Separation vessels for use in polymerization processes and methods for cleaning same

• US 10,358,511 B2
• Filed: 01/13/2017
• Issued: 07/23/2019
• Est. Priority Date: 12/22/2009
• Status: Active Grant

• Current Assignee: ExxonMobil Chemical Patents Inc. (Exxon Mobil Corporation)
• Original Assignee: ExxonMobil Chemical Patents Inc. (Exxon Mobil Corporation)
• Inventors: Cornelissen, Philip H., Lammens, Henri A., Ciancio, Fausto F., Morgan, Christopher K., Reynders, Leo E.
• Primary Examiner(s): Blan, Nicole
• Application Number:
  US15/405,939
• Publication Number:
  US 20170204207A1
• Time in Patent Office: 921 Days
• Field of Search: None
• CPC Class Codes: B01J 19/02 Apparatus characterised by being constructed of material selected for its chemically-resistant properties
• CPC Class Codes: B01J 2219/0245 of synthetic organic material
• CPC Class Codes: B01J 2219/1946 conical
• CPC Class Codes: B01J 3/03 Pressure vessels, or vacuum vessels, having closure members or seals specially adapted therefor
• CPC Class Codes: B08B 1/165 Scrapers
• CPC Class Codes: C08F 10/00 Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
• CPC Class Codes: C08F 110/02 Ethene
• CPC Class Codes: C08F 2/007 Scale prevention in the auxiliary parts

Abstract

Both a system and method for cleaning a low pressure separation vessel of a high pressure polyethylene polymerization plant are provided. The system includes a polytetrafluoroethylene lining that covers the interior surfaces of the vessel, and a cover mounting assembly including an annular clamp for detachably mounting a cover over the vessel. The mounting assembly includes a clamp actuator for quickly securing and releasing the cover with respect to a top rim of the vessel. The vessel is drained of liquid polyethylene and allowed to cool to ambient temperature, thus creating a frozen “skin” of polyethylene around the interior surfaces of the vessel. The clamp actuator releases the cover. The polyethylene skin is peeled off the interior sides the vessel and gathered up at the top to form a neck, thus peeling the polyethylene skin away from the polytetrafluoroethylene lining along with any degraded polymers or other impurities that have accumulated on the interior surfaces of the vessel.

Claims

1. A method for removing polymer from a low pressure separation vessel in a high pressure polymerization plant comprising:

providing a low pressure separation vessel which had been in operation as part of a high pressure polymerization process, said vessel comprising;

i) a detachable cover,

ii) a low-stick lining that covers at least a portion of the interior surfaces of the vessel, said low-stick lining producing a reduced tendency for polymer product to adhere to a surface so lined as compared to a surface without such low-stick lining, and

iii) a liquid polymer, comprising at least one of polyethylene or polypropylene, which is the reaction product of the high pressure polymerization process;

removing the detachable cover from the low pressure separation vessel;

emptying the low pressure separation vessel of the liquid polymer;

cooling the low pressure separation vessel an amount sufficient to freeze the liquid polymer clinging to the interior surfaces of the low pressure separation vessel to form a skin layer of the liquid polymer, wherein the skin layer is disposed on the low-stick lining; and

removing the skin layer from the low pressure separation vessel.

2. The method of claim 1, wherein the low pressure separation vessel receives a stream of the liquid polymer and the method further comprises stopping the stream of the liquid polymer to the low pressure separation vessel prior to removing the detachable cover and/or emptying the low pressure separation vessel of at least a portion of the liquid polymer.

3. The method of claim 1, wherein the skin layer forms a continuous mass in the low pressure separation vessel.

4. The method of claim 3, wherein the continuous mass is removed from the low pressure separation vessel using a hoist.

5. The method of claim 1, wherein the low-stick lining comprises a layer of polytetrafluoroethylene.

6. The method of claim 5, wherein the low-stick lining comprises both a layer of polytetrafluoroethylene and a layer of nickel, and the layer of polytetrafluoroethylene is disposed on the layer of nickel.

7. The method of claim 6, wherein the layer of nickel has a thickness from about 0.050 and 0.150 mm.

8. The method of claim 5, wherein the layer of polytetrafluoroethylene has a thickness from about 0.02 and 0.20 mm.

9. The method of claim 1, wherein the cooling comprises cooling the low pressure separation vessel to substantially ambient temperature.

10. A method for production of polyolefin polymers comprising the method of claim 1.