Multi-frequency excitation schemes for high sensitivity magnetometry measurement with drift error compensation

• US 10,338,163 B2
• Filed: 07/11/2016
• Issued: 07/02/2019
• Est. Priority Date: 07/11/2016
• Status: Active Grant

• Current Assignee: Lockheed Martin Corporation (Martin Marietta Corporation)
• Original Assignee: Lockheed Martin Corporation (Martin Marietta Corporation)
• Inventors: Kaup, Peter G., Manickam, Arul, Bruce, Gregory Scott
• Primary Examiner(s): Natalini, Jeff W
• Assistant Examiner(s): Yeninas, Steven L
• Application Number:
  US15/207,457
• Publication Number:
  US 20180011151A1
• Time in Patent Office: 1,086 Days
• Field of Search: 324202, 324244, 3242441, 324260, 324304, 324305
• CPC Class Codes: G01N 24/12 by using double resonance
• CPC Class Codes: G01R 33/26 using optical pumping
• CPC Class Codes: G01R 33/323 Detection of MR without the use of RF or microwaves, e.g. force-detected MR, thermally detected MR, MR detection via electrical conductivity, optically detected MR

Abstract

A system for magnetic detection includes a nitrogen vacancy (NV) diamond material, a radio frequency (RF) excitation source that provides RF excitation to the NV diamond material, an optical excitation source that provides optical excitation to the NV diamond material, an optical detector that receives an optical signal emitted by the NV diamond material, a magnetic field generator that generates a magnetic field applied to the NV diamond material, and a controller. The controller controls the RF excitation source to apply a first RF excitation having a first frequency and a second RF excitation having a second frequency. The first frequency is associated with a first slope point of a fluorescence intensity response of an NV center orientation of a first spin state, and the second frequency is associated with a second slope point of the fluorescence intensity response of the NV center orientation of the first spin state.

Claims

1. A system for magnetic detection, comprising:

a magneto-optical defect center material comprising a plurality of magneto-optical defect centers;

a radio frequency (RF) excitation source configured to provide RF excitation to the magneto-optical defect center material;

an optical excitation source configured to provide optical excitation to the magneto-optical defect center material;

an optical detector configured to receive an optical signal emitted by the magneto-optical defect center material;

a magnetic field generator configured to generate a magnetic field applied to the magneto-optical defect center material; and

a controller configured to;

control the optical excitation source to apply optical excitation to the magneto-optical defect center material;

control the RF excitation source to apply a first RF excitation to the magneto-optical defect center material, the first RF excitation having a first frequency;

control the RF excitation source to apply a second RF excitation to the magneto-optical defect center material, the second RF excitation having a second frequency,

wherein the first frequency is a frequency associated with a first slope point of a fluorescence intensity response of a magneto-optical defect center orientation of a first spin state due to the optical excitation, the first slope point being a positive slope point, and

wherein the second frequency is a frequency associated with a second slope point of the fluorescence intensity response of the magneto-optical defect center orientation of the first spin state due to the optical excitation, the second slope point being a negative slope point;

measure a first fluorescence intensity at the positive slope point;

measure a second fluorescence intensity at the negative slope point; and

calculate a compensated fluorescence intensity based on the measured first fluorescence intensity and the measured second fluorescence intensity.

2. The system of claim 1, wherein the controller is configured to control the RF excitation source to alternately apply the first RF excitation as a single RF pulse and apply the second RF excitation as a single RF pulse.

3. The system of claim 1, wherein the controller is configured to control the RF excitation source to alternately apply the first RF excitation as two or more RF pulses in sequence and apply the second RF excitation as two or more RF pulses in sequence.

4. The system of claim 3, wherein the controller is configured to measure the first fluorescence intensity based on an average of a fluorescence intensity associated with each of the two or more RF pulses of the first RF excitation and measure the second fluorescence intensity based on an average of a fluorescence intensity associated with each of the two or more RF pulses of the second RF excitation.

5. The system of claim 1, wherein the controller is further configured to:

control the RF excitation source to alternately apply the first RF excitation as three or more RF pulses in sequence and apply the second RF excitation as three or more RF pulses in sequence;

measure the first fluorescence intensity based on an average of a fluorescence intensity associated with each of two or more RF pulses of the three or more RF pulses of the first RF excitation; and

measure the second fluorescence intensity based on an average of a fluorescence intensity associated with each of two or more RF pulses of the three or more RF pulses of the second RF excitation.

6. The system of claim 5, wherein the two or more RF pulses of the first RF excitation are applied last in the sequence of the three or more pulses, and wherein the two or more RF pulses of the second RF excitation are applied last in the sequence of the three or more pulses.

7. The system of claim 1, wherein the positive slope point is a maximum positive slope point of the fluorescence intensity response of the magneto-optical defect center orientation of the first spin state and the negative slope point is a maximum negative slope point of the fluorescence intensity response of the magneto-optical defect center orientation of the first spin state.

8. The system of claim 1, wherein the positive slope point and the negative slope point are set as an average of a maximum positive slope point and a maximum negative slope point of the fluorescence intensity response of the magneto-optical defect center orientation of the first spin state due to the optical excitation.

9. The system of claim 1, wherein the controller is further configured to:

calculate the compensated fluorescence intensity based on a difference between the measured first fluorescence intensity and the measured second fluorescence intensity divided by a difference between the slope of the positive slope point and the slope of the negative slope point.

10. The system of claim 1, wherein the controller is further configured to:

control the RF excitation source to apply a third RF excitation to the magneto-optical defect center material, the third RF excitation having a third frequency,

wherein the third frequency is a frequency associated with a third slope point of the fluorescence intensity response of the magneto-optical defect center orientation of a second spin state due to the optical excitation.

11. The system of claim 10, wherein the third slope point is a positive slope point.

12. The system of claim 10, wherein the third slope point is a negative slope point.

28. The system of claim 1, wherein the magneto-optical defect center material is a nitrogen vacancy (NV) diamond material.

13. A system for magnetic detection, comprising:

a magneto-optical defect center material comprising a plurality of magneto-optical defect centers;

a radio frequency (RF) excitation source configured to provide RF excitation to the NV diamond material;

an optical excitation source configured to provide optical excitation to the magneto-optical defect center material;

an optical detector configured to receive an optical signal emitted by the magneto-optical defect center material;

a magnetic field generator configured to generate a magnetic field applied to the magneto-optical defect center material; and

a controller configured to;

control the optical excitation source to apply optical excitation to the magneto-optical defect center material;

control the RF excitation source to apply a first RF excitation to the magneto-optical defect center material, the first RF excitation having a first frequency;

control the RF excitation source to apply a second RF excitation to the magneto-optical defect center material, the second RF excitation having a second frequency,

wherein the first frequency is a frequency associated with a first slope point of a fluorescence intensity response of a magneto-optical defect center orientation of a first spin state due to the optical excitation, and

wherein the second frequency is a frequency associated with a second slope point of the fluorescence intensity response of the magneto-optical defect center orientation of a second spin state due to the optical excitation;

measure a first fluorescence intensity at the first slope point;

measure a second fluorescence intensity at the second slope point; and

calculate a compensated fluorescence intensity based on the measured first fluorescence intensity and the measured second fluorescence intensity.

14. The system of claim 13, wherein the first slope point is a positive slope point.

15. The system of claim 14, wherein the second slope point is a negative slope point.

16. The system of claim 14, wherein the second slope point is a positive slope point.

17. The system of claim 13, wherein the first slope point is a negative slope point.

18. The system of claim 17, wherein the second slope point is a positive slope point.

19. The system of claim 17, wherein the second slope point is a negative slope point.

20. The system of claim 13, wherein the controller is configured to control the RF excitation source to alternately apply the first RF excitation as two or more RF pulses in sequence and apply the second RF excitation as two or more RF pulses in sequence.

21. The system of claim 20, wherein the controller is configured to measure the first fluorescence intensity based on an average of a fluorescence intensity associated with each of the two or more RF pulses of the first RF excitation and measure the second fluorescence intensity based on an average of a fluorescence intensity associated with each of the two or more RF pulses of the second RF excitation.

22. The system of claim 13, wherein the controller is further configured to:

control the RF excitation source to alternately apply the first RF excitation as three or more RF pulses in sequence and apply the second RF excitation as three or more RF pulses in sequence;

measure the first fluorescence intensity based on an average of a fluorescence intensity associated with each of two or more RF pulses of the three or more RF pulses of the first RF excitation; and

measure the second fluorescence intensity based on an average of a fluorescence intensity associated with each of two or more RF pulses of the three or more RF pulses of the second RF excitation.

23. The system of claim 22, wherein the two or more RF pulses of the first RF excitation are applied last in the sequence of the three or more pulses, and wherein the two or more RF pulses of the second RF excitation are applied last in the sequence of the three or more pulses.

24. The system of claim 13, wherein the controller is further configured to:

control the RF excitation source to apply a third RF excitation to the magneto-optical defect center material, the third RF excitation having a third frequency; and

control the RF excitation source to apply a fourth RF excitation to the magneto-optical defect center material, the fourth RF excitation having a fourth frequency,

wherein the third frequency is a frequency associated with a third slope point of the fluorescence intensity response of the magneto-optical defect center orientation of the first spin state due to the optical excitation, and

wherein the fourth frequency is a frequency associated with a fourth slope point of the fluorescence intensity response of the magneto-optical defect center orientation of the second spin state due to the optical excitation.

29. The system of claim 13, wherein the magneto-optical defect center material is a nitrogen vacancy (NV) diamond material.

25. A method for compensating for drift error in a magnetic detection system, the method comprising:

applying optical excitation to a magneto-optical defect center material comprising a plurality of magneto-optical defect centers;

applying a first RF excitation to the magneto-optical defect center material, the first RF excitation having a first frequency;

applying a second RF excitation to the magneto-optical defect center material, the second RF excitation having a second frequency;

applying a third RF excitation to the magneto-optical defect center material, the third RF excitation having a third frequency;

applying a fourth RF excitation to the magneto-optical defect center material, the fourth RF excitation having a fourth frequency,

wherein the first frequency is a frequency associated with a first slope point of a fluorescence intensity response of a magneto-optical defect center orientation of a first spin state due to the optical excitation, the first slope point being a positive slope point,

wherein the second frequency is a frequency associated with a second slope point of the fluorescence intensity response of the magneto-optical defect center orientation of the first spin state due to the optical excitation, the second slope point being a negative slope point,

wherein the third frequency is a frequency associated with a third slope point of the fluorescence intensity response of the magneto-optical defect center orientation of a second spin state due to the optical excitation, and

wherein the fourth frequency is a frequency associated with a fourth slope point of the fluorescence intensity response of the magneto-optical defect center orientation of the second spin state due to the optical excitation;

measure a first fluorescence intensity at the first or second slope points;

measure a second fluorescence intensity at the third or fourth slope points; and

calculate a compensated fluorescence intensity based on the measured first fluorescence intensity and the measured second fluorescence intensity.

26. The method of claim 25, further comprising applying each of the steps to each of four magneto-optical defect center orientations of the magneto-optical defect center material.

30. The method of claim 25, wherein the magneto-optical defect center material is a nitrogen vacancy (NV) diamond material.

27. A system for magnetic detection, comprising:

magneto-optical defect center material comprising a plurality of magneto-optical defect centers;

a radio frequency (RF) excitation source configured to provide RF excitation to the magneto-optical defect center material;

an optical excitation source configured to provide optical excitation to the magneto-optical defect center material;

an optical detector configured to receive an optical signal emitted by the magneto-optical defect center material;

a magnetic field generator configured to generate a magnetic field applied to the magneto-optical defect center; and

a means for;

controlling the optical excitation source to apply optical excitation to the magneto-optical defect center material;

controlling the RF excitation source to apply a first RF excitation to the magneto-optical defect center material, the first RF excitation having a first frequency;

controlling the RF excitation source to apply a second RF excitation to the magneto-optical defect center material, the second RF excitation having a second frequency,

wherein the first frequency is a frequency associated with a first slope point of a fluorescence intensity response of a magneto-optical defect center orientation of a first spin state due to the optical excitation, the first slope point being a positive slope point, and

wherein the second frequency is a frequency associated with a second slope point of the fluorescence intensity response of the magneto-optical defect center orientation of the first spin state due to the optical excitation, the second slope point being a negative slope point;

measure a first fluorescence intensity at the positive slope point;

measure a second fluorescence intensity at the negative slope point; and

calculate a compensated fluorescence intensity based on the measured first fluorescence intensity and the measured second fluorescence intensity.

31. The system of claim 27, wherein the magneto-optical defect center material is a nitrogen vacancy (NV) diamond material.