Surface-enhanced Raman scattering element

• US 10,408,761 B2
• Filed: 08/09/2013
• Issued: 09/10/2019
• Est. Priority Date: 08/10/2012
• Status: Active Grant

• Current Assignee: Hamamatsu Photonics KK
• Original Assignee: Hamamatsu Photonics KK
• Inventors: Ito, Masashi, Shibayama, Katsumi, Yokino, Takafumi, Hirose, Masaki, Kawai, Toshimitsu, Ofuji, Kazuto, Maruyama, Yoshihiro
• Primary Examiner(s): Smith, Maurice C
• Application Number:
  US14/420,506
• Publication Number:
  US 20150233831A1
• Time in Patent Office: 2,223 Days
• CPC Class Codes: B82Y 40/00 Manufacture or treatment of nanostructures
• CPC Class Codes: G01N 2021/651 Cuvettes therefore
• CPC Class Codes: G01N 21/658 enhancement Raman, e.g. surface plasmons

Abstract

A surface-enhanced Raman scattering element comprises a substrate having a principal surface; a molded layer having a support part formed on the principal surface of the substrate so as to extend along the principal surface and a fine structure part formed on the support part; a frame part formed on the principal surface of the substrate so as to surround the support part and fine structure part along the principal surface; and a conductor layer formed on at least the fine structure part and constituting an optical functional part for generating surface-enhanced Raman scattering; while the fine structure part are formed integrally with the support part.

Claims

1. A surface-enhanced Raman scattering element comprising:

a substrate having a principal surface;

a molded layer having a support part formed on the principal surface of the substrate so as to extend along the principal surface and a fine structure part formed on the support part;

a frame part formed on the principal surface of the substrate so as to surround the support part and fine structure part along the principal surface; and

a conductor layer formed on at least the fine structure part and constituting an optical functional part for generating surface-enhanced Raman scattering;

wherein the fine structure part is formed integrally with the support part,

wherein a front surface of the support part is formed integrally with the fine structure part, and a rear surface of the support part is joined to the principal surface of the substrate,

wherein the fine structure part includes a plurality of pillars, a thickness of the support part from a front face of the substrate being larger than a column diameter of at least one of the plurality of pillars, a height of at least one of the plurality of pillars being larger than the column diameter of at least one of the plurality of pillars,

wherein the conductor layer reaches the surfaces of the plurality of pillars and a surface of the support part exposed between the plurality of pillars,

wherein the conductor layer is formed on both top surfaces of the pillars and the surface of the support part exposed between the pillars.

2. The surface-enhanced Raman scattering element according to claim 1, wherein the frame part is formed integrally with the support part as the molded layer.

3. The surface-enhanced Raman scattering element according to claim 1, wherein the frame part has a height from the principal surface of the substrate greater than that of the fine structure part from the principal surface of the substrate.

4. The surface-enhanced Raman scattering element according to claim 1, wherein the frame part is constituted by an elastic material.

5. The surface-enhanced Raman scattering element according to claim 1, wherein the fine structure part includes the plurality of pillars erected on the support part;

and

wherein the plurality of pillars are formed integrally with the support part and connected to each other.

6. The surface-enhanced Raman scattering element according to claim 5, wherein, in a direction along the principal surface of the substrate, the frame has a width greater than a thickness of the pillar.

7. The surface-enhanced Raman scattering element according to claim 1, wherein the conductor layer is formed over the fine structure part and frame part.