Carbon dioxide fractionalization process

• US 10,316,260 B2
• Filed: 10/31/2016
• Issued: 06/11/2019
• Est. Priority Date: 01/10/2007
• Status: Active Grant

• Current Assignee: Pilot Intellectual Property LLC (Hero Technologies, Inc.)
• Original Assignee: Pilot Energy Solutions, L.L.C. (Hero Technologies, Inc.)
• Inventors: Prim, Eric
• Primary Examiner(s): Bhat, Nina
• Application Number:
  US15/339,610
• Publication Number:
  US 20170044449A1
• Time in Patent Office: 953 Days
• Field of Search: 585802, 208 92, 96108, 95214, 62621-624
• CPC Class Codes: B01D 3/146 Multiple effect distillation
• CPC Class Codes: C10G 21/00 Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents C10G17/00, C10G19/00 take precedence
• CPC Class Codes: C10G 21/06 characterised by the solvent used
• CPC Class Codes: C10G 21/16 Oxygen-containing compounds
• CPC Class Codes: C10G 21/28 Recovery of used solvent
• CPC Class Codes: C10G 31/00 Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for by distillation C10G7/00
• CPC Class Codes: C10G 7/02 Stabilising gasoline by removing gases by fractioning
• CPC Class Codes: C10G 70/045 using membranes, e.g. selective permeation
• CPC Class Codes: C10G 70/06 by gas-liquid contact
• CPC Class Codes: E21B 43/164 Injecting CO2 or carbonated water in combination with organic material C09K8/594
• CPC Class Codes: E21B 43/40 Separation associated with re-injection of separated materials E21B43/385 takes precedence

Abstract

A method comprises separating a hydrocarbon feed stream having carbon dioxide into a heavy hydrocarbon stream and a light hydrocarbon stream. The light hydrocarbon stream is separated into a carbon dioxide-rich stream and a carbon dioxide-lean stream. At least a portion of the carbon dioxide-lean stream is fed to a hydrocarbon sweetening process. Another method comprises receiving a hydrocarbon feed stream that comprises 30 molar percent to 80 molar percent carbon dioxide. A heavy hydrocarbon stream is separated from the hydrocarbon feed stream, wherein the heavy hydrocarbon stream comprises at least 90 molar percent C₃₊ hydrocarbons. A carbon dioxide-rich stream is separated from the hydrocarbon feed stream, wherein the carbon dioxide-rich stream comprises at least 95 molar percent carbon dioxide.

Claims

1. A process comprising:

receiving a hydrocarbon feed stream comprising carbon dioxide;

separating the hydrocarbon feed stream into a light hydrocarbon stream and a heavy hydrocarbon stream;

separating the light hydrocarbon stream into a carbon dioxide-rich stream and a carbon dioxide-lean stream;

heating the carbon dioxide-lean stream to produce a heated carbon dioxide-lean stream; and

feeding the heated carbon dioxide-lean stream into a hydrocarbon sweetening process, thereby increasing the processing capacity of the hydrocarbon sweetening process compared to the processing capacity of the hydrocarbon sweetening process when fed the hydrocarbon feed stream.

2. The process of claim 1, wherein the hydrocarbon sweetening process comprises:

absorbing at least some of the carbon dioxide from the heated carbon dioxide-lean stream with a solvent;

separating the solvent from the heated carbon dioxide-lean stream; and

releasing at least some of the carbon dioxide from the solvent by lowering the pressure of the solvent.

3. The process of claim 1, wherein the hydrocarbon sweetening process comprises separating at least some of the carbon dioxide from the heated carbon dioxide-lean stream using a membrane.

4. The process of claim 1, wherein the hydrocarbon sweetening process comprises:

absorbing at least some of the carbon dioxide from the heated carbon dioxide-lean stream with a solvent;

separating a methane-rich stream from the solvent;

separating an ethane-rich stream from the solvent; and

separating a heavy hydrocarbon stream from the solvent.

5. The process of claim 1, wherein the hydrocarbon feed stream contains from about 30 molar percent to about 80 molar percent carbon dioxide.

6. The process of claim 1, wherein the carbon dioxide-lean stream contains less than about 60 molar percent carbon dioxide and less than about 5 molar percent C₃₊.

7. The process of claim 1, wherein the carbon dioxide-lean stream contains at least about 95 molar percent of a combination of methane and carbon dioxide.

8. The process of claim 1, wherein the heavy hydrocarbon stream contains at least about 90 molar percent C₃₊.

9. The process of claim 1, wherein the carbon dioxide-rich stream contains at least about 95 molar percent carbon dioxide.

10. The process of claim 1, further comprising

transferring the carbon dioxide-rich stream to a pipeline for injection into a subterranean formation.

11. The process of claim 1, wherein the increase in processing capacity of the hydrocarbon sweetening process is directly proportional to the decrease in carbon dioxide concentration between the hydrocarbon feed stream and the heated carbon dioxide-lean stream, and the decrease in flow rate between the hydrocarbon feed stream and the heated carbon dioxide-lean stream.

12. An apparatus comprising:

a first separator that receives a hydrocarbon feed stream containing carbon dioxide and produces a heavy hydrocarbon stream and a light hydrocarbon stream;

a second separator that receives the light hydrocarbon stream and produces a carbon dioxide-rich stream and a carbon dioxide-lean stream;

a heat exchanger that heats the carbon dioxide-lean stream to produce a heated carbon dioxide-lean stream; and

a physical solvent process, a membrane process, or a carbon dioxide recovery process that receives the heated carbon dioxide-lean stream.

13. The apparatus of claim 12, wherein the first separator comprises:

a column that receives the hydrocarbon feed stream and produces the light hydrocarbon stream and the heavy hydrocarbon stream; and

a drum that receives the heavy hydrocarbon stream and produces an acid gas stream and a heavy hydrocarbon stream.

14. The apparatus of claim 12, wherein the first separator comprises:

a drum that receives the hydrocarbon feed stream and produces a light fraction and a heavy fraction;

a column that receives the heavy fraction and produces the light hydrocarbon stream and the heavy hydrocarbon stream, the light fraction being combined with the light hydrocarbon stream prior to the second separator.

15. The apparatus of claim 12, further comprising a second heat exchanger configured to use the carbon dioxide-lean stream to cool the light hydrocarbon stream.

16. The apparatus of claim 12, wherein the heat exchanger is configured to use the carbon dioxide-lean stream to cool the hydrocarbon feed stream.

17. A process comprising:

receiving a hydrocarbon feed stream comprising carbon dioxide;

cooling the hydrocarbon feed stream using a carbon dioxide-lean stream;

separating the cooled hydrocarbon feed stream into a light hydrocarbon stream and a heavy hydrocarbon stream;

compressing the light hydrocarbon stream;

cooling the compressed light hydrocarbon stream using the carbon dioxide-lean stream;

separating the compressed light hydrocarbon stream into a carbon dioxide-rich stream and the carbon dioxide-lean stream;

heating the carbon dioxide-lean stream to produce a heated carbon dioxide-lean stream; and

removing at least some of the carbon dioxide in the heated carbon dioxide-lean stream using a hydrocarbon sweetening process.

18. The process of claim 17, further comprising separating the heavy hydrocarbon stream into an acid gas stream and a heavy hydrocarbon stream.

19. The process of claim 17, wherein separating the cooled hydrocarbon feed stream into the light hydrocarbon stream and the heavy hydrocarbon stream comprises:

separating the cooled hydrocarbon feed stream into a light fraction and a heavy fraction;

separating the heavy fraction into the light hydrocarbon stream and the heavy hydrocarbon stream; and

combining the light fraction with the light hydrocarbon stream.

20. The process of claim 17, wherein the hydrocarbon sweetening process is a physical solvent process, a membrane process, or a carbon dioxide recovery process.