Damping thermoplastic elastomers

• US 10,329,419 B2
• Filed: 02/10/2016
• Issued: 06/25/2019
• Est. Priority Date: 02/11/2015
• Status: Active Grant

• Current Assignee: Avient Corp.
• Original Assignee: Polyone Corporation (Avient Corp.)
• Inventors: Gu, Jiren
• Primary Examiner(s): Huhn, Richard A
• Application Number:
  US15/550,343
• Publication Number:
  US 20180022915A1
• Time in Patent Office: 1,231 Days
• Field of Search: None
• CPC Class Codes: B29L 2031/721 Vibration dampening equipment, e.g. shock absorbers bumpers B29L2031/3044, springs B29L2031/774
• CPC Class Codes: C08F 297/04 polymerising vinyl aromatic monomers and conjugated dienes
• CPC Class Codes: C08G 2350/00 Acoustic or vibration damping material
• CPC Class Codes: C08K 3/00 Use of inorganic substances as compounding ingredients
• CPC Class Codes: C08K 5/00 Use of organic ingredients
• CPC Class Codes: C08K 5/01 Hydrocarbons C08K5/0091 takes precedence
• CPC Class Codes: C08L 101/00 Compositions of unspecified macromolecular compounds
• CPC Class Codes: C08L 2205/02 containing two or more polymers of the same C08L -group
• CPC Class Codes: C08L 2205/03 containing three or more polymers in a blend
• CPC Class Codes: C08L 23/06 Polyethene
• CPC Class Codes: C08L 25/00 Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 53/02 of vinyl-aromatic monomers and conjugated dienes
• CPC Class Codes: C08L 53/025 modified
• CPC Class Codes: C08L 71/12 Polyphenylene oxides
• CPC Class Codes: G10K 11/162 Selection of materials

Abstract

A thermoplastic elastomer compound includes styrenic block copolymer that is high vinyl styrene-(ethylene/butylene)-styrene block copolymer and high softening point tackifier. The high vinyl styrene-(ethylene/butylene)-styrene block copolymer has a Copolymer Tan Delta Peak Temperature and the thermoplastic elastomer compound has a Compound Tan Delta Peak Temperature. The Compound Tan Delta Peak Temperature is greater than the Copolymer Tan Delta Peak Temperature. The thermoplastic elastomer compound exhibits useful damping properties at or above room temperature while also advantageously possessing improved stability for processing and/or applications at high temperatures and upon exposure to weathering.

Claims

1. A thermoplastic elastomer compound comprising:

(a) high vinyl styrene-(ethylene/butylene)-styrene block copolymer having a Copolymer Tan Delta Peak Temperature; and

(b) tackifier having a softening point of at least about 80°

C. according to ASTM 6493; and

wherein the compound has a Compound Tan Delta Peak Temperature, and the Compound Tan Delta Peak Temperature is greater than the Copolymer Tan Delta Peak Temperature.

2. The compound of claim 1, wherein the compound is essentially free of styrene-(ethylene-ethylene/propylene)-styrene block copolymer and low vinyl styrene-(ethylene/butylene)-styrene block copolymer.

3. The compound of claim 1, wherein the compound is essentially free of hydrogenated styrene-isoprene-styrene block copolymer with hydrogenated vinylic isoprene midblock.

4. The compound of claim 1, wherein the Copolymer Tan Delta Peak Temperature is greater than −

40°

C. but less than −

10°

C.

5. The compound of claim 1, wherein the Compound Tan Delta Peak Temperature is at least −

10°

C.

6. The compound of claim 1, wherein the tackifier has a softening point ranging from about 80°

C. to about 150°

C. according to ASTM 6493.

7. The compound of claim 1, wherein the tackifier has a weight average molecular weight ranging from about 400 to about 3,500.

8. The compound of claim 1, wherein the tackifier comprises a saturated cyclo-aliphatic amorphous hydrocarbon resin.

9. The compound of claim 1, wherein the tackifier is present in an amount ranging from about 20 parts by weight to about 200 parts by weight, per 100 parts by weight of the styrenic block copolymer.

10. The compound of claim 1, wherein the compound further comprises plasticizer.

11. The compound of claim 1, wherein the compound further comprises secondary polymer.

12. The compound of claim 1, wherein the compound further comprises filler.

13. The compound of claim 1, wherein the compound further comprises at least one additive selected from the group consisting of adhesion promoters;

biocides;

anti-fogging agents;

anti-static agents;

blowing and foaming agents;

bonding agents and bonding polymers;

dispersants;

flame retardants and smoke suppressants;

impact modifiers;

initiators;

lubricants;

micas;

pigments, colorants and dyes;

processing aids;

release agents;

silanes, titanates and zirconates;

slip and anti-blocking agents;

stabilizers;

stearates;

ultraviolet light absorbers;

viscosity regulators;

waxes; and

combinations of any of the aforementioned additives.

14. The compound of claim 1, wherein the compound comprises:

(a) 100 parts by weight of the styrenic block copolymer;

(b) from about 20 to about 200 parts by weight of the tackifier;

(c) from 0 to about 200 parts by weight of optional plasticizer;

(d) from 0 to about 300 parts by weight of optional secondary polymer;

(e) from 0 to about 150 parts by weight of optional filler; and

(f) from 0 to about 100 parts by weight of optional other additives.

15. A plastic article formed from the compound of claim 1.