Furnace atmosphere measurement

• US 10,345,229 B2
• Filed: 08/27/2015
• Issued: 07/09/2019
• Est. Priority Date: 09/01/2014
• Status: Active Grant

• Current Assignee: Pilkington Group Limited
• Original Assignee: Pilkington Group Limited
• Inventors: Haden, Michael Richard, Inskip, Julian, Perry, William Stephen, Williams, Ian Ross
• Primary Examiner(s): Chowdhury, Tarifur R
• Assistant Examiner(s): Nixon, Omar H
• Application Number:
  US15/506,276
• Publication Number:
  US 20170254744A1
• Time in Patent Office: 1,412 Days
• Field of Search: 356315
• CPC Class Codes: G01J 3/0218 using optical fibers
• CPC Class Codes: G01J 3/0286 Constructional arrangements for compensating for fluctuations caused by temperature, humidity or pressure, or using cooling or temperature stabilization of parts of the device; Controlling the atmosphere inside a spectrometer, e.g. vacuum
• CPC Class Codes: G01J 3/42 Absorption spectrometry; Double beam spectrometry; Flicker spectrometry; Reflection spectrometry beam switching arrangements G01J3/08
• CPC Class Codes: G01N 2021/3148 using three or more wavelengths
• CPC Class Codes: G01N 2021/3155 Measuring in two spectral ranges, e.g. UV and visible
• CPC Class Codes: G01N 2021/8578 Gaseous flow IR analysers G01N21/8507
• CPC Class Codes: G01N 21/314 with comparison of measurements at specific and non-specific wavelengths dual wavelength spectrometry G01J3/427

Abstract

A method of determining the concentration of a species in a portion of a furnace atmosphere is described. The method comprises the steps of measuring first, second and third intensities of electromagnetic radiation in the furnace at first, second and third wavelengths respectively. The third wavelength is selected to be representative of absorption of electromagnetic radiation by the species. A fourth intensity of electromagnetic radiation is calculated, being an estimate of the intensity of electromagnetic radiation in the furnace at the third wavelength absent any absorbing species in the furnace atmosphere. The third intensity and the fourth intensities are used to determine a parameter that is proportional to the concentration of absorbing species in the portion of the furnace atmosphere. Apparatus for carrying out the method is also described.

Claims

1. A method of determining the concentration of a species in a portion of a furnace atmosphere comprising the steps:

(i) measuring a first intensity I₁ of electromagnetic radiation in the furnace at a first wavelength λ

₁;

(ii) measuring a second intensity I₂ of electromagnetic radiation in the furnace at a second wavelength λ

₂;

(iii) measuring a third intensity I₃ of electromagnetic radiation in the furnace at a third wavelength λ

₃, the third wavelength being selected to be representative of the absorption of electromagnetic radiation by the species;

(iv) calculating a fourth intensity I₄ at the third wavelength using the first and second intensities, the fourth intensity being an estimate of the intensity of electromagnetic radiation in the furnace at the third wavelength absent any absorbing species in the furnace atmosphere; and

(v) using the third intensity and the fourth intensity to determine a parameter that is proportional to the concentration of absorbing species in the portion of the furnace atmosphere.

2. The method according to claim 1, wherein at step (v) the parameter is determined using the difference between the third intensity and the fourth intensity.

3. The method according to claim 1, wherein the measurement steps (i), (ii) and (iii) measure the respective intensity through a measurement path length and wherein the parameter or the third and fourth intensities are corrected for the measurement path length.

4. The method according to claim 1, wherein the measurement steps (i), (ii) and (iii) measure the respective intensity through a measurement path length and wherein the first intensity, the second intensity and the third intensity are corrected for the measurement path length.

5. The method according to claim 1, wherein the parameter is used to determine a concentration of the species in the portion of the furnace atmosphere.

6. The method according to claim 5, wherein the concentration is a qualitative concentration of the species in the portion of the furnace atmosphere or a quantitative concentration of the species in the portion of the furnace atmosphere.

7. The method according to claim 5, wherein the parameter is used to determine the quantitative concentration of the species in the portion of the furnace atmosphere by using an absorption coefficient for the particular species at the third wavelength, the absorption coefficient indicating the absorption strength of a unit quantity of the species per unit length.

8. The method according to claim 1, wherein the first and second intensities (I₁, I₂) are used to determine the temperature inside the furnace, the temperature being determined by calculating the gradient δ

I/δ

λ and

comparing the calculated gradient with the theoretical gradient at that wavelength, the determined temperature in the furnace then being used to calculate a blackbody spectrum, thereby allowing a calculation of an intensity at the third wavelength.

9. The method according to claim 1, wherein the fourth intensity is calculated by linear interpolation between the first intensity at the first wavelength and the second intensity at the second wavelength to obtain a predicted intensity at the third wavelength.

10. The method according to claim 1, wherein the first wavelength and the second wavelength are shorter than the third wavelength.

11. The method according to claim 1, wherein the first wavelength is shorter than the third wavelength and the second wavelength is longer than the third wavelength.

12. The method according to claim 1, wherein the species is sodium.

13. The method according to claim 12, wherein the third wavelength is between 585 nm and 595 nm.

14. The method according to claim 12, wherein the first wavelength is between 500 nm and 584.9 nm.

15. The method according to claim 12, wherein the second wavelength is between 500 nm and 584.9 nm or wherein the second wavelength is between 596 nm and 700 nm.

16. The method according to claim 1, wherein the measured intensity at more than two wavelengths is used to determine the intensity at the third wavelength.

17. The method according to claim 1, wherein the furnace is a glass making furnace.

18. Apparatus for measuring the concentration of a species in a portion of a furnace atmosphere, the species absorbing electromagnetic radiation in the furnace, the apparatus comprising:

means for collecting electromagnetic radiation to collect electromagnetic radiation from inside the furnace;

means for coupling to direct the collected electromagnetic radiation to a suitable means for measuring, the means for measuring being configured to;

(i) measure a first intensity I₁ of electromagnetic radiation in the furnace at a first wavelength λ

₂;

(ii) measure a second intensity I₂ of electromagnetic radiation in the furnace at a second wavelengthλ

₂;

(iii) and measure a third intensity I₃ of electromagnetic radiation in the furnace at a third wavelength λ

₃, the third wavelength being selected to be representative of the absorption of electromagnetic radiation by the species; and

means for computing, configured to take the output from the measuring means to determine the amount of absorption of electromagnetic radiation inside the furnace at a measurement wavelength, the measurement wavelength being selected to be representative of the absorption of electromagnetic radiation in the furnace atmosphere by the species, by

calculating a fourth intensity I₄ at the third wavelength using the first and second intensities, the fourth intensity being an estimate of the intensity of electromagnetic radiation in the furnace at the third wavelength absent any absorbing species in the furnace atmosphere; and

using the third intensity and the fourth intensity to determine a parameter that is proportional to the concentration of absorbing species in the portion of the furnace atmosphere.

19. The apparatus according to claim 18, wherein:

the means for measuring is sensitive to electromagnetic radiation having a wavelength between 380 nm and 800 nm;

or

wherein the species is a metal species.

20. A method of determining the concentration of a species in a portion of a furnace atmosphere without using a separate background trace, comprising the steps:

(i) measuring a first intensity I₁ of electromagnetic radiation in the furnace at a first wavelength λ

₁ ;

(ii) measuring a second intensity I₂ of electromagnetic radiation in the furnace at a second wavelength λ

₂;

(iii) measuring a third intensity I₃ of electromagnetic radiation in the furnace at a third wavelength λ

₃, the third wavelength being selected to be representative of the absorption of electromagnetic radiation by the species;

(iv) calculating a fourth intensity I₄ at the third wavelength using the first and second intensities, the fourth intensity being an estimate of the intensity of electromagnetic radiation in the furnace at the third wavelength absent any absorbing species in the furnace atmosphere; and

(v) using the third intensity and the fourth intensity to determine a parameter that is proportional to the concentration of absorbing species in the portion of the furnace atmosphere.