Method and system for an oxygen sensor

• US 10,386,345 B2
• Filed: 03/19/2015
• Issued: 08/20/2019
• Est. Priority Date: 03/19/2015
• Status: Active Grant

• Current Assignee: Ford Global Technologies, LLC (Ford Motor Company)
• Original Assignee: Ford Global Technologies, LLC (Ford Motor Company)
• Inventors: Hakeem, Mohannad, Anderson, James Eric, Yamada, Shuya Shark, Surnilla, Gopichandra
• Primary Examiner(s): Hossain, Moazzam
• Assistant Examiner(s): Mojaddedi, Omar F
• Application Number:
  US14/663,243
• Publication Number:
  US 20160274073A1
• Time in Patent Office: 1,615 Days
• Field of Search: 702 24
• CPC Class Codes: G01N 2030/8854 involving hydrocarbons
• CPC Class Codes: G01N 30/7206 interfaced to gas chromatograph interfaces in general for introducing or extracting samples to be analysed with specially adapted mass spectrometer, see H01J49/04
• CPC Class Codes: G01N 33/2829 Mixtures of fuels

Abstract

Examples are provided for estimating an amount of fuel in an engine oil and an effect of the fuel on a gas sensor. In one example, an apparatus may include an analyzer to analyze an engine fluid and a computing device operably coupled to the analyzer, the computing device storing non-transitory instructions executable to determine fuel dilution in engine oil based on speciation of hydrocarbons in fuel in the engine oil determined based on output received from the analyzer.

Claims

1. An apparatus, comprising:

an analyzer including a port to receive engine oil from an engine that has undergone fuel combustion, thereby subjecting the engine oil to fuel products, the analyzer configured to measure molecular parameters of each fraction of the engine oil and output the measured molecular parameters; and

a computing device operably coupled to the analyzer, the computing device storing non-transitory instructions executable to;

receive the measured molecular parameters output from the analyzer;

identify one or more individual hydrocarbon species in the fuel products in the engine oil based on the measured molecular parameters received from the analyzer and a model derived from analyzer data collected from a set of known hydrocarbon species; and

output a notification of the identified one or more individual hydrocarbon species for display on a display device.

2. The apparatus of claim 1, wherein the engine oil is sampled from an engine oil sump of the engine, and where the analyzer comprises a gas chromatographer configured to output the measured molecular parameters, the measured molecular parameters including one or more retention times of the engine oil.

3. The apparatus of claim 2, wherein the analyzer further comprises a mass spectrometer to detect output from the gas chromatographer.

4. The apparatus of claim 3, wherein the gas chromatographer outputs a plurality of retention times each corresponding to a fraction of the engine oil, and wherein the instructions are executable to identify at least one hydrocarbon species present in each fraction based at least on a corresponding retention time.

5. The apparatus of claim 4, wherein the instructions are further executable to identify one or more of a molecular weight of that fraction, a boiling point of that fraction, and a vapor pressure of each identified hydrocarbon species in the engine oil.

6. The apparatus of claim 4, wherein the instructions are further executable to identify one or more of a molar concentration, apartial pressure, and a molar fraction of each identified hydrocarbon species in the engine oil.

7. The apparatus of claim 4, wherein the instructions are further executable to identify a molar fraction of each identified hydrocarbon species in a gaseous phase of an engine compartment housing the engine oil sump.

8. The apparatus of claim 7, wherein the instructions are further executable to identify a predicted effect on an oxygen sensor based on the retention time and molar fraction of each identified hydrocarbon species in the gaseous phase.

9. The apparatus of claim 8, wherein the instructions are further executable to output the predicted effect for display on the display device.

10. The apparatus of claim 8, wherein the instructions are executable to:

receive an oxygen concentration measured by the oxygen sensor, the oxygen sensor positioned to sample intake air or exhaust gas of the engine,

determine a difference between the measured oxygen concentration and an expected oxygen concentration determined based on the predicted effect on the oxygen sensor, and

if the difference is greater than a threshold, adjust a calibration value of the oxygen sensor.

11. The apparatus of claim 2, wherein the instructions are further executable to output a concentration of the identified one or more hydrocarbon species for display on the display device.

12. An engine testing apparatus, comprising:

a gas chromatographer mass spectrometer (GC-MS) configured to sample an engine fluid and measure a respective retention time for each of a plurality of fractions of the engine fluid; and

a computing device operably coupled to the GC-MS, the computing device storing non-transitory instructions executable to;

identify one or more hydrocarbon species present in the engine fluid based on each retention time and a model derived from GC-MS data collected from a set of known hydrocarbon species; and

output a notification of the identified one or more hydrocarbon species for display on a display device.

13. The engine testing apparatus of claim 12, wherein the engine fluid is engine oil sampled from an oil sump of an engine that has undergone fuel combustion, thereby providing fuel products to the engine oil, and wherein the identified one or more hydrocarbon species present in the engine oil comprise or are derived from the fuel products.

14. The engine testing apparatus of claim 12, wherein the GC-MS is configured to measure a respective mass spectrometer ion count for each of the plurality of fractions of the engine fluid, and wherein the instructions are further executable to determine a concentration of each identified hydrocarbon species present in the engine fluid based on each retention time and corresponding mass spectrometer ion count.

15. The engine testing apparatus of claim 14, wherein the instructions are further executable to output a notification of an identity and concentration of each identified hydrocarbon species present in the engine fluid for display on the display device.

16. The engine testing apparatus of claim 12, wherein the instructions are further executable to determine a predicted effect on an oxygen sensor based on each retention time and output a notification of the predicted effect for display on the display device.

17. An engine testing apparatus, comprising:

a gas chromatographer mass spectrometer (GC-MS) configured to sample engine oil and determine, for each of a plurality of fractions of the engine oil, a retention time; and

a computing device operably coupled to the GC-MS, the computing device storing non-transitory instructions executable to;

identify one or more hydrocarbon species and a concentration of each identified hydrocarbon species present in the engine oil based on each retention time and a model derived from GC-MS data collected from a set of known hydrocarbon species;

determine a calibration value usable for calibrating an oxygen sensor of a vehicle based on each retention time; and

output a notification of the calibration value for display on a display device.

18. The engine testing apparatus of claim 17, wherein the engine oil is sampled from an oil sump positioned in a crankcase of an engine of the vehicle, and wherein the oxygen sensor is positioned to sample intake air or exhaust gas of the engine.

19. The engine testing apparatus of claim 17, wherein the identifying includes identifying one or more of a molecular weight, a vapor pressure, a boiling point, and a type of hydrocarbon for the one or more hydrocarbon species.