Method of producing composite members having increased strength

• US 10,357,906 B2
• Filed: 05/19/2011
• Issued: 07/23/2019
• Est. Priority Date: 08/19/2005
• Status: Active Grant

• Current Assignee: Ecopuro, LLC
• Original Assignee: Ecopuro, LLC
• Inventors: Johnson, Sr., William L.
• Primary Examiner(s): Daniels, Matthew J
• Application Number:
  US13/111,680
• Publication Number:
  US 20110268876A1
• Time in Patent Office: 2,987 Days
• Field of Search: 264 453, 264131, 427194
• CPC Class Codes: B29C 2948/92561 Time, e.g. start, termination, duration or interruption
• CPC Class Codes: B29C 2948/926 Flow or feed rate
• CPC Class Codes: B29C 2948/92761 Mechanical properties
• CPC Class Codes: B29C 2948/92952 Drive section, e.g. gearbox, motor or drive fluids
• CPC Class Codes: B29C 2948/9298 Start-up, shut-down or parameter setting phase; Emergency shut-down; Material change; Test or laboratory equipment or studies
• CPC Class Codes: B29C 44/128 Internally reinforcing constructional elements, e.g. beams
• CPC Class Codes: B29C 44/186 Filling multiple cavities B29C44/181, B29C44/182 and B29C44/188 takes precedence
• CPC Class Codes: B29C 44/3411 Relieving stresses
• CPC Class Codes: B29C 48/07 Flat, e.g. panels
• CPC Class Codes: B29C 48/11 comprising two or more partially or fully enclosed cavities, e.g. honeycomb-shaped
• CPC Class Codes: B29C 48/12 Articles with an irregular circumference when viewed in cross-section, e.g. window profiles
• CPC Class Codes: B29C 48/304 specially adapted for bringing together components, e.g. melts within the die
• CPC Class Codes: B29K 2105/04 cellular or porous
• CPC Class Codes: B29L 2031/60 Multitubular or multicompartmented articles, e.g. honeycomb

Abstract

This invention relates to extruded composite materials specifically focusing on the increasing load bearing capacity and the overall strength of composites. Injectable conformable structural core materials are used to replace foam cells inside extruded composite materials thereby increasing the overall load bearing stability and strength. The core materials are tailored to have a desired CTE with respect to the structural materials. The core materials may also incorporate fibers and solid structural fillers for increasing the strength of the composite member. The objective is to enable composite materials to have the highest structural load bearing capability possible so that these technologies can be used as the replacement of wood, in aerospace applications and for other purposes.

Claims

1. A method of making a foam member comprising the steps of:

determining a volume expansion of an unexpanded foam material from a liquid to a solid;

incorporating chopped fibers and substantially incompressible filler material into said foam material to form a foam mixture in an amount wherein said incompressible filler material comprises a volume ratio of 20% to 80% with respect to an expanded volume of said foam mixture;

feeding said foam mixture through a die, wherein said foam mixture locates in a deformable structural material, said step of feeding after said step of determining said volume expansion of said foam material for preventing swelling of said deformable structural material;

expanding said foam mixture;

wherein said fibers contact and adhere to at least some of said filler material to act as anchoring members to said fibers;

adjusting a selected amount of said filler material in said foam mixture to achieve a coefficient of thermal expansion of said foam mixture that reduces shear stress between said foam mixture and said deformable structural material for preventing delamination of said foam mixture from said deformable structural material.

2. The method according to claim 1 wherein said fibers are selected from a group consisting of natural, man-made, synthetic and mineral fibers.

3. The method according to claim 1 wherein:

said fibers comprise greater than approximately 4% by weight of said foam material.

4. The method according to claim 1 wherein:

said volume ratio is 20% to 50%.

5. The method according to claim 1 wherein:

said volume ratio is 40% to 80%.

20. The method according to claim 1 wherein:

said deformable structural material is an outer shell created by said foam upon curing.

6. A method of making a member comprising the steps of:

determining a volume expansion of a foam material from a liquid to a solid;

incorporating fibers and rigidly solid substantially incompressible filler material into said foam material to form a foam mixture in an amount wherein said filler material comprises a volume ratio that adjusts said volume expansion of said foam mixture to reduce shear stress between said foam mixture and a deformable structural material;

introducing said foam mixture through a die, wherein said foam mixture locates in said deformable structural material, said step of introducing after said step of determining said volume expansion of said foam material for preventing swelling of said deformable structural material;

wherein said fibers contact and interact with at least some of said filler material, said filler material acting as anchoring members to anchor said fibers in said foam mixture, thereby strengthening the member;

wherein said rigidly solid incompressible filler material interacts with said fibers throughout said foam mixture.

7. The method according to claim 6 wherein:

said volume ratio of said filler material is 20% to 80% with regard to said volume expansion of said foam mixture.

8. The method according to claim 6 wherein said filler material comprises microspheres.

9. The method according to claim 6 wherein said fibers are selected from a group consisting of natural, man-made, synthetic and mineral fibers.

10. The method according to claim 6 wherein said foam material is a polyurethane composite foam.

11. The method according to claim 6 further comprising the steps of:

extruding a structural material through a die to form an elongate structure that defines a durable outer shell;

filling said durable outer shell with said foam material for forming a strengthened extruded composite member;

wherein said fibers contact and interact with at least some of said filler material to act as anchoring members to said fibers.

12. The method according to claim 11 further comprising the steps of:

determining the coefficient of thermal expansion of said structural material; and

adjusting an amount of said filler material in said foam mixture to achieve a coefficient of thermal expansion of said foam mixture to reduce shear stress between said foam mixture and said deformable structural material.

13. The method according to claim 11 further comprising the steps of:

determining the coefficient of thermal expansion of said structural material;

adding a selected amount of said filler material to said foam material to achieve a coefficient of thermal expansion of said foam mixture to reduce shear stress between said foam mixture and said deformable structural material.

14. The method according to claim 6 wherein said rigidly solid incompressible filler material is selected from glass microspheres, ceramic microspheres, and mixtures thereof.

15. The method according to claim 6 wherein said rigidly solid incompressible filler material is selected from glass microspheres.

16. The method according to claim 6 wherein said rigidly solid incompressible filler material is selected from ceramic microspheres.

17. The method according to claim 6 wherein said rigidly solid incompressible material has a density of less than 40 lb./ft3.

18. The method according to claim 6 wherein:

said step of introducing comprises injection molding.

19. The method according to claim 6 wherein:

said step of introducing comprises cast molding.

21. A method of making a foam member comprising the steps of:

determining an expanded foam volume of an unexpanded mixture of an unexpanded polymer material, chopped fibers and substantially incompressible filler material;

calculating an optimal feed rate of said unexpanded mixture for preventing a volume mismatch with respect to a deformable structural material;

feeding said unexpanded mixture through a die and expanding said unexpanded mixture to form an expanded foam mixture, wherein said filler material comprises a volume ratio of 20% to 80% with respect to a volume of said expanded foam mixture, wherein said expanded foam mixture locates in said deformable structural material;

wherein said step of feeding is after said step of determining said expanded foam volume for preventing swelling of said deformable structural material;

wherein said fibers contact and adhere to at least some of said filler material, said filler material acting as anchoring members to said fibers.

22. A method of making a member comprising the steps of:

determining an expanded foam volume of an unexpanded mixture of unexpanded polymer material, chopped fibers and substantially incompressible filler material;

calculating an optimal feed rate of said unexpanded mixture comprising said unexpanded polymer material, said fibers and said filler material for preventing a volume mismatch with respect to a deformable structural material;

introducing said unexpanded mixture through a die, wherein said unexpanded mixture expands to form an expanded foam mixture, wherein said filler material comprises a volume ratio that adjusts a volume of said expanded foam mixture, to reduce shear stress between said expanded foam mixture and a deformable structural material wherein said expanded mixture locates in said deformable structural material;

said step of introducing is after said step of determining said expanded foam volume for preventing swelling of said deformable structural material;

wherein said fibers contact and interact with at least some of said filler material, said filler material acting as anchoring members to anchor said fibers in said expanded foam mixture, for strengthening the member;

wherein said filler material interacts with said fibers throughout said expanded foam mixture;

adjusting a selected amount of said filler material in said unexpanded mixture to achieve a desirable coefficient of thermal expansion of said expanded foam mixture with respect to said deformable structural material for reducing a difference in a coefficient of thermal expansion between the expanded foam mixture and the deformable structural material for significantly reducing or preventing delamination of said expanded foam mixture from said deformable structural material.