System and method for retrofitting a refrigeration system from HCFC to HFC refrigerant

• US 10,330,364 B2
• Filed: 06/19/2015
• Issued: 06/25/2019
• Est. Priority Date: 06/26/2014
• Status: Active Grant

• Current Assignee: Hudson Technologies, Inc.
• Original Assignee: Hudson Technologies, Inc.
• Inventors: Harkins, Charles
• Primary Examiner(s): Jules, Frantz F
• Assistant Examiner(s): Tadesse, Martha
• Application Number:
  US14/744,776
• Publication Number:
  US 20150377533A1
• Time in Patent Office: 1,467 Days
• CPC Class Codes: C09K 2205/104 Carboxylic acid esters
• CPC Class Codes: C09K 2205/122 Halogenated hydrocarbons
• CPC Class Codes: C09K 2205/22 All components of a mixture being fluoro compounds
• CPC Class Codes: C09K 2205/40 Replacement mixtures
• CPC Class Codes: C09K 2205/43 Type R22
• CPC Class Codes: C09K 5/045 containing only fluorine as halogen
• CPC Class Codes: C10M 105/38 of polyhydroxy compounds
• CPC Class Codes: C10M 171/008 Lubricant compositions compatible with refrigerants
• CPC Class Codes: C10M 2207/2835 used as base material
• CPC Class Codes: C10N 2020/101 Containing Hydrofluorocarbons
• CPC Class Codes: C10N 2020/103 Containing Hydrocarbons
• CPC Class Codes: C10N 2040/30 Refrigerators lubricants or compressors lubricants
• CPC Class Codes: F25B 2345/001 Charging refrigerant to a cycle
• CPC Class Codes: F25B 2345/007 characterised by the weighing of refrigerant or oil
• CPC Class Codes: F25B 31/002 Lubrication
• CPC Class Codes: F25B 45/00 Arrangements for charging or discharging refrigerant

Abstract

A system and method for retrofitting a refrigeration system containing an HCFC refrigerant and a compatible lubricant, with an HFC refrigerant, comprising providing a transport container containing a mixture of a miscible lubricant and the HFC refrigerant, removing the HCFC refrigerant from the refrigeration system while maintaining at least a portion of a lubricant immiscible with the HFC refrigerant, and charging the refrigeration system with the mixture. The polyol ester lubricant may be present in a range exceeding about 5-15% by weight, e.g., 8%.

Claims

1. A method for retrofitting a refrigeration system from an HCFC refrigerant compatible with a mineral oil or alkyl benzene lubricant to an HFC refrigerant compatible with a polyol ester lubricant, comprising:

evacuating the HCFC from the refrigeration system, leaving at least a portion of the mineral oil or alkyl benzene lubricant; and

charging the refrigeration system with a composition comprising the HFC refrigerant mixed with a polyol ester lubricant,

thereby resulting in a refrigeration system charged with the HFC and a mixed lubricant comprising both the mineral oil or alkyl benzene lubricant and the polyol ester lubricant.

2. The method according to claim 1,

wherein the refrigeration system comprises a hermetically sealed refrigeration system, further comprising:

providing a transport container containing the HFC refrigerant mixed with the polyol ester lubricant; and

said evacuating comprises withdrawing the HCFC from within the refrigeration system through a charge-discharge port, leaving at least a portion of the mineral oil or alkyl benzene lubricant.

3. The method according to claim 1, wherein the mineral oil or alkyl benzene lubricant is a mineral oil lubricant.

4. The method according to claim 1, wherein the HCFC comprises R-22, and the HFC comprises R-407C.

5. The method according to claim 1, wherein the polyol ester is provided in an amount of 5% to 15% by weight.

6. The method according to claim 1, wherein the polyol ester is provided in an amount of 8% by weight.

7. The method according to claim 1, wherein the refrigeration system after recharging has a concentration of 15-32% by weight mixed lubricant.

8. The method according to claim 1, wherein the transport container is U.S. Department of Transportation compliant.

9. The method according to claim 1, wherein the transport container is compliant at least one of U.S. Department of Transportation standards DOT-39, DOT 3, DOT 3A, DOT 3AA, DOT 3AL, DOT 3B, DOT 3BN, DOT 3E, DOT 4B, DOT 4BA, DOT 4B240ET, DOT 4BW, DOT 4E, DOT 3AL1800;

DOT 4D;

DOT-3A1000;

DOT-3A1200;

DOT-3A150;

DOT-3A1800;

DOT-3A2000;

DOT-3A225;

DOT-3A240;

DOT-3A2400;

DOT-3A300;

DOT-3A400;

DOT-3A480;

DOT-3A480X;

DOT-3AA;

DOT-3AA1000;

DOT-3AA1200;

DOT-3AA150;

DOT-3AA1800;

DOT-3AA2000;

DOT-3AA225;

DOT-3AA240;

DOT-3AA2400;

DOT-3AA300;

DOT-3AA400;

DOT-3AA480;

DOT-3AAX1800;

DOT-3AAX2000;

DOT-3AAX2200;

DOT-3AAX2400;

DOT-3AL;

DOT-3AL1000;

DOT-3AL150;

DOT-3AL1800;

DOT-3AL2000;

DOT-3AL225;

DOT-3AL240;

DOT-3AL2400;

DOT-3AL400;

DOT-3AL480;

DOT-3AX1800;

DOT-3AX2000;

DOT-3AX2200;

DOT-3AX2400;

DOT-3B;

DOT-3B150;

DOT-3B1800;

DOT-3B225;

DOT-3B240;

DOT-3B300;

DOT-3B400;

DOT-3BN400;

DOT-3BN480;

DOT-3E1800;

DOT-3HT;

DOT-3HT2000;

DOT-3T1800;

DOT-3T2000;

DOT-3T2200;

DOT-3T2400;

DOT-4A;

DOT-4AA480;

DOT-4B;

DOT-4B150;

DOT-4B150;

DOT-4B225;

DOT-4B240;

DOT-4B240ET;

DOT-4B300;

DOT-4B400;

DOT-4B480;

DOT-4BA;

DOT-4BA225;

DOT-4BA240;

DOT-4BA300;

DOT-4BA400;

DOT-4BW225;

DOT-4BW240;

DOT-4BW300;

DOT-4BW400;

DOT-4BW480;

DOT-4DA;

DOT-4DS;

DOT-4E225;

DOT-4E240;

DOT-4L;

DOT-AAX2400; and

ICC-3E1800.

10. The method according to claim 1, wherein the HFC refrigerant is a blend of difluoromethane (R-32), pentafluoroethane (R-125), and 1,1,1,2-tetrafluoroethane (R-134a).

11. The method according to claim 10, wherein the HFC is R-407C, and the polyol ester lubricant is premixed with the HFC refrigerant in an amount of 8% by weight.

12. The method according to claim 10, wherein the system after charging has a concentration of 20-25% by weight lubricant mixture.

13. The method according to claim 10, wherein the HFC refrigerant mixed with the polyol ester lubricant is provided in a U.S. Department of Transportation compliant transport container having a capacity of 50 pounds or lower.

14. A method for retrofitting an HCFC refrigeration system having a mineral oil or alkyl benzene lubricant, which persists as a residual after removal of the HCFC from the refrigeration system by evacuation, to an HFC refrigerant which is not compatible with the HFC refrigerant as a sole lubricant, comprising:

providing a container adapted for common carrier transport, containing a composition comprising an HFC refrigerant mixed with a compatible polyol ester lubricant;

evacuating the HCFC from the refrigeration system, leaving at least a portion of the mineral oil or alkyl benzene lubricant within the refrigeration system; and

charging the refrigeration system with the composition from the container, comprising the HFC refrigerant mixed with the compatible polyol ester lubricant,

to thereby provide the refrigeration system charged with the HFC and a combination of the mineral oil or alkyl benzene lubricant and the HFC refrigerant.

15. The method according to claim 14, wherein:

the HCFC comprises R-22;

the container comprises a U.S. Department of Transportation certified transport container; and

the HFC is R-407C.

16. The method according to claim 14, wherein the polyol ester lubricant is present in the container an amount of 5% to 15% by weight and the HFC refrigerant is present in an amount of 95-85% by weight.

17. The method according to claim 14, wherein the polyol ester lubricant is present in the container an amount of 8% by weight and the HFC refrigerant is present in an amount of 92% by weight.

18. The method according to claim 14, wherein the HFC is selected from the group consisting of R-134a, R-404A, R-407A, R-407C, R-407F, R-410A, R-417A, R-417B, R-422A, R-422B, R-422C, R-422D, R-424A, R-427A, R-428A, R-434A, R-438A, R-442A, and RS07A.

19. The method according to claim 14, wherein the transport container is DOT-39 compliant.

20. A method for retrofitting a refrigeration system from an HCFC refrigerant compatible with a mineral oil or alkyl benzene lubricant to 407C premixed with a compatible polyol ester lubricant in an amount of between 5%-20% by weight of the refrigerant, comprising:

providing a mixture of the 407C premixed with the compatible polyol ester lubricant to the refrigeration system in a U.S. Department of Transportation compliant transport container having a capacity of 50 pounds or lower;

evacuating the HCFC from the refrigeration system through a charge-discharge port of the refrigeration system, without draining the mineral oil or alkyl benzene lubricant, and leaving at least a portion of the mineral oil or alkyl benzene lubricant in the refrigeration system; and

charging the refrigeration system with the mixture from the container of the 407C premixed with the compatible polyol ester lubricant,

thereby resulting in the refrigeration system charged with the 407C and a mixed lubricant comprising both the mineral oil or alkyl benzene lubricant and the compatible polyol ester lubricant, wherein the mixed lubricant is present in the refrigeration system in an amount of 16% to 32% by weight of the refrigerant charge, and the compatible polyol ester lubricant is present in the refrigeration system an amount of 25% to 50% by weight of the mixed lubricant.