SOFC system and method which maintain a reducing anode environment

• US 10,361,442 B2
• Filed: 11/08/2016
• Issued: 07/23/2019
• Est. Priority Date: 11/08/2016
• Status: Active Grant

• Current Assignee: Bloom Energy Corporation
• Original Assignee: Bloom Energy Corporation
• Inventors: Perry, Martin, Ballantine, Arne, Gasda, Michael, Karuppaiah, Chockkalingam
• Primary Examiner(s): O'Donnell, Lucas J.
• Application Number:
  US15/346,052
• Publication Number:
  US 20180131018A1
• Time in Patent Office: 987 Days
• Field of Search: None
• CPC Class Codes: H01M 2008/1293 Fuel cells with solid oxide electrolytes
• CPC Class Codes: H01M 8/04074 Heat exchange unit structures specially adapted for fuel cell
• CPC Class Codes: H01M 8/04097 with recycling of the reactants H01M8/04119, H01M8/04104 take precedence
• CPC Class Codes: H01M 8/04201 Reactant storage and supply, e.g. means for feeding, pipes
• CPC Class Codes: H01M 8/04228 during shut-down
• CPC Class Codes: H01M 8/04303 applied during shut-down
• CPC Class Codes: H01M 8/04708 of fuel cell reactants
• CPC Class Codes: H01M 8/04955 Shut-off or shut-down of fuel cells
• CPC Class Codes: H01M 8/0656 by electrochemical means H01M8/065 takes precedence
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A solid oxide fuel cell system and method including a hotbox containing a fuel cell stack, a fuel supply configured to provide a fuel to the fuel cell stack, and a hydrogen supply thermally integrated with the hotbox. The hydrogen supply is configured to produce hydrogen during or shortly after the SOFC system is shutdown using residual heat of the hot box, and to provide the hydrogen to the SOFC stack such that an anode reducing environment is maintained in the stack.

Claims

1. A method of operating a solid oxide fuel cell (SOFC) system, comprising:

operating the SOFC system which includes a hotbox containing a SOFC stack and a hydrogen supply, in steady-state by;

providing a flow of fuel from a fuel supply to the SOFC system to generate electricity and maintain the SOFC stack at a temperature of above 750°

C.; and

maintaining the hydrogen supply at a temperature ranging from about 150°

C. to about 300°

C. to store hydrogen; and

shutting down the SOFC system by;

stopping the flow of the fuel to the SOFC system;

heating the hydrogen supply to a temperature ranging from about 400°

C. to about 650°

C. using residual heat of the hotbox to release the stored hydrogen; and

providing the hydrogen released from the hydrogen supply to the SOFC stack before the SOFC stack temperature drops below 750°

C., such that an anode reducing environment is maintained in the SOFC stack.

2. The method of claim 1, wherein:

the operating the SOFC system in the steady-state further comprises supplying electricity to a normally open valve, such that the normally open valve remains closed and the hydrogen is not provided from the hydrogen supply to the SOFC stack; and

the shutting down the SOFC system further comprises supplying no electricity to the normally open valve, such that the normally open valve automatically opens to provide the hydrogen from the hydrogen supply to the SOFC stack.

3. The method of claim 1, wherein the hydrogen supply is embedded between walls of the hotbox or disposed inside of the hotbox.

4. The method of claim 3, wherein the hydrogen supply is disposed in a portion of the hotbox that is maintained at the temperature ranging from about 150°

C. to about 300°

C. during the operating the SOFC system in the steady-state.

5. The method of claim 1, wherein the hydrogen supply comprises a solid metal hydride hydrogen storage material.

6. The method of claim 5, further comprising:

separating hydrogen from an anode exhaust of the SOFC stack; and

providing the separated hydrogen to the hydrogen supply.

7. The method of claim 1, wherein the hydrogen supply comprises a thermochemical hydrogen generation source which produces the hydrogen from a hydrogen and oxygen containing source using the residual heat of the hotbox.

8. The method of claim 7, wherein:

the thermochemical hydrogen generation source comprises a material selected from zinc, ceria (CeO₂), ceria doped with a transition metal or a rare earth, lanthanum-strontium manganite (LSM) and a combination of sodium carbonate and Mn₃O₄; and

the hydrogen and oxygen containing source comprises water or potassium hydride which is provided to the thermochemical hydrogen generation source during or shortly after the shutdown of the SOFC system.

9. The method of claim 8, further comprising:

separating water from an exhaust output from the hotbox;

storing the separated water; and

providing the stored water to the hydrogen supply during the shutdown of the SOFC system.

10. The method of claim 1, wherein:

during the operating the SOFC system in the steady-state, the hydrogen supply is cooled by an air inlet stream supplied to the SOFC stack; and

during the shutting down the SOFC system, the air inlet stream is turned off.