configured to receive a second reactor feed zone reactant (206B) into the second reactor feed zone (BZ-B); and

,

a second reactor splash zone reactant input (208C) configured to receive a second reactor splash zone reactant (206C) into the second reactor splash zone (BZ-C).

14. The three-stage energy-integrated product gas generation system (1001) according to claim 13, further comprising:

a second reactor dense bed zone oxygen-containing gas input (220A) configured to receive a second reactor oxygen-containing gas (218A) into the second reactor dense bed zone (BZ-A);

a second reactor feed zone oxygen-containing gas input (220B) configured to receive a second reactor feed zone oxygen-containing gas (218B) into the second reactor feed zone (BZ-B); and

a second reactor splash zone oxygen-containing gas input (220C) configured to receive a second reactor splash zone oxygen-containing gas (218C) into the second reactor splash zone (BZ-C).

15. The three-stage energy-integrated product gas generation system (1001) according to claim 14, comprising:

at least three second reactor feed zone oxygen-containing gas inputs; and

,

at least three second reactor splash zone oxygen-containing gas inputs.

16. The three-stage energy-integrated product gas generation system (1001) according to claim 13, comprising:

at least three second reactor feed zone reactant inputs; and

at least three second reactor splash zone reactant inputs.

17. The three-stage energy-integrated product gas generation system (1001) according to claim 1, further comprising:

a second reactor solids output (207); and

a first reactor solids input (107) in fluid communication with the second reactor solids output (207), wherein;

the first reactor solids input (107) is configured to receive, into the first interior (101), second reactor particulate heat transfer material (205) present in the second interior (201).

18. The three-stage energy-integrated product gas generation system (1001) according to claim 1, wherein the first reactor further comprises:

a first reactor first heat exchanger (HX-A1) in thermal contact with the first interior (101), the first reactor first heat exchanger (HX-A1) comprising;

a first reactor first heat exchanger fuel inlet (112A) configured to receive a first reactor first heat exchanger fuel (110A) at a first inlet temperature (T3A); and

a first reactor first heat exchanger combustion stream outlet (116A) configured to output a first reactor first heat exchanger combustion stream (114A), at a first outlet temperature (T4A).

19. The three-stage energy-integrated product gas generation system (1001) according to claim 18, further comprising:

an auxiliary heat exchanger (HX-2) external to the first reactor (100) and in thermal contact with the first reactor first heat exchanger combustion stream (114A) exiting the first reactor first heat exchanger combustion stream outlet (116A);

wherein

the auxiliary heat exchanger (HX-2) is configured to transfer heat from the first reactor first heat exchanger combustion stream (114A) to an auxiliary heat exchanger heat transfer medium (164) which exits the auxiliary heat exchanger (HX-2) via auxiliary heat exchanger heat transfer medium outlet conduit (170).

20. The three-stage energy-integrated product gas generation system (1001) according to claim 19, wherein:

the auxiliary heat exchanger heat transfer medium outlet conduit (170) is in fluid communication with the second reactor heat transfer medium inlet (212), to thereby supply the auxiliary heat exchanger heat transfer medium (164) to the second reactor heat exchanger (HX-B).

21. The three-stage energy-integrated product gas generation system (1001) according to claim 19, wherein:

a portion of the third reactor heat transfer medium (310) is transferred from the outlet (316) of the third reactor heat exchanger (HX-C) to the inlet (166) of the auxiliary heat exchanger (HX-2) for use as the auxiliary heat exchanger heat transfer medium (164).

22. The three-stage energy-integrated product gas generation system (1001) according to claim 21, wherein a steam turbine (172) with an integrated generator (173) is configured to accept the third reactor transfer medium (310) discharged from the auxiliary heat exchanger (HX-2) to produce power (175).

23. The three-stage energy-integrated product gas generation system (1001) according to claim 18, wherein the first reactor comprises:

two first reactor heat exchangers (HX-A1, HX-A2) positioned in the first interior (101) and vertically spaced apart from one another along a height dimension of the first interior;

wherein;

alternate first reactor heat exchangers along said height dimension are arranged cross-wise to one another such that, in a top view of the first interior, the four first reactor heat exchangers define four open vertically extending quadrants (Q1, Q2, Q3, Q4).

24. The three-stage energy-integrated product gas generation system (1001) according to claim 23, comprising:

six first reactor carbonaceous material inputs (104A, 104B, 104C, 104D, 104E, 104F) to the first interior (101);

wherein;

only two of the six first reactor carbonaceous material inputs are configured to inject carbonaceous material into the vertically extending quadrants (Q1, Q2, Q3, Q4).

25. The three-stage energy-integrated product gas generation system (1001) according to claim 1, comprising:

at least two first reactors (100A, 100B) in fluid communication one common third reactor (300), each first reactor (100A, 100B) configured to produce a source of first reactor product gas (122A, 122B).

26. The three-stage energy-integrated product gas generation system (1001) according to claim 1, comprising:

at least two second reactors (200A, 200B) in fluid communication with one common third reactor (300);

each second reactor (200A, 200B) configured to produce a source of second reactor product gas (222A, 222B) which is supplied to the common third reactor.

27. The three-stage energy-integrated product gas generation system (1001) according to claim 1, wherein:

the third reactor (300) further comprises an annulus-type burner (346) at a top portion thereof;

the annulus-type burner (346) has annular port (320) configured to receive an oxygen-containing gas (318), and a central port (324) configured to receive a hydrocarbon stream (322); and

the annulus-type burner (346) further comprises a nozzle (347) through which a combustion stream (CZ-AP) is output into a reaction zone (CZ-B) of the third reactor (300).