Ammonia storage structure and associated systems

• US 10,329,158 B2
• Filed: 04/11/2014
• Issued: 06/25/2019
• Est. Priority Date: 04/12/2013
• Status: Active Grant

• Current Assignee: Aaqius & Aaqius Sa
• Original Assignee: Aaqius & Aaqius Sa
• Inventors: Dementhon, Jean-Baptiste
• Primary Examiner(s): Tran, Binh Q
• Application Number:
  US14/783,595
• Publication Number:
  US 20160185612A1
• Time in Patent Office: 1,901 Days
• Field of Search: 60274, 60286, 60295, 60297, 60301, 60303
• CPC Class Codes: B01D 2251/2062 Ammonia
• CPC Class Codes: B01D 2253/112 Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
• CPC Class Codes: B01D 2257/404 Nitrogen oxides other than dinitrogen oxide
• CPC Class Codes: B01D 2258/012 Diesel engines and lean burn gasoline engines
• CPC Class Codes: B01D 53/02 by adsorption, e.g. preparative gas chromatography solid sorbent compositions B01J20/00, preparation of inorganic compounds or elements C01
• CPC Class Codes: B01D 53/9431 Processes characterised by a specific device
• CPC Class Codes: B01J 20/046 containing halogens, e.g. halides
• CPC Class Codes: B01J 20/28026 Particles within, immobilised, dispersed, entrapped in or on a matrix, e.g. a resin
• CPC Class Codes: B01J 20/28042 Shaped bodies; Monolithic structures
• CPC Class Codes: B01J 20/2805 Sorbents inside a permeable or porous casing, e.g. inside a container, bag or membrane
• CPC Class Codes: B01J 20/28052 Several layers of identical or different sorbents stacked in a housing, e.g. in a column
• CPC Class Codes: B01J 20/3007 Moulding, shaping or extruding
• CPC Class Codes: B01J 20/3035 Compressing
• CPC Class Codes: C01C 1/006 making use of solid ammonia storage materials, e.g. complex ammine salts
• CPC Class Codes: F01N 2610/06 the substance being in the gaseous form
• CPC Class Codes: F01N 2610/1406 Storage means for substances, e.g. tanks or reservoirs
• CPC Class Codes: F01N 3/2066 Selective catalytic reduction [SCR]
• CPC Class Codes: F17C 11/00 Use of gas-solvents or gas-sorbents in vessels absorbing compositions for acetylene C10L3/04; absorbing compositions for hydrogen C01B3/0005
• CPC Class Codes: Y02A 50/20 Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Abstract

The disclosure relates to an ammonia storage structure in particular for the selective catalytic reduction of nitrogen oxides in the exhaust gases of combustion vehicles, where the structure includes at least one element for storing a gas such as ammonia, in the form of a porous matrix, with which an irrigating device the storage element are associated. The disclosure also relates to an ammonia storage and removal system of a vehicle that includes a storage chamber receiving such a storage structure, a selective catalytic reduction system for internal combustion engine exhaust gases, including such an ammonia storage system and to a module for feeding ammonia into the exhaust gases, and, finally, to a monolithic porous matrix for storing a gas, where the matrix contains the irrigation device in the interior thereof, in order to promote the sorption/desorption of the gas in the matrix.

Claims

1. A storage structure comprising at least one storage element of a gas in the form of a porous matrix, to which an irrigation network of the storage element is associated,

i) wherein the irrigation network comprises a main channel extending along an axis of a container receiving a stack of wafers held in position by a wall of the container, the wafer comprising storage elements alternating with intercalary elements, the intercalary elements comprising a star-shaped network of irrigation channels starting from a central opening taking part in the main channel, so that the intercalary elements form a secondary irrigation network starting from the main channel, to facilitate circulation of gas towards and from the storage elements, or

ii) wherein the irrigation network comprise a film located inside the storage structure and formed of two flexible porous membranes being deformable such that they are able to draw away from and draw close to each other within the limits of the deformability allowed by the storage structure,

wherein the space between the two membranes communicates with a main channel to input and output the gas to be stored,

wherein,

depending on the pressure values prevailing inside and outside the membrane respectively, the film assumes different states in which the membranes are drawn away from each other to a greater or lesser extent,

when the storage matrix is heated to deliver gas, the gas enters the space increasing the pressure therein, the membranes then drawing away from each other to facilitate the circulation of gas towards the main channel,

when filling, the gas pressure applied to the main channel causes the membranes to draw away from one another to facilitate irrigation of the gas towards the core of the storage matrix.

2. The structure according to claim 1, wherein at least part of the irrigation network is arranged inside the storage element.

3. The structure according to claim 1, wherein at least part of the irrigation network is arranged inside an irrigation element adjacent the storage element.

4. The structure according to claim 1, wherein the irrigation network comprises one or more channels essentially devoid of porous material.

5. The structure according to claim 4, wherein the channels comprise tubes having a wall provided with orifices and wherein the channels comprise tubes having a porous wall.

6. The structure according to claim 1, wherein the irrigation network comprises one or more channels formed in a porous matrix and defined by regions of the porous matrix having greater porosity than the remainder of the matrix.

7. The structure according to claim 6, wherein the porous matrix in which the channel(s) are formed is the matrix of the storage element, and wherein the porous matrix in which the channel(s) are formed is the matrix of an intercalary element between two storage elements.

8. The structure according to claim 6, wherein the porous matrix in which the channel(s) are formed is rigid, or wherein the porous matrix in which the channel(s) are formed is in powder form.

9. The structure according to claim 1, wherein the irrigation network comprises at least two channels according to a ramified arrangement.

10. The structure according to claim 1, wherein the irrigation network comprises a film formed by two porous membranes and delimiting a space therebetween.

11. The structure according to claim 1, wherein the irrigation network comprises at least one flexible membrane forming a flexible duct.

12. The structure according to claim 1, wherein the irrigation network comprises two plates provided with orifices and spaced apart, intercalated between two gas storage elements.

13. The storage structure of claim 12, wherein the two plates delimit an intercalary space free of solid material, each plate being provided with a series of holes ensuring communication between the space and the porous storage matrix formed by the storage elements.

14. The storage structure of claim 13, wherein the plates are held in position by crimping on a duct forming a main channel.

15. The structure according to claim 1, wherein the irrigation network extends from a main channel passing through the gas storage element(s).

16. A construction module of the structure according to claim 1, the module comprising the irrigation network configured to be connected to the irrigation network of at least one other module to form the storage structure.

17. A storage and delivery system for vehicles, comprising the at least one storage element which comprises the storage structure according to claim 1.

18. A selective catalytic reduction system for the exhaust gases of an internal combustion engine, wherein it comprises the ammonia storage system according to claim 17 and an injection module to inject the ammonia into the exhaust gases.

19. The storage structure according to claim 1, for selective catalytic reduction of nitrogen oxides in exhaust gases of combustion structure vehicles.

20. The storage structure of claim 1, wherein the gas is ammonia gas.

21. The storage structure according to claim 1, wherein at least part of the irrigation network is arranged inside an irrigation element adjacent the storage element.

22. The storage structure of claim 1, wherein the irrigation network comprises a series of ducts and cross-shaped junction elements, so that the ducts cross over one another at the cross-shaped junction elements.

23. The storage structure of claim 1, wherein the irrigation channels are connected to other channels via cross-shaped connection elements.

24. The storage structure of claim 1, wherein the storage structure comprises a stack of gas storage elements, wherein the gas storage elements are directly separated by films with intercalary membranes, each film comprising two porous membranes freely movable in relation to one another within the limits allowed by the over and underlying storage elements, an inner space thus formed communicating with a main channel for the input and output of gas.

25. The storage structure of claim 1, wherein the irrigation network comprises at least one flexible, porous membrane located inside the storage structure, the flexible membrane forming a flexible duct, the flexible membrane delimiting an inner space forming a channel, the flexible membrane having a cylindrical shape,

wherein the flexible membrane is deformable along its longitudinal and/or radial dimension that can be increased or decreased by the volume of the inner space within the limits of deformability allowed by the storage structure.

26. The structure of claim 25, wherein the flexible membrane comprises a thin metal felt or woven material, having a mesh size allowing the passing of gas and being sufficiently narrow to prevent the passing of a powder particle used to form the storage material of the storage structure.

27. The storage structure of claim 1, wherein said structure is in the form of juxtaposed modules stacked edge to edge,

each module comprising an irrigation network configured to be connected to an irrigation network of at least one other module so as to form a storage structure, the irrigation network of each module securing the module to at least one other module.

28. A method for manufacturing a module comprising:

compressing a powder inside a mould, to form a coherent block; and

forming a network of irrigation channels inside the coherent block to obtain the module, the module comprising at least one storage element of a gas in the form of a porous matrix,

i) wherein the network of irrigation channels comprises a main channel extending along an axis of a container receiving a stack of wafers held in position by a wall of the container, the wafer comprising storage elements alternating with intercalary elements, the intercalary elements comprising a star-shaped network of irrigation channels starting from a central opening taking part in the main channel, so that the intercalary elements form a secondary irrigation network starting from the main channel, to facilitate circulation of gas towards and from the storage elements, or

ii) wherein the network of irrigation channels comprises a film located inside the module and formed of two flexible porous membranes being deformable such that they are able to draw away from and draw close to each other within the limits of the deformability allowed by the module,

wherein the space between the two membranes communicates with a main channel to input and output the gas to be stored,

wherein,

depending on the pressure values prevailing inside and outside the membrane respectively, the film assumes different states in which the membranes are drawn away from each other to a greater or lesser extent,

when the storage matrix is heated to deliver gas, the gas enters the space increasing the pressure therein, the membranes then drawing away from each other to facilitate the circulation of gas towards the main channel,

when filling, the gas pressure applied to the main channel causes the membranes to draw away from one another to facilitate irrigation of the gas towards the core of the storage matrix.

29. A monolithic porous matrix to store gas including irrigation means to promote the sorption/desorption of the gas within the matrix, wherein said porous matrix includes at least one storage element of a gas in the form of said porous matrix

i) wherein the irrigation means comprises a main channel extending along an axis of a container receiving a stack of wafers held in position by a wall of the container, the wafer comprising storage elements alternating with intercalary elements, the intercalary elements comprising a star-shaped network of irrigation channels starting from a central opening taking part in the main channel, so that the intercalary elements form a secondary irrigation network starting from the main channel, to facilitate circulation of gas towards and from the storage elements, or

ii) wherein the irrigation means comprise a film located inside the porous matrix and formed of two flexible porous membranes being deformable such that they are able to draw away from and draw close to each other within the limits of the deformability allowed by the porous matrix,

wherein the space between the two membranes communicates with a main channel to input and output the gas to be stored,

wherein,

depending on the pressure values prevailing inside and outside the membrane respectively, the film assumes different states in which the membranes are drawn away from each other to a greater or lesser extent,

when the storage matrix is heated to deliver gas, the gas enters the space increasing the pressure therein, the membranes then drawing away from each other to facilitate the circulation of gas towards the main channel,

when filling, the gas pressure applied to the main channel causes the membranes to draw away from one another to facilitate irrigation of the gas towards the core of the storage matrix.