Laminated lenses with anti-fogging functionality

• US 10,295,821 B2
• Filed: 08/17/2017
• Issued: 05/21/2019
• Est. Priority Date: 08/19/2016
• Status: Active Grant

• Current Assignee: Oakley, Inc. (EssilorLuxottica SA)
• Original Assignee: Oakley, Inc. (EssilorLuxottica SA)
• Inventors: McCabe, Brock Scott
• Primary Examiner(s): Dang, Hung X
• Application Number:
  US15/679,872
• Publication Number:
  US 20180052319A1
• Time in Patent Office: 642 Days
• Field of Search: 351 62, 35115962
• CPC Class Codes: A42B 3/245 using means for heating, e.g. electric heating of the visor
• CPC Class Codes: A61F 9/028 Ventilation means
• CPC Class Codes: A61F 9/029 Additional functions or features, e.g. protection for other parts of the face such as ears, nose or mouth; Screen wipers or cleaning devices
• CPC Class Codes: B29D 11/0073 Optical laminates
• CPC Class Codes: G02B 1/18 Coatings for keeping optical surfaces clean, e.g. hydrophobic or photo-catalytic films G02B1/16 takes precedence
• CPC Class Codes: G02B 27/0006 with means to keep optical surfaces clean, e.g. by preventing or removing dirt, stains, contamination, condensation G02B1/18 takes precedence; cleaning in general B08B
• CPC Class Codes: G02C 11/08 Anti-misting means, e.g. ventilating, heating H05B3/84 takes precedence; Wipers
• CPC Class Codes: G02C 2202/16 Laminated or compound lenses
• CPC Class Codes: G02C 7/02 Lenses; Lens systems ; Methods of designing lenses
• CPC Class Codes: G02C 7/101 having an electro-optical light valve electro-optical elements per se G02F
• CPC Class Codes: G02C 7/102 Photochromic filters
• CPC Class Codes: G02C 7/108 Colouring materials

Abstract

Eyewear can include a laminated lens that has anti-fogging functionality. The lens can include an anti-fog layer configured to resist accumulation of condensate on a posterior surface of the lens and an interface layer comprising a thin layer of inorganic material with ceramic bulk properties. The interface layer can be disposed between the anti-fog layer and an adhesive layer configured to adhere to adjacent layers of the laminated lens. The adhesive layer can be disposed between two lens elements. One of the lens elements can include a polymer layer that provides stiffness to the lens and an electrically conductive layer deposited on the polymer layer. When electric current is applied across the electrically conductive layer via one or more electrodes, the lens can be heated.

Claims

1. A lens for eyewear comprising:

an anti-fog layer configured to resist accumulation of condensate, wherein the anti-fog layer comprises a hydrophilic material, wherein the anti-fog layer is proximal to a wearer when the eyewear is worn;

an interface layer comprising an inorganic material with ceramic bulk properties; and

a lens component, wherein the interface layer is configured to facilitate attachment of the anti-fog layer to the lens component.

2. The lens of claim 1, wherein the hydrophilic material comprises cellulose acetate propionate.

3. The lens of claim 1, wherein the interface layer comprises silicon dioxide.

4. The lens of claim 1, wherein the lens component comprises a functional layer, wherein the functional layer comprises at least one of an electrically conductive layer, an electrochromic layer, a photochromic layer, a color filter, or a light attenuation filter.

5. The lens of claim 4, wherein the functional layer comprises an electrically conductive layer configured to conduct electric current when a power supply is electrically connected to the electrically conductive layer via one or more electrodes.

6. The lens of claim 5, wherein the electrically conductive layer comprises indium tin oxide.

7. The lens of claim 5, wherein the electrically conductive layer is disposed over a polymer layer configured to stiffen the lens.

8. The lens of claim 4, wherein the functional layer comprises an electrochromic layer.

9. The lens of claim 1, wherein the lens component comprises an adhesive layer disposed over the interface layer such that the interface layer is between the adhesive layer and the anti-fog layer, wherein the adhesive layer has a luminous transmittance greater than or equal to 50% using CIE Illuminant D65.

10. The lens of claim 1, wherein the lens component comprises one or more spacers configured to provide a gap between the interface layer and the lens component.

11. The lens of claim 10, wherein the gap comprises air, an inert gas or a getter.

12. The lens of claim 10, wherein the one or more spacers comprise an adhesive.

13. The lens of claim 1, further comprising a proximal lens element and a distal lens element spaced apart from the proximal lens element, the proximal lens element comprising the anti-fog layer, the interface layer, and the lens component.

14. Eyewear comprising a frame and the lens of claim 1 attached to the frame.

15. The eyewear of claim 14, wherein the eyewear is a goggle comprising:

a head strap configured to secure the goggle to a head of the wearer,

wherein the frame comprises a goggle frame comprising;

a central portion; and

a bridge disposed at the central portion, the bridge comprising a nosepiece section, and

wherein the goggle frame comprises one or more recesses adapted to hold the lens within a field of view of the wearer.

16. A helmet comprising the eyewear of claim 14, wherein the frame attaches to a base portion of the helmet, wherein the base portion is configured to absorb or distribute force from an impact, and wherein the eyewear is releasably attachable to the base portion.

17. The lens of claim 1, wherein the anti-fog layer has a thickness between 100 to 1000 μ

m, and wherein the interface layer has a thickness between 1 nm to 1000 nm.

18. A laminated anti-fog lens for eyewear comprising:

a first lens element comprising;

an anti-fog layer configured to resist accumulation of condensate on a proximal surface of the first lens element, wherein the anti-fog layer comprises a hydrophilic material, wherein the anti-fog layer is proximal to a wearer when the eyewear is worn, and wherein the anti-fog layer has a thickness of 100 μ

m to 1000 μ

m;

an interface layer having a thickness between 1 nm and 100 nm; and

a functional layer comprising an electrically conductive layer, the functional layer configured to conduct electric current when a power supply is electrically connected to the electrically conductive layer via one or more electrodes and generate Joule heating when electric current flows therethrough, wherein the interface layer is disposed between the anti-fog layer and the functional layer; and

a second lens element comprising a polymer layer, the second lens element spaced apart from the first lens element by a gap.

19. The lens of claim 18, wherein the hydrophilic material comprises cellulose acetate propionate.

20. The lens of claim 19, wherein the interface layer comprises silicon dioxide, and wherein at least a portion of the interface layer is in contact with at least a portion of the anti-fog layer.

21. The lens of claim 18, further comprising an adhesive layer between the interface layer and the functional layer, wherein the adhesive layer has a luminous transmittance greater than or equal to 50% using CIE Illuminant D65.

22. The lens of claim 18, wherein the gap comprises air or an inert gas.

23. The lens of claim 18, further comprising a second functional layer, the second functional layer comprising an electrochromic layer.

24. A lens for eyewear comprising:

a first lens element comprising;

an anti-fog layer configured to resist accumulation of condensate on a proximal surface of the first lens element; and

an interface layer comprising an inorganic material with ceramic bulk properties; and

an adhesive layer configured to adhere to adjacent layers of the lens, wherein the interface layer is disposed between the anti-fog layer and the adhesive layer.

25. The lens of claim 24, further comprising:

a second lens element comprising;

an electrically conductive layer configured to conduct electric current; and

a polymer layer configured to stiffen the lens;

wherein the adhesive layer is disposed between the first lens element and the second lens element.

26. The lens of claim 24, further comprising:

a second lens element comprising a functional layer, wherein the functional layer comprises at least one of an electrically conductive layer, an electrochromic layer, a photochromic layer, a color filter, or a light attenuation filter, and

wherein the adhesive layer is disposed between the first lens element and the second lens element.

27. The lens of claim 26, further comprising a proximal lens component and a distal lens component spaced apart from the proximal lens component by an insulating layer comprising a gas, wherein the proximal lens component comprises the first lens element, the second lens element, and the adhesive layer.

28. The lens of claim 24, wherein the anti-fog layer comprises cellulose acetate propionate.

29. The lens of claim 24, wherein the anti-fog layer has a thickness of 100 μ

m to 1000 μ

m, and wherein the interface layer has a thickness of 1 nm to 100 nm.

30. The lens of claim 24, wherein the interface layer comprises chalcogenide glass or mineral oxide glass.

31. The lens of claim 24, wherein the interface layer is a nanoscale composite comprising the inorganic material present in a matrix of organic material.

32. The lens of claim 24, wherein the adhesive layer comprises optically clear adhesive having a luminous transmittance greater than or equal to 50% using CIE Illuminant D65, wherein the adhesive layer has a thickness between 10 μ

m and 300 μ

m.

33. The lens of claim 24, wherein the adhesive layer covalently bonds to the first lens element and a second lens element.