Structural composition and method

• US 10,343,313 B2
• Filed: 06/25/2018
• Issued: 07/09/2019
• Est. Priority Date: 11/17/2015
• Status: Active Grant

• Current Assignee: Marhaygue LLC
• Original Assignee: Marhaygue LLC
• Inventors: Green, Guerry E.
• Primary Examiner(s): Wollschlager, Jeffrey M
• Application Number:
  US16/016,942
• Publication Number:
  US 20180339436A1
• Time in Patent Office: 379 Days
• CPC Class Codes: B29C 2043/188 thermosetting adhesives, e.g. polyurethane adhesives
• CPC Class Codes: B29C 43/28 incorporating preformed parts or layers, e.g. compression moulding around inserts or for coating articles
• CPC Class Codes: B29C 43/34 Feeding the material to the mould or the compression means B29C43/085 takes precedence
• CPC Class Codes: B29C 43/46 Rollers
• CPC Class Codes: B29C 43/52 Heating or cooling
• CPC Class Codes: B29C 48/0018 combined with shaping by orienting, stretching or shrinking, e.g. film blowing B29C48/0017 takes precedence
• CPC Class Codes: B29C 48/0022 combined with cutting
• CPC Class Codes: B29C 48/05 Filamentary, e.g. strands
• CPC Class Codes: B29C 48/07 Flat, e.g. panels
• CPC Class Codes: B29C 48/08 flexible, e.g. films
• CPC Class Codes: B29C 48/12 Articles with an irregular circumference when viewed in cross-section, e.g. window profiles
• CPC Class Codes: B29C 48/15 incorporating preformed parts or layers, e.g. extrusion moulding around inserts
• CPC Class Codes: B29C 48/154 Coating solid articles, i.e. non-hollow articles
• CPC Class Codes: B29C 48/156 Coating two or more articles simultaneously
• CPC Class Codes: B29C 48/21 the layers being joined at their surfaces
• CPC Class Codes: B29C 48/2886 of fibrous, filamentary or filling materials, e.g. thin fibrous reinforcements or fillers
• CPC Class Codes: B29C 48/30 Extrusion nozzles or dies extrusion characterised by the shape or cross-section of the extruded article B29C48/03
• CPC Class Codes: B29C 48/304 specially adapted for bringing together components, e.g. melts within the die
• CPC Class Codes: B29C 48/307 specially adapted for bringing together components, e.g. melts within the die
• CPC Class Codes: B29C 48/34 Cross-head annular extrusion nozzles, i.e. for simultaneously receiving moulding material and the preform to be coated
• CPC Class Codes: B29C 55/06 : parallel with the direction of feed
• CPC Class Codes: B29C 55/18 : by squeezing between surfaces, e.g. rollers
• CPC Class Codes: B29K 2027/06 : PVC, i.e. polyvinylchloride
• CPC Class Codes: B29K 2105/04 : cellular or porous
• CPC Class Codes: B29K 2105/12 : of short lengths, e.g. chopped filaments, staple fibres or bristles
• CPC Class Codes: B29K 2105/26 : Scrap or recycled material
• CPC Class Codes: B29L 2031/001 : Profiled members, e.g. beams, sections
• CPC Class Codes: B29L 2031/005 : for making window frames windows B29L2031/778

Abstract

A structural polymeric composite includes a stiffening layer. The composite is made in a continuous extrusion process in which the stiffening layer is pulled through a cross-head die as a polymer is extruded over it. The layer includes a film or textile carrier, a filler of carbon fibers, fiberglass, organic fibers or minerals forming a mat. A binder may be dispersed over the mat and a second carrier applied. The mat is subjected to heat and pressure to soften the carriers and binder so they penetrate into the interstices of the filler and binds mechanically with them and the carriers and binder bind chemically with each other to form the stiffening layer. A polymer is then extruded over the stiffening layer, which may be used flat, provided with holes or punches for composite action with the polymer, formed into a profile, or segmented to provide spaced-apart stiffening layers.

Claims

1. A method for making a structural composite, said method comprising the steps of:

(a) providing a first carrier;

(b) dispersing filler onto said first carrier;

(c) providing a second carrier onto said filler, said second carrier being chemically compatible with said first carrier;

(d) heating said first carrier, said filler and said second carrier to liquefy said first carrier and said second carrier;

(e) pressing said first carrier, said filler, and said second carrier together, wherein said first carrier and said second carrier liquefy and penetrate into said filler, and wherein said first carrier and said second carrier bind mechanically with said filler to form a stiffening layer as said first carrier, said filler and said second carrier cool;

(f) cutting said stiffening layer into strips;

(g) separating said strips;

(h) then extruding a polymer over said strips through a cross-head die to position said strips with respect to said polymer, wherein said structural composite has a neutral axis and wherein said strips are positioned away from, and on opposing sides of, said neutral axis of said structural composite, wherein said strips reinforce said polymer, said polymer binding with said strips chemically to form a structural composite that resists delamination with said strips.

2. The method of claim 1, further comprising the step of dispersing a binding agent onto said first carrier, said binding agent being chemically compatible with said first carrier, said second carrier and said polymer.

3. The method of claim 2, wherein said binding agent is a liquid.

4. The method of claim 2, wherein said binding agent is granular.

5. The method of claim 1, wherein said stiffening layer is flat and wherein said method further comprises the step of deforming said stiffening layer.

6. The method of claim 1, wherein said filler includes fibers.

7. The method of claim 1, wherein said filler includes synthetic fibers.

8. The method of claim 1, wherein said filler includes natural fibers.

9. The method of claim 1, wherein said filler includes minerals.

10. The method of claim 1, wherein said polymer is polyvinyl chloride.

11. A method for making a structural composite, said method comprising the steps of:

(a) rolling out a first carrier;

(b) distributing filler onto said first carrier;

(c) dispersing a binding agent onto said filler;

(d) rolling out a second carrier onto said filler, said filler being between said first carrier and said second carrier;

(d) heating said first carrier, said binding agent, and said second carrier to liquefy at least one of said first carrier, said binding agent and said second carrier;

(e) pressing said filler, said binding agent, said first carrier, and said second carrier together, wherein said first carrier, said binding agent, and said second carrier bind together chemically and bind said filler mechanically to form a stiffening layer, as said first carrier, said filler, said binding agent, and said second carrier cool;

(f) cutting said stiffening layer into strips;

(g) separating said strips; and

(h) extruding a polymer with said strips through a cross-head die, wherein said polymer covers said strips, said polymer binding chemically with said first carrier, said binder, and said second carrier, and wherein said cross-head die positions said strips with respect to said polymer to reinforce said polymer.

12. The method of claim 11, wherein at least one of said first carrier, said binding agent, and said second carrier is made of polyethylene terephthalate.

13. The method of claim 11, wherein at least one of said first carrier, said binding agent, and said second carrier is made of high-density polyethylene.