Compact spectroscopic optical instrument

• US 10,386,232 B2
• Filed: 12/15/2017
• Issued: 08/20/2019
• Est. Priority Date: 12/15/2017
• Status: Active Grant

• Current Assignee: Horiba Instruments Incorporated (Horiba Limited)
• Original Assignee: Horiba Instruments Incorporated (Horiba Limited)
• Inventors: Kovach, Ronald Joseph, Atzeni, Salvatore Hauptmann
• Primary Examiner(s): Nur, Abdullahi
• Application Number:
  US15/844,228
• Publication Number:
  US 20190186991A1
• Time in Patent Office: 613 Days
• CPC Class Codes: G01J 2003/045 Sequential slits; Multiple slits
• CPC Class Codes: G01J 2003/1842 Types of grating
• CPC Class Codes: G01J 3/0202 Mechanical elements; Supports for optical elements
• CPC Class Codes: G01J 3/021 using plane or convex mirrors, parallel phase plates, or particular reflectors
• CPC Class Codes: G01J 3/0229 using masks, aperture plates, spatial light modulators or spatial filters, e.g. reflective filters
• CPC Class Codes: G01J 3/0235 using means for replacing an element by another, for replacing a filter or a grating
• CPC Class Codes: G01J 3/0237 Adjustable, e.g. focussing
• CPC Class Codes: G01J 3/0256 Compact construction
• CPC Class Codes: G01J 3/0291 Housings; Spectrometer accessories; Spatial arrangement of elements, e.g. folded path arrangements
• CPC Class Codes: G01J 3/04 Slit arrangements slit adjustment
• CPC Class Codes: G01J 3/18 using diffraction elements, e.g. grating gratings per se G02B
• CPC Class Codes: G01J 3/1838 Holographic gratings
• CPC Class Codes: G01J 3/40 Measuring the intensity of spectral lines by determining density of a photograph of the spectrum; Spectrography G01J3/42, G01J3/44 take precedence
• CPC Class Codes: G01J 3/42 Absorption spectrometry; Double beam spectrometry; Flicker spectrometry; Reflection spectrometry beam switching arrangements G01J3/08

Abstract

An optical instrument for spectroscopy applications includes a compact arrangement having a three-dimensional folded optical path. A plate configured as an optical reference plane is secured to a housing and is configured to secure optical components above or below the plate. A modular light source module may be secured within the housing without fasteners. A monochromator and spectrometer are secured below the plate. Mirrors disposed above the plate are configured to direct light from the monochromator passing through a first opening in the plate through a sample disposed above the plate, and to direct light from the sample through a second opening in the plate to the spectrometer. A controller is configured for communication with the monochromator and the spectrometer. The controller may control an entrance slit actuator for the spectrometer and positioning of an aperture upstream of the spectrometer to adjust resolution and throughput.

Claims

1. An optical instrument, comprising:

a housing;

a plate disposed within the housing and configured to secure optical components to either a top surface or a bottom surface of the plate;

a light source;

a detector;

at least one mirror secured to the plate and configured to direct light passing through at least one opening in the plate from the light source to a sample, and to direct light from the sample through the at least one opening in the plate to the detector;

a monochromator; and

a controller configured to communicate with the light source and the detector, wherein the at least one mirror comprises;

a first mirror secured to the bottom surface of the plate and configured to direct light from the light source to an input of the monochromator; and

a second mirror secured to the bottom surface of the plate and configured to direct light from an output of the monochromator through the at least one opening in the plate to one of the at least one mirror, the at least one mirror secured to the top surface of the plate.

2. The optical instrument of claim 1 further comprising a lens secured to the bottom surface of the plate in an optical path between the light source and the first mirror.

3. The optical instrument of claim 1 wherein the light source is disposed below the plate.

4. The optical instrument of claim 1 further comprising a sample holder configured to hold the sample and removably secured to the top surface of the plate.

5. The optical instrument of claim 1, wherein the housing comprises an access panel, and wherein the light source comprises a module having a lamp secured to the module and connected to an electrical connector of the module, the module configured to engage a complementary electrical connector in the housing upon insertion of the module into the housing, the module configured to be removable from the optical instrument through the access panel and secured in the housing by an associated latch.

6. The optical instrument of claim 1 further comprising an absorbance detector in communication with the controller and secured to the top surface of the plate, the absorbance detector positioned in an optical path of light from the light source that passes through the sample.

7. The optical instrument of claim 1 further comprising a reference detector in communication with the controller and secured to the top surface of the plate, the reference detector positioned to receive a portion of light from the light source and provide a corresponding signal to the controller.

8. The optical instrument of claim 1 further comprising:

an aperture positioning mechanism disposed above the top surface of the plate and in communication with the controller, the aperture positioning mechanism configured to selectively position an aperture into, or out of, an optical path between the sample and the detector in response to a positioning signal from the controller, wherein the detector comprises a spectrometer.

9. The optical instrument of claim 8 further comprising a slit plate positioning mechanism in communication with the controller, the slit plate positioning mechanism having a slit plate comprising a plurality of entrance slits having different widths and a common height, the slit plate positioned in the optical path between the sample and the spectrometer, the slit plate positioning mechanism configured to position one of the plurality of entrance slits in the optical path in response to a signal from the controller.

10. The optical instrument of claim 1 wherein the light source includes a spectrometer comprising:

a fixed concave diffraction grating positioned to receive an input light beam after passing through the sample, and to diffract the input light beam at a wavelength-dependent angle; and

a detector positioned to receive light diffracted from the fixed concave diffraction grating and configured to provide signals to the controller in response to the light received from the fixed concave diffraction grating.

11. The optical instrument of claim 1 wherein the housing includes a hinged sample access door selectively openable to access a sample chamber having a bottom defined by the top surface of the plate, the optical instrument further comprising:

a sample tray module configured for insertion into the sample chamber and to position the sample in an optical path between the light source and the detector, the sample tray module having a microcontroller configured to identify the sample tray module and coupled to an associated electrical connector, the associated electrical connector configured to engage a complementary electrical connector connected to the controller and disposed within the sample chamber upon insertion of the sample tray module in the sample chamber.

12. The optical instrument of claim 1 wherein the light source comprises a spectrometer including a fixed concave grating, the spectrometer having a focal length of less than 100 mm.

13. An optical instrument comprising:

a housing having a plate configured as an optical reference plane for one or more optical components of the optical instrument and configured to secure optical components above or below the plate;

a light source disposed in the housing below the plate;

a monochromator disposed below the plate and secured to the plate;

a spectrometer having a fixed concave grating, the spectrometer disposed below the plate and secured to the plate;

one or more mirrors disposed above the plate, secured to the plate, and configured to direct light from the monochromator passing through a first opening in the plate through a sample disposed above the plate, and to direct light from the sample through a second opening in the plate to the spectrometer; and

a controller configured for communication with the monochromator and the spectrometer.

14. The optical instrument of claim 13 further comprising:

an aperture configured for selective positioning either into, or out of, an optical path between the sample and the spectrometer by an actuator in communication with the controller.

15. The optical instrument of claim 14 wherein the aperture is disposed above the plate.

16. The optical instrument of claim 13 further comprising:

a sample tray module configured for insertion into a sample chamber of the housing above the plate to position the sample in an optical path between the monochromator and the spectrometer, the sample tray module having a microcontroller configured to identify the sample tray module and coupled to an electrical connector, the electrical connector configured to engage a complementary electrical connector in the housing within the sample chamber and connected to the controller.

17. The optical instrument of claim 13 wherein the light source comprises:

a module having a lamp secured to the module and connected to an electrical connector of the module, the module configured to engage a complementary electrical connector in the housing upon insertion of the module into the housing, the module configured to be removable from the optical instrument through an access panel of the housing, and secured in the housing without fasteners by an associated latch.

18. The optical instrument of claim 13 further comprising:

an absorbance detector disposed above the plate and secured to the plate, the absorbance detector configured to communicate with the controller and disposed in an optical path of light from the monochromator after passing through the sample; and

a reference detector disposed above the plate and secured to the plate, the reference detector configured to communicate with the controller and configured to receive a portion of light from the monochromator.

19. The optical instrument of claim 13 further comprising:

an actuator associated with a slit plate having a plurality of entrance slits each having a different width and a predetermined height, the actuator disposed below the plate and configured to communicate with the controller to position one of the plurality of entrance slits in an optical path of an input beam to the spectrometer.

20. An optical instrument comprising:

a plate having a first surface and a second surface opposite the first surface;

a first optical component secured to either the first surface or the second surface of the plate;

a second optical component secured to an opposite one of the first and second surfaces of the plate relative to the first optical component, wherein the second optical component comprises at least one of a light source, a detector, a monochromator, and a spectrometer;

at least one mirror secured to the same surface of the plate as the second optical component and configured to direct light from the second optical component through a first opening in the plate; and

at least one mirror secured to the same surface of the plate as the first optical component and configured to direct light from the first opening in the plate to the first optical component, and to direct light from the first optical component through a second opening in the plate.