Nested-flow heat exchangers and chemical reactors

• US 10,401,092 B2
• Filed: 03/23/2018
• Issued: 09/03/2019
• Est. Priority Date: 03/12/2015
• Status: Active Grant

• Current Assignee: BayoTech, Inc.
• Original Assignee: BayoTech, Inc.
• Inventors: Vernon, Milton Edward
• Primary Examiner(s): Young, Natasha E
• Application Number:
  US15/934,763
• Publication Number:
  US 20180209743A1
• Time in Patent Office: 529 Days
• CPC Class Codes: B01J 12/007 in the presence of catalytically active bodies, e.g. porous plates
• CPC Class Codes: B01J 2208/00212 Plates; Jackets; Cylinders
• CPC Class Codes: B01J 2208/00309 with two or more reactions in heat exchange with each other, such as an endothermic reaction in heat exchange with an exothermic reaction
• CPC Class Codes: B01J 2208/0053 Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
• CPC Class Codes: B01J 2208/025 Two or more types of catalyst
• CPC Class Codes: B01J 2219/00495 Means for heating or cooling the reaction vessels
• CPC Class Codes: B01J 2219/0072 Organic compounds
• CPC Class Codes: B01J 2219/00745 Inorganic compounds
• CPC Class Codes: B01J 8/008 Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction B01J8/0285, B01J8/067, B01J8/087, B01J8/1836 take precedence
• CPC Class Codes: B01J 8/0257 in a cylindrical annular shaped bed
• CPC Class Codes: B01J 8/0278 Feeding reactive fluids for solid material B01J8/0015
• CPC Class Codes: B01J 8/0285 Heating or cooling the reactor for tubular reactors in furnaces B01J8/062
• CPC Class Codes: B01J 8/0465 the beds being concentric
• CPC Class Codes: C01B 2203/0233 the reforming step being a steam reforming step
• CPC Class Codes: C01B 2203/0283 containing a CO-shift step, i.e. a water gas shift step
• CPC Class Codes: C01B 2203/068 Ammonia synthesis
• CPC Class Codes: C01B 2203/0811 by combustion of fuel
• CPC Class Codes: C01B 2203/1241 Natural gas or methane
• CPC Class Codes: C01B 2203/82 Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
• CPC Class Codes: C01B 3/384 the catalyst being continuously externally heated
• CPC Class Codes: C01B 3/48 : followed by reaction of water vapour with carbon monoxide
• CPC Class Codes: C01C 1/0417 : characterised by the synthesis reactor, e.g. arrangement of catalyst beds and heat exchangers in the reactor arrangement of several reactors C01C1/0405; fixed-bed reactors in general B01J8/02
• CPC Class Codes: C01C 1/0482 : Process control; Start-up or cooling-down procedures
• CPC Class Codes: C05C 9/00 : Fertilisers containing urea or urea compounds
• CPC Class Codes: C07C 273/04 : from carbon dioxide and ammonia
• CPC Class Codes: F28D 2021/0022 : for chemical reactors
• CPC Class Codes: F28D 7/103 : consisting of more than two coaxial conduits or modules of more than two coaxial conduits
• CPC Class Codes: F28D 7/12 : the surrounding tube being closed at one end, e.g. return type F28D7/14 takes precedence
• CPC Class Codes: F28F 1/122 : and being formed of wires
• CPC Class Codes: H01M 2250/10 : Fuel cells in stationary systems, e.g. emergency power source in plant
• CPC Class Codes: H01M 8/0618 : Reforming processes, e.g. autothermal, partial oxidation or steam reforming
• CPC Class Codes: Y02B 90/10 : Applications of fuel cells in buildings
• CPC Class Codes: Y02E 60/50 : Fuel cells
• CPC Class Codes: Y02P 20/10 : Process efficiency
• CPC Class Codes: Y02P 20/141 : Feedstock
• CPC Class Codes: Y02P 20/52 : using catalysts, e.g. selective catalysts

Abstract

Disclosed is a technology based upon the nesting of tubes to provide chemical reactors or chemical reactors with built in heat exchanger. As a chemical reactor, the technology provides the ability to manage the temperature within a process flow for improved performance, control the location of reactions for corrosion control, or implement multiple process steps within the same piece of equipment. As a chemical reactor with built in heat exchanger, the technology can provide large surface areas per unit volume and large heat transfer coefficients. The technology can recover the thermal energy from the product flow to heat the reactant flow to the reactant temperature, significantly reducing the energy needs for accomplishment of a process.

Claims

1. A process of making hydrogen, the process comprising:

flowing a first reactant comprising methane through a first flow path;

flowing a second reactant comprising air through a second flow path;

reacting air and methane to produce an exhaust and an amount of heat;

heating the first reactant and the second reactant with a first portion of the amount of heat;

flowing the exhaust through a third flow path;

flowing a third reactant through a fourth flow path, wherein the third reactant comprises water and methane;

heating the third reactant with a second portion of the amount of heat;

reacting the third reactant to produce a product comprising hydrogen and carbon monoxide;

flowing the product through a fifth flow path; and

transferring heat from the product to the third reactant in the fourth flow path, wherein;

the first flow path, the second flow path, the third flow path, the fourth flow path, and the fifth flow path are coaxial about a longitudinal axis,

the third flow path is in fluid communication with the first flow path and with the second flow path, and

the fourth flow path is in fluid communication with the fifth flow path.

2. The process of claim 1, wherein the product is produced by steam methane reforming using the third reactant.

3. The process of claim 1, wherein:

the third reactant further comprises carbon monoxide, and

the product is produced by the water shift reaction using the third reactant.

4. The process of claim 3, wherein the product is produced by steam methane reforming using the third reactant in addition to the water shift reaction.

5. The process of claim 1, wherein:

the product comprises carbon monoxide and hydrogen.

6. The process of claim 5, wherein:

the product further comprises carbon dioxide.

7. The process of claim 1, wherein reacting the air and methane to produce the exhaust will have an equilibrium level higher than 85% combustion level.

8. The process of claim 1, wherein:

reacting the third reactant to produce the product comprises using a catalyst,

the process further comprising;

maintaining a constant temperature of the third reactant at the catalyst.

9. The process of claim 1, wherein reacting air and methane comprises using a catalyst.

10. The process of claim 1, wherein reacting air and methane is at a temperature greater than 800°

C.

11. The process of claim 1, wherein:

the first reactant, the second reactant, and the third reactant flow in a first direction,

the exhaust and the product flow in a second direction, and

the first direction is a direction opposite the second direction.

12. The process of claim 1, wherein the first flow path, the second flow path, and the third flow path are in a bayonet configuration.

13. The process of claim 1, wherein:

a first tube defines a portion of the first flow path,

a second tube and the first tube define a portion of the second flow path,

a third tube and the second tube define a portion of the third flow path,

a fourth tube and the third tube define a portion of the fourth flow path, and

a fifth tube and the fourth tube define a portion of the fifth flow path.

14. The process of claim 13, wherein:

the first flow path, the second flow path, the third flow path, the fourth flow path, and the fifth flow path are annular flow paths.

15. The process of claim 13, wherein:

the first tube is characterized by a first diameter,

the second tube is characterized by a second diameter,

the third tube is characterized by a third diameter,

the fourth tube is characterized by a fourth diameter,

the fifth tube is characterized by a fifth diameter,

the fifth diameter is greater than the fourth diameter,

the fourth diameter is greater than the third diameter,

the third diameter is greater than the second diameter, and

the second diameter is greater than the first diameter.

16. The process of claim 15, wherein the fifth diameter is in a range from 0.875 inch to 1.375 inch.

17. The process of claim 13, further comprising:

flowing a coolant through a sixth flow path,

transferring heat from the product to the coolant,

wherein;

the fifth tube defines a portion of the sixth flow path.

18. The process of claim 13, wherein:

the portion of the second flow path is a first portion of the second flow path,

a first catalyst defines a second portion of the second flow path,

the portion of the fourth flow path is a first portion of the fourth flow path, and

a second catalyst defines a second portion of the fourth flow path.

19. A process of making hydrogen, the process comprising:

reacting air and methane in a first flow path;

flowing a reactant through an input, the reactant comprising water and methane;

flowing the reactant through a second flow path;

reacting the reactant to produce a product comprising hydrogen;

flowing the product through a third flow path; and

flowing the product through an outlet;

wherein;

a portion of the first flow path is defined by a first tube,

a portion of the second flow path is defined by the first tube and a second tube,

a portion of the third flow path is defined by the second tube and a third tube,

the second flow path and the third flow path are annular flow paths,

the first tube has a first end,

the second tube has a second end,

the third tube has a third end,

the third end is the end of the third tube closest to the first end,

a manifold system is in contact with the first end, the second end, and the third end,

the manifold system comprises a plurality of plates,

the manifold system defines the input and the outlet,

the input is in fluid communication with the second flow path, and

the outlet is in fluid communication with the third flow path.

20. A process of making hydrogen, the process comprising:

flowing a first reactant comprising methane through a first flow path;

flowing a second reactant comprising air through a second flow path;

reacting air and methane to produce an exhaust and an amount of heat;

heating the first reactant and the second reactant with a first portion of the amount of heat;

flowing the exhaust through a third flow path;

flowing a third reactant through a fourth flow path, wherein the third reactant comprises water and methane;

heating the third reactant with a second portion of the amount of heat;

reacting the third reactant to produce a product comprising hydrogen and carbon monoxide;

flowing the product through a fifth flow path; and

transferring heat from the product to the third reactant in the fourth flow path, wherein;

the first flow path, the second flow path, the third flow path, the fourth flow path, and the fifth flow path are coaxial about a longitudinal axis,

a first tube defines a portion of the first flow path,

a second tube and the first tube define a portion of the second flow path,

a third tube and the second tube define a portion of the third flow path,

a fourth tube and the third tube define a portion of the fourth flow path, and

a fifth tube and the fourth tube define a portion of the fifth flow path.