Methods of preparing anodes using tin as active material

• US 10,367,193 B2
• Filed: 01/09/2019
• Issued: 07/30/2019
• Est. Priority Date: 04/07/2016
• Status: Active Grant

• Current Assignee: StoreDot Ltd.
• Original Assignee: StoreDot Ltd.
• Inventors: Burshtain, Doron, Remizov, Sergey, Jacob, David, Shadmi, Nitzan, Farran, Hani, Shapiro, Leora, Goldbart, Ohad, Brudnik, Boris, Ophir, Carmit, Aronov, Daniel
• Primary Examiner(s): Slifka, Sarah A.
• Application Number:
  US16/243,224
• Publication Number:
  US 20190148713A1
• Time in Patent Office: 202 Days
• Field of Search: None
• CPC Class Codes: H01M 10/0525 Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• CPC Class Codes: H01M 4/134 Electrodes based on metals, Si or alloys
• CPC Class Codes: H01M 4/1395 of electrodes based on metals, Si or alloys
• CPC Class Codes: H01M 4/366 as layered products
• CPC Class Codes: H01M 4/386 Silicon or alloys based on silicon
• CPC Class Codes: H01M 4/387 Tin or alloys based on tin
• CPC Class Codes: H01M 4/621 Binders
• CPC Class Codes: H01M 4/624 Electric conductive fillers
• CPC Class Codes: H01M 4/625 Carbon or graphite
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

Improved anodes and cells are provided, which enable fast charging rates with enhanced safety due to much reduced probability of metallization of lithium on the anode, preventing dendrite growth and related risks of fire or explosion. Anodes and/or electrolytes have buffering zones for partly reducing and gradually introducing lithium ions into the anode for lithiation, to prevent lithium ion accumulation at the anode electrolyte interface and consequent metallization and dendrite growth. Various anode active materials and combinations, modifications through nanoparticles and a range of coatings which implement the improved anodes are provided.

Claims

1. A method for preparing a lithium ion cell comprising:

attaching nanoparticles to anode active material particles that comprise 5-80% tin, wherein the nanoparticles are at least one order of magnitude smaller than the anode active material particles,

preparing an anode from the anode active material particles having the attached nanoparticles, and

preparing a lithium ion cell using the prepared anode.

2. The method of claim 1, wherein the anode active material particles are 100-500 nm in diameter and the attached nanoparticles are 10-50 nm in diameter.

3. The method of claim 1, wherein the nanoparticles are embedded in the anode active material particles.

4. The method of claim 1, wherein the nanoparticles are made of boron carbide and/or tungsten carbide.

5. The method of claim 4, wherein the nanoparticles are B₄C nanoparticles present in an amount of 2-25 weight % of the anode active material particles having the attached nanoparticles.

6. The method of claim 1, further comprising coating the anode active material particles having the attached nanoparticles with a 1-10 nm thick surface layer of an amorphous carbon, graphene or graphite.

7. The method of claim 1, further comprising coating the anode active material particles having the attached nanoparticles with a 1-10 nm thick surface layer of a transition metal.

8. The method of claim 1, further comprising coating the anode active material particles having the attached nanoparticles with a 1-10 nm thick surface layer of a lithium polymer.

9. The method of claim 1, further comprising coating the anode active material particles having the attached nanoparticles with a polymer which is conductive and/or lithiated.

10. The method of claim 9, wherein the anode active material particles are 20-500 nm in diameter and the coating is 2-200 nm thick.

11. The method of claim 1, further comprising configuring the surface layer to provide a buffering zone that receives lithium ions from an interface of the anode active material particles with an electrolyte, wherein the buffering zone partially reduces the received lithium ions, and enables the partially reduced lithium ions to move into an inner zone of the anode active material particles for lithiation therein.

12. The method of claim 1, further comprising carrying out the attaching of the nanoparticles to the anode active material particles by milling.

13. The method of claim 1, further comprising carrying out the anode preparation by forming a slurry with the active material particles, a solvent, and at least one additive selected from the group consisting of conductive particles, binder and plasticizer;

and removing the solvent and consolidating the slurry to form the anode.

14. The method of claim 1, wherein the anode active material particles that comprise 5-80% tin further comprise at least one of Si, Ge, B, W, alloys thereof and mixtures thereof.

15. The method of claim 14, wherein the anode active material particles that comprise 5-80% tin have a particle size of 100-500 nm.