Wide operating temperature range electrophoretic device

• US 10,324,353 B2
• Filed: 10/16/2014
• Issued: 06/18/2019
• Est. Priority Date: 10/22/2013
• Status: Active Grant

• Current Assignee: E Ink Holdings Incorporated
• Original Assignee: Vlyte Innovations Limited, Vlyte Limited
• Inventors: O'Keeffe, Donal
• Primary Examiner(s): Beatty, Collin X
• Assistant Examiner(s): Gagnon, Grant A
• Application Number:
  US15/027,480
• Publication Number:
  US 20160246154A1
• Time in Patent Office: 1,706 Days
• Field of Search: 359296
• CPC Class Codes: E06B 2009/2464 featuring transparency control by applying voltage, e.g. LCD, electrochromic panels
• CPC Class Codes: E06B 9/24 Screens or other constructions affording protection against light, especially against sunshine; Similar screens for privacy or appearance; Slat blindsoperating, guiding or securing devices or arrangements for roll-type closures E06B9/56; free-hanging flexible screens A47H23/00
• CPC Class Codes: G02F 1/167 by electrophoresis
• CPC Class Codes: G02F 1/1675 Constructional details
• CPC Class Codes: G02F 2001/1678 characterised by the composition or particle type

Abstract

An electrophoretic device (101) comprises a first electrode (60) and a second electrode (60) spaced apart from the first electrode (60). An electrophoretic cell (809) containing an electrophoretic ink (830) and one or more optically-transparent, non-planar, solid polymer elements (808) is located between the electrodes (60). The ink (830) includes charged particles (11) of at least one type suspended in an optically-transparent suspending fluid (820). The refractive indices of the solid polymer elements (808) and the suspending fluid (820) are matched to have a difference of less than 0.0075, and for half or more of the operating temperature range of the device (0° C.-70° C.), the thermo-optic coefficients (temperature coefficient of refractive index per Kelvin) of the solid polymer elements (808) and the suspending fluid (820) are matched to have an arithmetic-mean difference of less than 0.0002/K in magnitude.

Claims

1. An electrophoretic device comprising a first electrode and a second electrode spaced apart from said first electrode, and between said electrodes an electrophoretic cell containing an electrophoretic ink and one or more optically-transparent, non-planar, solid polymer elements, said ink including charged particles of at least one type suspended in an optically-transparent suspending fluid, at a visible wavelength, the refractive indices of said solid polymer elements and said suspending fluid being matched to have a difference of less than 0.0075, and for half or more of the operating temperature range of said device spanning at least 30 degrees Celsius, the thermo-optic coefficients, the respective differential dn/dT of the refractive index n with respect to temperature T, of the solid polymer elements and the suspending fluid are matched to have an arithmetic-mean difference of less than 0.0002/K in magnitude.

2. An electrophoretic device according to claim 1 wherein the matched thermo-optic coefficients are both negative and have a magnitude greater than 2.25×

10⁴/K, and preferably greater than 3.0×

10<sup>−

4</sup>/K, and most preferably greater than 3.25×

10⁴/K.

3. An electrophoretic device according to claim 1 wherein said thermo-optic coefficients match has an arithmetic-mean difference of less than 0.000125/K in magnitude, and more preferably less than 0.0001/K, and most preferably less than 0.000075/K.

4. An electrophoretic device according to claim 1 wherein said operating temperature range spans from 0 degrees Celsius to 70 degrees Celsius, and more preferably, from −

10 degrees Celsius to 70 degrees Celsius, even more preferably from −

20 degrees Celsius to 85 degrees Celsius, and most preferably from −

40 degrees Celsius to 100 degrees Celsius.

5. An electrophoretic device according to claim 1 wherein said suspending fluid is a fluorosilicone or fluorosilicone containing copolymer having at least one pendant group containing a phenyl group, and said non-planar, solid polymer is a polysiloxane elastomer;

and, preferably said suspending fluid comprises more than 10% (by mole %) methyltrifluoropropylsiloxane, and preferably more than 20%, and most preferably more than 25%, and said solid polymer is polydimethylsiloxane.

6. An electrophoretic device according to claim 1 wherein said electrodes are transparent and coated onto a pair of film substrates and in use is an electro-active window mounted in an opening of a frame.

7. An electrophoretic device according to claim 1 wherein said non-planar, solid polymer element is an optically transparent elastomer and has a glass transition temperature, Tg, less than 20 degrees Celsius and has crosslinks.

8. An electrophoretic device according to claim 7 wherein a crosslink density of said elastomeric, solid polymer is selected so that said thermo-optic coefficient of said solid polymer closely matches that of said suspending fluid.

9. An electrophoretic device according to claim 7 wherein said non-planar, solid polymer element is viscoelastic for temperatures greater than said glass transition temperature;

and its Young'"'"'s Modulus, E, is less than 50 MPa and its hardness is less than 90 Shore A.

10. An electrophoretic device according to claim 7 wherein said optically transparent elastomeric, non-planar, solid polymer element has flexible linkages in its backbone and includes one or more of the following linkages:

ether (i.e. R—

O—

R′

), siloxane (i.e. Si—

O—

Si), fluoroether (i.e. CF₂—

O—

CF₂), thioether (i.e. R—

S—

R′

), methylene (i.e. CH₂), difluoromethylene (i.e. CF₂), or phosphazene (i.e. N═

P).

11. An electrophoretic device according to claim 1 wherein said charged particles are responsive to an electric field applied to said electrophoretic device to move between:

a first extreme light state in which particles are maximally spread within said cell to lie in the path of sunlight through the cell and to strongly attenuate light transmitted through the cell, and a second extreme light state in which said particles are maximally concentrated within the cell to remove them from the path of sunlight through the cell and to substantially transmit light through the cell to provide visual access there through.

12. An electrophoretic device according to claim 11 wherein said electrophoretic cell comprises said electrophoretic ink distributed in discrete or semi-discrete volumes, and said volumes of said electrophoretic ink form a monolayer that is adjacent one of said electrodes on one side and adjacent said non-planar polymer structure comprising a monolayer of close packed protrusions on the opposite side, and the protrusions project into the volumes and are in contact with the suspending fluid, and said charged particles move over a protrusion'"'"'s surface projecting into said volume in response to an applied electrical field to concentrate in the space between protrusions in said second light state.

13. An electrophoretic device according to claim 1 wherein said suspending fluid is silicone oil comprising 75% or more (by mole %) of one or more of the following polymer repeat units:

dimethylsiloxane, methylalkylsiloxane, or methylphenylsiloxane, and said solid polymer is a fluorosilicone or fluorosilicone containing copolymer or terpolymer comprising more than 10% (by mole %) a repeat unit either of the type;

fluoroalkylsiloxane including methyltrifluoropropylsiloxane (MTFPS), methylpentafluorobutylsiloxane, methylheptafluoropentylsiloxane, or methylnonafluorohexylsiloxane, or fluoroalkoxyalkylsiloxane, and preferably more than 20%, and most preferably more than 25%.

14. An electrophoretic device according to claim 13 wherein the dielectric constant of said solid polymer is greater than the dielectric constant of said suspending fluid.