Oxidative coupling of methane for olefin production

• US 10,407,361 B2
• Filed: 03/05/2018
• Issued: 09/10/2019
• Est. Priority Date: 04/13/2016
• Status: Active Grant

• Current Assignee: Lummus Technology LLC
• Original Assignee: Siluria Technologies, Inc. (Lummus Technology LLC)
• Inventors: Radaelli, Guido, Duggal, Suchia, Cizeron, Joel, Schammel, Wayne, Martens, Franciscus J. A.
• Primary Examiner(s): Cheung, William K
• Application Number:
  US15/912,104
• Publication Number:
  US 20180327334A1
• Time in Patent Office: 554 Days
• Field of Search: 526 75
• CPC Class Codes: C07C 11/04 Ethylene
• CPC Class Codes: C07C 11/06 Propene
• CPC Class Codes: C07C 11/08 with four carbon atoms
• CPC Class Codes: C07C 2/08 Catalytic processes
• CPC Class Codes: C07C 2/84 catalytic
• CPC Class Codes: C07C 6/04 at a carbon-to-carbon double bond
• CPC Class Codes: C07C 9/06 Ethane
• CPC Class Codes: C08F 10/02 Ethene
• CPC Class Codes: C08F 10/06 Propene
• CPC Class Codes: F22B 1/16 the heat carrier being hot liquid or hot vapour, e.g. waste liquid, waste vapour
• CPC Class Codes: F22B 37/14 Supply mains, e.g. rising mains, down-comers, in connection with water tubes
• CPC Class Codes: F22B 37/22 Drums; Headers; Accessories therefor making boilers from sheet metal B21D51/24; pressure vessels in general F16J12/00; covers or similar closure members F16J13/00
• CPC Class Codes: F22B 9/00 Steam boilers of fire-tube type, i.e. the flue gas from a combustion chamber outside the boiler body flowing through tubes built-in in the boiler body
• CPC Class Codes: F22G 1/00 Steam superheating characterised by heating method exothermal chemical reactions not involving a supply of free oxygen gas, apparatus or devices for using the heat therefrom F24V30/00
• CPC Class Codes: F22G 1/14 using heat generated by chemical reactions
• CPC Class Codes: F22G 7/00 Steam superheaters characterised by location, arrangement, or disposition
• CPC Class Codes: F28D 2021/0022 for chemical reactors
• CPC Class Codes: F28D 7/10 the conduits being arranged one within the other, e.g. concentrically multiple wall tubes for leak detection F28F1/003
• CPC Class Codes: F28D 7/16 the conduits being arranged in parallel spaced relation F28D7/0008 - F28D7/0058 take precedence; F28D7/02 - F28D7/10 take precedence
• CPC Class Codes: F28F 19/00 Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers
• CPC Class Codes: F28F 9/22 : Arrangements for directing heat-exchange media into successive compartments, e.g. arrangements of guide plates
• CPC Class Codes: F28F 9/26 : Arrangements for connecting different sections of heat-exchange elements, e.g. of radiators connecting different sections in water heaters F24H9/14 , connecting headers with inlet or outlet fittings F28F9/0246
• CPC Class Codes: Y02P 20/52 : using catalysts, e.g. selective catalysts

Abstract

The present disclosure provides natural gas and petrochemical processing systems, including oxidative coupling of methane reactor systems that may integrate process inputs and outputs to cooperatively utilize different inputs and outputs in the production of higher hydrocarbons from natural gas and other hydrocarbon feedstocks. The present disclosure also provides apparatuses and methods for heat exchange, such as an apparatus that can perform boiling and steam super-heating in separate chambers in order to reach a target outlet temperature that is relatively constant as the apparatus becomes fouled. A system of the present disclosure may include an oxidative coupling of methane (OCM) subsystem that generates a product stream comprising compounds with two or more carbon atoms, and a dual compartment heat exchanger downstream of, and fluidically coupled to, the OCM subsystem.

Claims

1. An apparatus for exchanging heat, the apparatus comprising:

a first chamber and a second chamber;

a plurality of tubes configured to contain a process fluid that flows from an inlet in the first chamber to an exit of the second chamber, passing through the first chamber and the second chamber; and

a steam drum configured to contain a liquid phase and a gas phase of a cooling fluid, wherein (i) the steam drum is in fluidic communication with the first chamber such that the liquid phase of the cooling fluid is contacted with an exterior of the plurality of tubes in the first chamber to boil the cooling fluid using heat derived from the process fluid, and (ii) the steam drum is in fluidic communication with the second chamber such that the gas phase of the cooling fluid is contacted with an exterior of the plurality of tubes in the second chamber to super-heat the cooling fluid using heat derived from the process fluid.

2. The apparatus of claim 1, wherein the first chamber shares a wall with the second chamber.

3. The apparatus of claim 1, wherein each of the plurality of tubes comprises a first tube adjoined to a second tube to provide a continuous conduit for the process fluid.

4. The apparatus of claim 3, wherein the first tube passes through the first chamber and the second tube passes through the second chamber, and wherein the first chamber is adjoined to the second chamber.

5. The apparatus of claim 1, wherein the apparatus does not comprise a cross-over duct between the first chamber and the second chamber.

6. The apparatus of claim 1, wherein the first chamber comprises at least one of (a) a down-comer connected to the steam drum to distribute the cooling fluid over the exterior of the plurality of tubes, (b) a riser connected to the steam drum to collect the cooling fluid, and (c) a baffle that supports the plurality of tubes and/or guides the cooling fluid from the down-comer to the riser.

7. The apparatus of claim 6, wherein the apparatus comprises (a), (b) and (c).

8. The apparatus of claim 1, wherein the second chamber comprises a plurality of baffles that supports the plurality of tubes or directs the cooling fluid over the exterior of the plurality of tubes.

9. The apparatus of claim 1, further comprising an atomizer for adding an aerosol of the cooling fluid to the gas phase of the cooling fluid prior to flowing into the second chamber, which atomizer is controlled by a valve that is capable of modulating an amount of the cooling fluid that is super-heated in the second chamber.

10. The apparatus of claim 1, further comprising a valve that is capable of modulating an amount of the gas phase of the cooling fluid that is withdrawn from the steam drum, which valve is capable of modulating an amount of the super-heated cooling fluid that is produced.

11. The apparatus of claim 1, wherein the cooling fluid flows substantially perpendicularly with respect to the process fluid in the first chamber.

12. The apparatus of claim 1, wherein the cooling fluid flows substantially co-currently with the process fluid in the second chamber.

13. The apparatus of claim 1, wherein the first chamber is a fire-tube boiler or the second chamber is a fire-tube steam superheater.

14. A method for exchanging heat, the method comprising:

(a) providing a heat exchanger comprising a first chamber and a second chamber;

(b) flowing a process fluid into the first chamber at an initial temperature;

(c) in the first chamber, decreasing the initial temperature of the process fluid to an intermediate temperature by boiling a first quantity of a cooling fluid using a first quantity of heat derived from the process fluid;

(d) flowing the process fluid into the second chamber at the intermediate temperature; and

(e) in the second chamber, further decreasing the intermediate temperature of the process fluid to an exit temperature to a target temperature by super-heating the boiled cooling fluid from (b) using a second quantity of heat derived from the process fluid,

wherein no more than about 100 milliseconds (ms) of time passes between the process fluid reaching the intermediate temperature and initiation of super-heating the boiled cooling fluid.

15. The method of claim 14, wherein no more than about 10 milliseconds (ms) of time passes between the process fluid reaching the intermediate temperature and initiation of super-heating the boiled cooling fluid.

16. The method of claim 14, wherein a second quantity of the cooling fluid in thermal communication with the process fluid in (c) is not boiled.

17. The method of claim 14, further comprising, when the exit temperature is lower than the target temperature, decreasing the first quantity of the cooling fluid that is boiled, thereby increasing the exit temperature to the target temperature.

18. The method of claim 14, further comprising, when the exit temperature is greater than the target temperature, increasing the first quantity of the cooling fluid that is boiled, thereby decreasing the exit temperature to the target temperature.

19. The method of claim 14, wherein the cooling fluid is super-heated to at least about 500°

C.

20. The method of claim 14, wherein a temperature of the process fluid is decreased from the initial temperature to the target temperature within about 250 milliseconds (ms).