Explosives detection using optical spectroscopy

• US 10,401,297 B2
• Filed: 05/29/2018
• Issued: 09/03/2019
• Est. Priority Date: 04/17/2014
• Status: Active Grant

• Current Assignee: Battelle Memorial Institute
• Original Assignee: Battelle Memorial Institute
• Inventors: Bartko, Andrew P., Ronningen, Theodore J.
• Primary Examiner(s): Jo, Taeho
• Application Number:
  US15/991,885
• Publication Number:
  US 20180306722A1
• Time in Patent Office: 462 Days
• Field of Search: 25033907
• CPC Class Codes: G01N 2021/3595 using FTIR
• CPC Class Codes: G01N 21/35 using infrared light G01N21/39 takes precedence
• CPC Class Codes: G01N 21/64 Fluorescence; Phosphorescence
• CPC Class Codes: G01N 21/6456 Spatial resolved fluorescence measurements; Imaging
• CPC Class Codes: G01N 21/65 Raman scattering
• CPC Class Codes: G01N 33/0057 Warfare agents or explosives
• CPC Class Codes: G01N 33/227 Explosives, e.g. combustive properties thereof

Abstract

Detecting threat materials used in explosives is performed by receiving a sample, and selecting an area of interest on the sample suspected of containing a threat material indicative of an explosive. Detection also includes interrogating the area of interest with a Raman laser producing a Raman spectrum, and comparing an amplitude of a first spectral region in the Raman spectrum to a first predetermined threshold. Detection further includes performing a verification, if the determination indicates that the area of interest includes the threat material, by checking the interrogated area of interest for a secondary indicator of the presence of the threat material, by comparing an amplitude of a second spectral region in the Raman spectrum, which is different from the first spectral region in the Raman spectrum, to a second predetermined threshold, and activating an indicator if the verification indicates that the area of interest contains the threat material.

Claims

1. A method for detecting threat materials used in explosives, comprising:

receiving a sample;

selecting a target location within the sample that distinguishes a target material from an innocuous material;

interrogating the selected target material, with a Raman laser, thereby producing a Raman spectrum;

determining whether the interrogated target material is suspected of being a threat material by comparing an amplitude of a first spectral region in the Raman spectrum, to a first predetermined threshold;

performing a verification, only when the determination indicates that the interrogated target material is suspected of being the threat material, by comparing a second predetermined threshold against an amplitude of a second spectral region in the Raman spectrum measured during the interrogation, where the second spectral region is different from the first spectral region; and

activating an indicator if the verification indicates that the interrogated target material is the threat material.

2. The method of claim 1 further comprising:

selecting a first spectral region to be narrow region that is sufficiently small to capture a single feature;

wherein;

interrogating the selected target material, with a Raman laser, thereby producing a Raman spectrum comprises;

considering only the first spectral region when determining whether the interrogated target material is suspected of being a threat material.

3. The method of claim 1 further comprising predetermining that the threat material is a nitrate.

4. The method of claim 3, wherein:

interrogating the selected target material, with a Raman laser further comprises;

interrogating at least a portion of the Raman spectrum in the first spectral region, which is set to a wave number shift around 1050 cm<sup>−

1</sup>.

5. The method of claim 4, wherein:

determining whether the interrogated target material is suspected of being a threat material by comparing an amplitude of a first spectral region in the Raman spectrum, to a first predetermined threshold comprises;

comparing the amplitude of the measured portion of the Raman spectrum at approximately 1050 cm<sup>−

1</sup> to the predetermined threshold, where the predetermined threshold is set to a value corresponding to a feature in the first spectral range that is indicative of a nitrate.

6. The method of claim 5, wherein:

performing a verification, only when the determination indicates that the interrogated target material is suspected of being the threat material comprises;

interrogating at least a portion of the Raman spectrum measured in the second spectral region, which is set to a wave number shift around 3225 cm<sup>−

1</sup>; and

comparing a second predetermined threshold against an amplitude of a second spectral region in the Raman spectrum measured during the interrogation, which where the second spectral region is different from the first spectral region comprises;

determining if the sample includes ammonium nitrate by comparing the amplitude of the measured portion of the Raman spectrum at approximately 3225 cm<sup>−

1</sup> to the predetermined threshold, where the second threshold is set to a value corresponding to a feature in the second spectral range indicative of ammonium nitrate.

7. The method of claim 5, wherein:

performing a verification, only when the determination indicates that the interrogated target material is suspected of being the threat material comprises;

interrogating at least a portion of the Raman spectrum measured in the second spectral region, which is set to a wave number shift around 550 cm<sup>−

1</sup>; and

comparing a second predetermined threshold against an amplitude of a second spectral region in the Raman spectrum measured during the interrogation, which where the second spectral region is different from the first spectral region comprises;

determining if the sample includes urea nitrate by comparing the amplitude of the measured portion of the Raman spectrum at approximately 550 cm<sup>−

1</sup> to the predetermined threshold, where the second threshold is set to a value corresponding to a feature in the second spectral range indicative of urea nitrate.

8. The method of claim 1, wherein:

interrogating the selected target material, with a Raman laser, thereby producing a Raman spectrum, comprises;

using interferometric spectroscopy to interrogate at least a portion of the selected target material to produce a spectrum of the portion of the selected target material.

9. The method of claim 1, wherein:

interrogating the selected target material, with a Raman laser, thereby producing a Raman spectrum, comprises;

interrogating at least a portion of the sample itself independently of reacted material.

10. The method of claim 1 further comprising detecting crystalline phases of the sample to determine a process of how the sample was created.

11. The method of claim 1, wherein receiving a sample further comprises receiving the sample onto a sample substrate in an open environment.

12. The method of claim 1, wherein receiving a sample further comprises drawing in a fluid stream, which is impacted onto a sample substrate to create the sample.

13. The method of claim 12, wherein receiving a sample further comprises at least one of using a pre-impactor to filter particulates in the fluid stream to a generally predetermined size, and impacting the fluid stream onto a gold sample substrate to create the sample.

14. The method of claim 1, wherein:

selecting a target location within the sample that distinguishes a target material from an innocuous material, comprises;

using a fluorescent device to select a target location by identifying a fluorescing region of the sample.

15. The method of claim 1 further comprising:

outputting an indication of the source of an explosive if threat material indicative of the explosive is detected.

16. The method of claim 15, wherein outputting an indication of the source of an explosive comprises determining at least one of the process and materials used to make the explosive and outputting determination results.

17. The method of claim 1, wherein receiving a sample comprises receiving the sample without perturbing the native state of an explosive being sampled.

18. A system for detecting threat materials used in explosives, comprising:

a sample collector that collects a sample;

a sample stage that receives the sample from the sample collector;

an interrogation station that includes a Raman laser source; and

a processor coupled to memory, where the processor is programmed to interact with the interrogation station to interrogate the sample and select a target location within the sample that distinguishes a target material from an innocuous material;

wherein the processor is further programmed to interact with the interrogation station to;

interrogate, with the Raman laser source, the target material, thereby producing a Raman spectrum;

determine whether the interrogated target material is suspected of being a threat material by comparing an amplitude of a first spectral region in the Raman spectrum, to a first predetermined threshold;

perform a verification, only when the determination indicates that the interrogated target material is suspected of being threat material, by comparing a second predetermined threshold against an amplitude of a second spectral region in the Raman spectrum measured during the interrogation, where the second spectral region is different from the first spectral region; and

activate an indicator if the verification indicates that the interrogated target material is the threat material.