Pre-vaporization formulation for controlling acidity in an e-vaping device

• US 10,327,472 B2
• Filed: 09/25/2015
• Issued: 06/25/2019
• Est. Priority Date: 09/25/2015
• Status: Active Grant

• Current Assignee: Altria Client Services LLC (Altria Group, Inc.)
• Original Assignee: Altria Client Services LLC (Altria Group, Inc.)
• Inventors: Li, San, Karles, Georgios, Kobal, Gerd, Li, Weiling, Secrist, Rebecca, Jarquin, Maria Del Carmen, Di Novi, Christopher, Pithawalla, Yezdi, Kane, David
• Primary Examiner(s): Felton, Michael J
• Assistant Examiner(s): Will, Katherine A
• Application Number:
  US14/865,813
• Publication Number:
  US 20170086500A1
• Time in Patent Office: 1,369 Days
• Field of Search: None
• CPC Class Codes: A24B 15/16 of tobacco substitutes
• CPC Class Codes: A24B 15/167 in liquid or vaporisable form, e.g. liquid compositions for electronic cigarettes
• CPC Class Codes: A24B 15/30 by organic substances A24B15/281 takes precedence
• CPC Class Codes: A24B 15/42 by organic and inorganic substances A24B15/281 takes precedence
• CPC Class Codes: A24F 40/10 Devices using liquid inhalable precursors
• CPC Class Codes: A24F 40/40 Constructional details, e.g. connection of cartridges and battery parts
• CPC Class Codes: A61K 9/007 Pulmonary tract; Aromatherapy

Abstract

A pre-vaporization formulation for an e-vaping device includes a vapor former, optionally water, nicotine, nicotine bitartrate and an acid. The pH of the pre-vaporization formulation is between about 4 and about 6. The acid can include one or more of pyruvic acid, formic acid, oxalic acid, glycolic acid, acetic acid, isovaleric acid, valeric acid, propionic acid, octanoic acid, lactic acid, sorbic acid, malic acid, tartaric acid, succinic acid, citric acid, benzoic acid, oleic acid, aconitic acid, butyric acid, cinnamic acid, decanoic acid, 3,7-diemthyl-6-octenoic acid, 1-glutamic acid, heptanoic acid, hexanoic acid, 3-hexenoic acid, trans-2-hexenoic acid, isobutyric acid, lauric acid, 2-methylbutyric acid, 2-methylvaleric acid, myristic acid, nonanoic acid, palmitic acid, 4-pentenoic acid, phenylacetic acid, 3-phenylpropionic acid, hydrochloric acid, phosphoric acid and sulfuric acid.

Claims

1. A pre-vaporization formulation of an e-vaping device, the pre-vaporization formulation comprising:

a vapor former;

nicotine;

nicotine bitartrate in a concentration of about 0.5% to about 2%; and

a combination of a plurality of acids;

wherein a pH of the pre-vaporization formulation is between about 4 and about 6, and

wherein the combination of the plurality of acids includes formic acid, oxalic acid, glycolic acid, acetic acid, isovaleric acid, valeric acid, propionic acid, octanoic acid, lactic acid, sorbic acid, malic acid, tartaric acid, succinic acid, citric acid, benzoic acid, oleic acid, aconitic acid, butyric acid, cinnamic acid, decanoic acid, 3,7-dimethyl-6-octenoic acid, 1-glutamic acid, heptanoic acid, hexanoic acid, 3-hexenoic acid, trans-2-hexenoic acid, isobutyric acid, lauric acid, 2-methylbutyric acid, 2-methvlvaleric acid, myristic acid, nonanoic acid, palmitic acid, 4-pentenoic acid, phenylacetic acid, 3-phenvlpropionic acid, hydrochloric acid, phosphoric acid and sulfuric acid.

2. The pre-vaporization formulation of claim 1, wherein the pH of the pre-vaporization formulation is between about 4.5 and 5.5.

3. The pre-vaporization formulation of claim 1, wherein the pH of the pre-vaporization formulation is about 5.

4. The pre-vaporization formulation of claim 1, wherein a concentration of the combination of a plurality of acids is between about 0.25% and about 2%.

5. The pre-vaporization formulation of claim 1, wherein the combination of acids includes equal parts of each of the tartaric acid and the acetic acid.

6. The pre-vaporization formulation of claim 1, wherein a concentration of the nicotine is between about 1.5% by weight and about 6% by weight.

7. The pre-vaporization formulation of claim 1, wherein a concentration of the nicotine bitartrate is between about 0.5% by weight and about 1.5% by weight.

8. The pre-vaporization formulation of claim 1, wherein the concentration of nicotine bitartrate is about 0.5% to 1% and wherein a concentration of a mixture of about equal parts tartaric acid and acetic acid is about 0.5% to 1%.

9. The pre-vaporization formulation of claim 1, wherein the concentration of nicotine bitartrate is about 0.5% to 1% and wherein a concentration of hydrochloric acid is about 0.01% to 0.1%.

10. The pre-vaporization formulation of claim 1, wherein a concentration of oleic acid is about 0.5% to 1% and a concentration of a mixture of about equal parts tartaric acid and acetic acid is about 0.5% to 1.5%.

11. The pre-vaporization formulation of claim 1, wherein a concentration of sorbic acid is about 0.1% to 0.5%, a concentration of tartaric acid is about 0.1% to 0.5%.

12. The pre-vaporization formulation of claim 1, wherein a concentration of succinic acid is about 0.1% to 0.5%, and a concentration of lactic acid is about 0.1% to 0.5%.

13. The pre-vaporization formulation of claim 1, wherein the combination of acids includes about 15% to 35% of each of the tartaric acid and the acetic acid.

14. The pre-vaporization formulation of claim 1, wherein the combination of acids includes about 10% to 40% of each of the tartaric acid and the acetic acid.

15. The pre-vaporization formulation of claim 1, wherein the combination of acids includes about 5% to 45% of each of the tartaric acid and the acetic acid.

16. The pre-vaporization formulation of claim 1, wherein the combination of acids includes less than about 50% of each of the tartaric acid and the acetic acid.

17. An e-vaping device, comprising:

a cartomizer including a reservoir holding a pre-vaporization formulation, a mouth piece and a heater configured to heat the pre-vaporization formulation; and

a power supply section removably connected to the cartomizer via a connector and including a sensor housed in a housing, a sensor holder holding the sensor, and a power source disposed in the power supply section and configured to supply power to the heater;

wherein the pre-vaporization formulation includes;

a vapor former;

nicotine;

nicotine bitartrate in a concentration of about 0.5% to about 2%; and

a combination of acids;

wherein a pH of the pre-vaporization formulation is between about 4 and about 6, and

wherein the combination of acids includes formic acid, oxalic acid, glycolic acid, acetic acid, isovaleric acid, valeric acid, propionic acid, octanoic acid, lactic acid, sorbic acid, malic acid, tartaric acid, succinic acid, citric acid, benzoic acid, oleic acid, aconitic acid, butyric acid, cinnamic acid, decanoic acid, 3,7-dimethyl-6-octenoic acid, 1-glutamic acid, heptanoic acid, hexanoic acid, 3-hexenoic acid, trans-2-hexenoic acid, isobutyric acid, lauric acid, 2-methylbutyric acid, 2-methylvaleric acid, myristic acid, nonanoic acid, palmitic acid, 4-pentenoic acid, phenylacetic acid, 3-phenylpropionic acid, hydrochloric acid, phosphoric acid and sulfuric acid.

18. The pre-vaporization formulation of claim 17, wherein the concentration of nicotine bitartrate is about 0.5% to 1%, and a concentration of a mixture of tartaric acid and acetic acid is about 0.5% to 1%.

19. The pre-vaporization formulation of claim 17, wherein the concentration of nicotine bitartrate is about 0.5% to 1%, and a concentration of hydrochloric acid is about 0.01% to 0.1%.

20. The pre-vaporization formulation of claim 17, wherein a concentration of oleic acid is about 0.5% to 1%, and a concentration of a mixture of tartaric acid and acetic acid is about 0.5% to 1.5.

21. The pre-vaporization formulation of claim 17, wherein a concentration of sorbic acid is about 0.1% to 0.5% and a concentration of tartaric acid is about 0.1% to 0.5%.

22. The pre-vaporization formulation of claim 17, wherein a concentration of succinic acid is about 0.1% to 0.5% and a concentration of lactic acid is about 0.1% to 0.5%.

23. A pre-vaporization formulation of an e-vaping device, the pre-vaporization formulation comprising:

a vapor former including of propylene glycol, glycerin, or both propylene glycol and glycerin;

nicotine at a concentration of about 6%;

nicotine salt at a concentration of about 0.5% to about 1%; and

a combination of acids including formic acid, oxalic acid, glycolic acid, acetic acid, isovaleric acid, valeric acid, propionic acid, octanoic acid, lactic acid, sorbic acid, malic acid, tartaric acid, succinic acid, citric acid, benzoic acid, oleic acid, aconitic acid, butyric acid, cinnamic acid, decanoic acid, 3,7-dimethyl-6-octenoic acid, 1-glutamic acid, heptanoic acid, hexanoic acid, 3-hexenoic acid, trans-2-hexenoic acid, isobutyric acid, lauric acid, 2-methylbutyric acid, 2-methylvaleric acid, myristic acid, nonanoic acid, palmitic acid, 4-pentenoic acid, phenylacetic acid, 3-phenylpropionic acid, hydrochloric acid, phosphoric acid and sulfuric acid;

wherein a pH of the pre-vaporization formulation is about 6.