Narrow pre-deposition laser deletion

• US 10,295,880 B2
• Filed: 12/23/2016
• Issued: 05/21/2019
• Est. Priority Date: 12/12/2011
• Status: Active Grant

• Current Assignee: View Incorporated
• Original Assignee: View Incorporated
• Inventors: Dixit, Abhishek Anant, Martin, Todd William, Pradhan, Anshu A.
• Primary Examiner(s): Jones, James C.
• Application Number:
  US15/390,421
• Publication Number:
  US 20170176831A1
• Time in Patent Office: 879 Days
• Field of Search: 359275
• CPC Class Codes: B32B 17/10119 having a composition deviating from the basic composition of soda-lime glass, e.g. borosilicate
• CPC Class Codes: B32B 17/10513 Electrochromic layer
• CPC Class Codes: B32B 17/1099 After-treatment of the layered product, e.g. cooling
• CPC Class Codes: B32B 37/14 characterised by the properties of the layers
• CPC Class Codes: B32B 38/10 Removing layers, or parts of layers, mechanically or chemically
• CPC Class Codes: B32B 38/105 on edges
• CPC Class Codes: G02F 1/1333 Constructional arrangements; Manufacturing methodsG02F1/135, G02F1/136 take precedence
• CPC Class Codes: G02F 1/133302 Rigid substrates, e.g. inorganic substrates
• CPC Class Codes: G02F 1/1524 Transition metal compounds
• CPC Class Codes: G02F 1/153 Constructional details
• CPC Class Codes: G02F 1/1533 structural features not otherwise provided for
• CPC Class Codes: G02F 1/155 Electrodes
• CPC Class Codes: G02F 2001/1536 additional, e.g. protective, layer inside the cell
• CPC Class Codes: G02F 2201/56 Substrates having a particular shape, e.g. non-rectangular
• CPC Class Codes: Y10T 156/1052 with cutting, punching, tearing or severing
• CPC Class Codes: Y10T 29/49126 Assembling bases

Abstract

Certain aspects pertain to methods of fabricating an optical device on a substantially transparent substrate that include a pre-deposition operation that removes a width of lower conductor layer at a distance from the outer edge of the substrate to form a pad at the outer edge. The pad and any deposited layers of the optical device may be removed in a post edge deletion operation.

Claims

1. A method of fabricating an optical device comprising one or more material layers sandwiched between a first and a second conductor layer, the method comprising:

receiving a substrate with the first conductor layer over its work surface;

(ii) removing a first width of the first conductor layer in a region along between about 50% and about 90% of the perimeter of the substrate while leaving a pad of the first conductor layer coextensive with the first width along the perimeter;

(iii) depositing said one or more material layers of the optical device and the second conductor layer over the work surface of the substrate; and

(iv) removing a second width of all the layers along substantially the entire perimeter of the substrate, wherein the depth of removal is at least sufficient to remove the first conductor layer, and wherein the second width of removal is sufficient to remove the pad and the remaining 10% to 50% of the first conductor layer along the perimeter of the substrate,

wherein at least one of the first and second conductor layers is transparent.

2. The method of claim 1, further comprising:

(v) removing a region of the one or more layers of the optical device and the second conductor layer revealing an exposed portion of the first conductor layer; and

(vi) applying a first bus bar to said an exposed portion of the first conductor layer.

3. The method of claim 1, wherein said one or more material layers of the optical device and the second conductor layer are deposited over substantially the entire work surface of the substrate due to the substrate being masked about the perimeter edge by a carrier holding mechanism.

4. The method of claim 1, wherein the first width is at a distance of between about 1 mm and about 10 mm from the outer edge of the substrate.

5. The method of claim 1, wherein the first width is at a distance of between about 1 mm and about 5 mm from the outer edge of the substrate.

6. The method of claim 1, wherein the first width is at a distance of about 10 mm from the outer edge of the substrate.

7. The method of claim 1, wherein the first width is between about 1 mm and about 5 mm.

8. The method of claim 1, wherein the first width is about 4 mm.

9. The method of claim 1, further comprising tapering the edge of the lower conductor layer.

10. The method of claim 2, further comprising applying a second bus bar to the second conductor layer.

11. The method of claim 10, further comprising incorporating the optical device into an insulated glass unit.

12. The method of claim 10, further comprising fabricating a laminate comprising the optical device and another substrate.

13. The method of claim 12, further comprising incorporating the laminate into an insulating glass unit.

14. The method of claim 10, wherein the second bus bar is applied to the second conductor layer on a portion that does not cover the first conductor layer.

15. The method of claim 10, further comprising fabricating at least one scribe line to isolate a portion of the optical device orthogonal to the first bus bar.

16. The method of claim 2, further comprising fabricating a scribe line to isolate a portion of the optical device between the first bus bar and an active region of the optical device.

17. The method of claim 10, further comprising:

fabricating at least one scribe line to isolate a portion of the optical device orthogonal the first bus bar; and

fabricating another scribe line to isolate a portion of the optical device between the first bus bar and an active region of the optical device.

18. The method of claim 10, wherein the depth of removal sufficient to remove at least the first conductor layer in (iv) is sufficient to remove the diffusion barrier, and wherein said second bus bar is applied to the second conductor layer on a portion that does not cover the first conductor layer or the diffusion barrier.

19. The method of claim 17, wherein the optical device is an all solid-state and inorganic electrochromic device.

20. The method of claim 15, wherein the substrate is float glass, tempered or untempered, and the first conductor layer comprises fluorinated tin oxide.

21. The method of claim 1, further comprising depositing a vapor barrier layer on the second conductor layer prior to (iv).

22. The method of claim 1, wherein the substrate is rectangular.

23. The method of claim 1, wherein (ii) comprises removing the first width of the first conductor layer from three sides about the perimeter of the substrate.

24. The method of claim 1, wherein the substrate is circular or oval.

25. The method of claim 23, wherein the substrate is a non-regular rectangle and the first width is removed from the two short sides and one long side of the non-regular rectangle.