Energy storage system using rare earth and hydroxyl co-doped ceramic in humid-environment
First Claim
Patent Images
1. An energy storage system, comprising:
- a hermetically-sealed casing having a volume defined within the casing wherein a relative humidity in said volume is a range of 30-90%; and
at least one energy storage capacitor disposed in said volume, each said energy storage capacitor having a solid dielectric sandwiched between two electrodes, wherein said solid dielectric is a lanthanum-doped barium titanate-based ceramic material, wherein a dopant of said lanthanum-doped barium titanate-based ceramic material is selected from the group consisting of lanthanum hydroxide and lanthanum oxide, and wherein said lanthanum-doped barium titanate-based ceramic material includes an alkali hydroxide co-dopant selected from the group consisting of potassium hydroxide, sodium hydroxide, rubidium hydroxide, and lithium hydroxide.
1 Assignment
0 Petitions
Accused Products
Abstract
An energy storage system includes a hermetically-sealed casing defining a volume whose relative humidity is a range of 30-90%. At least one energy storage capacitor disposed in the volume has a solid dielectric sandwiched between two electrodes with the solid dielectric being a lanthanum-doped barium titanate-based ceramic material.
-
Citations
17 Claims
-
1. An energy storage system, comprising:
-
a hermetically-sealed casing having a volume defined within the casing wherein a relative humidity in said volume is a range of 30-90%; and at least one energy storage capacitor disposed in said volume, each said energy storage capacitor having a solid dielectric sandwiched between two electrodes, wherein said solid dielectric is a lanthanum-doped barium titanate-based ceramic material, wherein a dopant of said lanthanum-doped barium titanate-based ceramic material is selected from the group consisting of lanthanum hydroxide and lanthanum oxide, and wherein said lanthanum-doped barium titanate-based ceramic material includes an alkali hydroxide co-dopant selected from the group consisting of potassium hydroxide, sodium hydroxide, rubidium hydroxide, and lithium hydroxide. - View Dependent Claims (2, 3, 4, 5)
-
-
6. An energy storage system, comprising:
-
a hermetically-sealed casing having a volume defined within the casing wherein a relative humidity in said volume is a range of 30-90%; and a stacked arrangement of a plurality energy storage capacitors disposed in said volume, each of said energy storage capacitors having a solid dielectric sandwiched between two electrodes, wherein said solid dielectric is a lanthanum-doped barium titanate-based ceramic material having a thickness in a range of 1-50 micrometers, wherein a dopant of said lanthanum-doped barium titanate-based ceramic material is selected from the group consisting of lanthanum hydroxide and lanthanum oxide, and wherein said lanthanum-doped barium titanate-based ceramic material includes an alkali hydroxide co-dopant selected from the group consisting of potassium hydroxide, sodium hydroxide, rubidium hydroxide, and lithium hydroxide. - View Dependent Claims (7, 8)
-
-
9. An energy storage system, comprising:
-
a hermetically-sealed casing having a volume defined within the casing wherein a relative humidity in said volume is a range of 30-90%; and at least one energy storage capacitor disposed in said volume, each said energy storage capacitor having a solid dielectric sandwiched between two electrodes, wherein said solid dielectric is a lanthanum-doped barium titanate-based ceramic material, wherein a dopant of said lanthanum-doped barium titanate-based ceramic material comprises lanthanum hydroxide, and wherein said lanthanum-doped barium titanate-based ceramic material includes an alkali hydroxide co-dopant selected from the group consisting of potassium hydroxide, sodium hydroxide, rubidium hydroxide, and lithium hydroxide, each said energy storage capacitor prepared by a process comprising the steps of providing particles of lanthanum hydroxide having an average grain diameter of 50-700 nanometers, particles of barium oxide having an average grain diameter of 50-700 nanometers, and particles of titanium dioxide having an average grain diameter of 50-700 nanometers, mixing 0.7-5.0 weight percent of said particles of lanthanum hydroxide, 60-65 weight percent of said particles of barium oxide, and a remaining weight percent of said particles of titanium dioxide, wherein a mixture of particles is generated, heating said mixture of particles to a temperature in a range of 1000−
1300°
C. wherein a sintered mixture is generated,milling said sintered mixture to generate milled particles having diameters of 50-700 nanometers, mixing 50-70 weight percent of said milled particles with 5-15 weight percent of glass particles having a particle size of 0.5-10 micrometers, 0.1-5.0 weight percent of an organic surfactant, 5-25 weight percent of a solvent, 5-25 weight percent of an organic vehicle, and 1-5 weight percent of said alkali hydroxide, wherein a liquid mixture is generated, providing a first electrode of said two electrodes, depositing a layer of said liquid mixture onto said first electrode, processing said first electrode with said layer thereon to remove liquid portions of said liquid mixture, wherein said step of processing includes a cycle of heating said layer to a temperature in a range of 850-900°
C. followed by a cycle of cooling said layer in a nitrogen atmosphere containing less than 25 parts per million of oxygen, andaffixing a second electrode of said two electrodes onto said layer after said liquid portions of said liquid mixture have been removed. - View Dependent Claims (10, 11, 12, 13, 14, 15, 16, 17)
-
Specification