Detergent composition comprising phosphinosuccinic acid adducts and methods of use

• US 10,377,971 B2
• Filed: 04/28/2017
• Issued: 08/13/2019
• Est. Priority Date: 09/13/2012
• Status: Active Grant

• Current Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Original Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Inventors: Silvernail, Carter M., Olson, Erik C.
• Primary Examiner(s): Douyon, Lorna M
• Application Number:
  US15/581,156
• Publication Number:
  US 20170233684A1
• Time in Patent Office: 837 Days
• Field of Search: None
• CPC Class Codes: C11D 2111/16 Metals
• CPC Class Codes: C11D 2111/18 Glass; Plastics
• CPC Class Codes: C11D 3/044 Hydroxides or bases
• CPC Class Codes: C11D 3/08 Silicates
• CPC Class Codes: C11D 3/10 Carbonates ; Bicarbonates
• CPC Class Codes: C11D 3/2082 Polycarboxylic acids-salts thereof
• CPC Class Codes: C11D 3/365 containing carboxyl groups

Abstract

Detergent compositions effective for controlling hard water scale accumulation are disclosed. Detergent compositions employing phosphinosuccinic acid and mono-, bis- and oligomeric phosphinosuccinic acid (PSO) derivatives with alkali metal carbonate and/or alkali metal hydroxide reduce had water scale accumulation on treated surfaces at alkaline conditions between about pH of 9 and 12.5. Methods employing the detergent compositions and preventing hard water scale accumulation are also provided.

Claims

1. A method of cleaning while preventing hard water scale accumulation on a treated surface comprising:

generating a use solution of a detergent composition within a ware washing machine,

applying the use solution of the detergent composition to a substrate surface,

wherein the detergent composition comprises between about 0.01 wt-% and about 40 wt-% of a phosphinosuccinic acid derivative comprising a phosphinosuccinic acid and mono-, bis- and oligomeric phosphinosuccinic acid adducts and an alkalinity source selected from the group consisting of an alkali metal hydroxide, carbonate, metasilicate, silicate, and combination thereof, and

wherein the detergent composition is effective for preventing the formation, precipitation and/or deposition of hard water scale on the surface;

wherein the use solution of the detergent composition has a pH greater than 9; and

the composition is a detergent composition, contains more of the alkalinity source than the phosphinosuccinic acid derivative in terms of weight percentage, and does not contain a bleaching agent.

2. The method of claim 1, where the surface is plastic, metal and/or glass surfaces.

3. The method of claim 1, wherein the phosphinosuccinic acid (I) and mono- (II), bis- (III) and oligomeric (IV) phosphinosuccinic acid adducts have the following formulas:

4. The method of claim 1, wherein the detergent composition comprises between about 1 wt-% and about 20 wt-% of the phosphinosuccinic acid derivative and between about 10 wt-% and about 90 wt-% of the alkalinity source.

5. The method of claim 1, wherein the detergent composition comprises between about 1 wt-% and about 20 wt-% of the phosphinosuccinic acid derivative and between about 50 wt-% and about 70 wt-% of the alkali metal hydroxide.

6. The method of claim 1, wherein the detergent composition further comprises a water soluble polymer, wherein the water soluble polymer is selected from the group consisting of a polycarboxylic acid, hydrophobically modified polycarboxylic acid, and mixture thereof.

7. The method of claim 1, wherein the detergent composition further comprises a defoaming agent.

8. The method of claim 7, wherein the defoaming agent is selected from the group consisting of silica dispersed in polydimethylsiloxane, fatty amide, hydrocarbon waxes, fatty acid, fatty ester, fatty alcohol, fatty acid soap, ethoxylate, mineral oil, polyethylene glycol ester, alkyl phosphate ester, and combination thereof.

9. The method of claim 1, wherein the detergent composition further comprises from about 0.1-40 wt-% of a nonionic surfactant.

10. The method of claim 9, wherein the nonionic surfactant is selected from the group consisting of an ethylene oxide/propylene oxide copolymer, capped ethylene oxide/propylene oxide copolymer, ethylene oxide/propylene oxide block copolymer, alcohol alkoxylate, capped alcohol alkoxylate, and combination thereof.

11. The method of claim 9, wherein the nonionic surfactant is an ethylene oxide/propylene oxide block copolymer.

12. The method of claim 9, wherein the detergent composition comprises from about 10-80 wt-% of the alkalinity source, from about 1-20 wt-% of the phosphinosuccinic acid derivative, and from about 1-10 wt-% of the nonionic surfactant.

13. The method of claim 9, wherein the detergent composition use solution comprises from about 100-1500 ppm of the alkalinity source, from about 1-500 ppm of the phosphinosuccinic acid derivative, from about 1-50 ppm of the nonionic surfactant.

14. The method of claim 1, where the use solution comprises from about 100-1500 ppm of the alkalinity source, from about 5-500 ppm of the phosphinosuccinic acid derivative.