Heat setting optical films

• US 10,350,818 B2
• Filed: 04/09/2015
• Issued: 07/16/2019
• Est. Priority Date: 04/08/2005
• Status: Active Grant

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Merrill, William W., Hebrink, Timothy J.
• Primary Examiner(s): Khare, Atul P.
• Application Number:
  US14/682,622
• Publication Number:
  US 20150210023A1
• Time in Patent Office: 1,559 Days
• Field of Search: 2642105, 2642107
• CPC Class Codes: B29C 35/0277 Apparatus with continuous transport of the material to be cured B29C35/025, B29C35/06, B29C35/10, B29C35/14 take precedence
• CPC Class Codes: B29C 55/06 parallel with the direction of feed
• CPC Class Codes: B29C 55/08 transverse to the direction of feed
• CPC Class Codes: B29C 55/085 in several stretching steps
• CPC Class Codes: B29D 11/00644 polarizing
• CPC Class Codes: B29K 2067/003 PET, i.e. poylethylene terephthalate
• CPC Class Codes: B29K 2069/00 Use of PC, i.e. polycarbonates or derivatives thereof, as moulding material
• CPC Class Codes: B29K 2995/0034 Polarising
• CPC Class Codes: B29K 2995/0051 mono-axially
• CPC Class Codes: C08G 63/181 Acids containing aromatic rings
• CPC Class Codes: C08J 2367/03 the dicarboxylic acids and dihydroxy compounds having the hydroxy and the carboxyl groups directly linked to aromatic rings
• CPC Class Codes: C08J 5/18 Manufacture of films or sheets
• CPC Class Codes: C09K 2323/031 Polarizer or dye
• CPC Class Codes: G02B 5/3083 Birefringent or phase retarding elements G02B5/3008, G02B5/3016 take precedence; systems for polarisation control G02B27/286; manufacturing phase modulating patterns by lithographic processes G03F7/001

Abstract

A method of making an optical film includes providing a film, substantially uniaxially orienting the film, and heat setting the oriented film. The film includes a polymeric material capable of developing birefringence.

Claims

1. A method of making an optical film, the method comprising:

providing a film comprising a polyester-based polymeric material capable of developing birefringence;

conveying the film along a machine direction while holding opposing edge portions of the film, wherein the film has an intended stretch direction transverse and orthogonal to the machine direction, an in-plane machine direction orthogonal to the stretch direction, and a thickness direction;

substantially uniaxially orienting the film in the stretch direction while allowing contraction of the film in the in-plane and thickness directions thereof, the oriented film having an initial refractive index in each of the stretch, in-plane, and thickness directions which define an initial relative birefringence of the oriented film; and

heat setting the substantially uniaxially oriented film, the heat setting thereby altering each of the initial refractive indices in the stretch, in-plane, and thickness directions to a final refractive index in each of the stretch, in-plane, and thickness directions, respectively, the final refractive indices in the stretch, in-plane, and thickness directions defining a final relative birefringence of the heat set film,

wherein the polyester-based material, a draw ratio and temperature for said uniaxially orienting, and a temperature and time for said heat setting are chosen such that the final relative birefringence is less than the initial relative birefringence, with the chosen heat setting temperature being above the glass transition temperature and below the melting temperature of the polyester-based polymer material, and

wherein the initial and final relative birefringence are each defined as |ny−

nz|/|nx−

nu|, where nx represents refractive index in the stretch direction, ny represents refractive index in the in-plane direction orthogonal to the stretch direction, nz represents refractive index in the thickness direction, and nu represents the average of ny and nz.

2. The method of claim 1 wherein the heat setting time is between about 1 second and about 10 minutes.

3. The method of claim 1 wherein:

the film comprises one or more polymeric materials in addition to the polyester-based polymeric material; and

the step of heat setting comprises heating the film to a temperature above the glass transition temperature and below the melting point of each of the polyester-based and the one or more additional polymeric materials forming the film.

4. The method of claim 1 wherein

the heat setting temperature is higher than the orienting temperature.

5. The method of claim 1 wherein the polyester-based polymeric material is selected from the group consisting of polyethylene naphthalate, polyethylene terephthalate, and copolymers thereof.

6. The method of claim 1 wherein the polyester-based polymeric material comprises a semicrystalline polymer.

7. The method of claim 1 wherein the film further comprises a polyester/polycarbonate blend.

8. The method of claim 1 wherein the provided film is in roll form.

9. The method of claim 1 wherein the step of providing a film comprises providing the film from an extruder.

10. The method of claim 1 wherein

the final refractive index in the in-plane direction orthogonal to the stretch direction is greater than the initial refractive index in the in-plane direction orthogonal to the stretch direction.

11. The method of claim 10 wherein the final refractive index in the thickness direction is greater than the initial refractive index in the thickness direction.

12. The method of claim 1 wherein

the final refractive index in the thickness direction is greater than the initial refractive index in the thickness direction.

13. The method of claim 1 wherein a difference between the final refractive indices in the in-plane and thickness directions is less than a difference between the initial refractive indices in the in-plane and thickness directions.

14. The method of claim 1 wherein

the final refractive index in the stretch direction is less than the initial refractive index in the stretch direction.

15. The method of claim 1 wherein a difference between the final refractive indices in the stretch and in-plane directions is less than a difference between the initial refractive indices in the stretch and in-plane directions.

16. The method of claim 1 wherein the step of substantially uniaxially orienting the film comprises stretching a non-continuous portion of the film in a tenter apparatus.

17. The method of claim 1 further comprising quenching the heat set film.

18. The method of claim 1 wherein:

the film comprises a plurality of layers; and

the step of heat setting results in an increased adhesion between adjacent layers of the plurality of layers.

19. The method of claim 1 wherein:

the film has a strain-induced crystallization point, which is a draw ratio at which significant strain-induced crystallization occurs; and

the draw ratio applied during said orienting is less than the strain-induced crystallization point.

20. The method of claim 19 wherein the strain-induced crystallization point is about 2.2.

21. The method of claim 1 wherein

the heat setting is conducted while applying stretch to the oriented film in the stretch direction.

22. The method of claim 1 wherein:

the film comprises an initial density; and

the step of heat setting results in the film having a final density greater than the initial density.

23. The method of claim 1 wherein:

the step of providing a film comprises providing the film having a plurality of layers, at least one of the layers comprising an amorphous material; and

the step of heat setting comprises retaining an amorphous character of the layer comprising the amorphous material.

24. The method of claim 23 wherein the amorphous material comprises polycarbonate or a blend of polycarbonate and copolyester.

25. The method of claim 1 further comprising a second step of heat setting applied to the heat set film.

26. The method of claim 1 wherein the draw ratio is less than about 2.2.