Extruded lightweight thermal insulating cement-based materials

• US 10,414,692 B2
• Filed: 04/24/2014
• Issued: 09/17/2019
• Est. Priority Date: 04/24/2013
• Status: Active Grant

• Current Assignee: The Intellectual Gorilla GmbH
• Original Assignee: The Intellectual Gorilla GmbH
• Inventors: Daniels, Evan R., Andersen, Per Just
• Primary Examiner(s): Green, Anthony J
• Application Number:
  US14/785,968
• Publication Number:
  US 20160068435A1
• Time in Patent Office: 1,972 Days
• CPC Class Codes: C04B 14/06 Quartz; Sand
• CPC Class Codes: C04B 14/12 Expanded clay
• CPC Class Codes: C04B 14/16 porous, e.g. pumice
• CPC Class Codes: C04B 14/185 expanded
• CPC Class Codes: C04B 14/24 porous, e.g. foamed glass
• CPC Class Codes: C04B 14/28 of calcium
• CPC Class Codes: C04B 14/42 Glass
• CPC Class Codes: C04B 16/0633 Polypropylene
• CPC Class Codes: C04B 16/0641 Polyvinylalcohols; Polyvinylacetates
• CPC Class Codes: C04B 16/065 Polyacrylates; Polymethacrylates
• CPC Class Codes: C04B 18/027 Lightweight materials
• CPC Class Codes: C04B 18/08 Flue dust , i.e. fly ash
• CPC Class Codes: C04B 18/141 Slags
• CPC Class Codes: C04B 18/146 Silica fume
• CPC Class Codes: C04B 18/24 Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper , cork
• CPC Class Codes: C04B 2103/0079 Rheology influencing agents
• CPC Class Codes: C04B 2103/20 Retarders
• CPC Class Codes: C04B 2111/00129 Extrudable mixtures
• CPC Class Codes: C04B 2111/28 Fire resistance, i.e. materials resistant to accidental fires or high temperatures
• CPC Class Codes: C04B 2111/40 Porous or lightweight materials
• CPC Class Codes: C04B 22/143 : Calcium-sulfate
• CPC Class Codes: C04B 2201/32 : for the thermal conductivity, e.g. K-factors
• CPC Class Codes: C04B 24/06 : containing hydroxy groups
• CPC Class Codes: C04B 24/14 : Peptides; Proteins; Derivatives thereof
• CPC Class Codes: C04B 24/38 : Polysaccharides or derivatives thereof C04B24/243 takes precedence
• CPC Class Codes: C04B 24/383 : Cellulose or derivatives thereof
• CPC Class Codes: C04B 28/02 : containing hydraulic cements other than calcium sulfates
• CPC Class Codes: C04B 41/4543 : by spraying, e.g. by atomising
• CPC Class Codes: Y02W 30/91 : Use of waste materials as fillers for mortars or concrete

Abstract

An extrudable cement-based material is formed from a mixture that includes cement in the range of about 40 to 90% by wet weight percent, a lightweight expanded aggregate in the range of about 10 to 60% by wet weight percent, a secondary material in the range of about 0.1 to 50% by wet weight percent, a reinforcement fiber in the range of about 1 to 20% by wet weight percent, a rheology modifying agent in the range of about 0.5 to 10% by wet weight percent, a retarder in the range of about 0.1 to 8% by wet weight percent, and water in the range of 10 to 60% of a total wet material weight.

Claims

1. An extrudable lightweight thermal insulating cement-based material formed from a mixture comprising:

a cement in the range of about 40 to 90% by wet weight percent;

a lightweight expanded aggregate comprising expanded glass, expanded pumice, or a combination thereof in the range of about 5 to 40% by wet weight percent;

a secondary material in the range of about 0.1 to 50% by wet weight percent;

a reinforcement fiber in the range of about 1 to 20% by wet weight percent;

a rheology modifying agent in the range of about 0.5 to 10% by wet weight percent;

a retarder in the range of about 0.1 to 8% by wet weight percent;

a water in the range of 10 to 60% of a total wet material weight; and

the mixture is extrudable.

2. The extrudable lightweight thermal insulating cement-based material as recited in claim 1, the expanded glass or the expanded pumice formed from a mixture comprising:

a ground glass or pumice in the range of about 40 to 60% by weight percent for a slurry;

a water in the range of about 40 to 60% by weight percent for the slurry;

a sodium silicate in the range of about 3 to 15% by weight percent for the slurry;

a NaNO₃ in the range of about 0.1 to 5% for the slurry;

the ground glass or pumice in the range of about 50 to 80% by weight percent for a granulator;

the slurry in the range of about 15 to 50% by weight percent for the granulator; and

wherein the mixture is processed using the slurry and the granulator such that the expanded lightweight aggregate has a maximum final aggregate size.

3. The extrudable lightweight thermal insulating cement-based material as recited in claim 2, the granulator having a ratio of about 1 part slurry to about 2.5 parts ground glass or pumice.

4. The extrudable lightweight thermal insulating cement-based material as recited in claim 1, the expanded glass or the expanded pumice formed from a mixture consisting essentially of:

a ground glass or pumice in the range of about 40 to 60% by weight percent for a slurry;

a water in the range of about 40 to 60% by weight percent for the slurry;

a sodium silicate in the range of about 3 to 15% by weight percent for the slurry;

a NaNO₃ in the range of about 0.1 to 5% for the slurry;

the ground glass or pumice in the range of about 50 to 80% by weight percent for a granulator;

the slurry in the range of about 15 to 50% by weight percent for the granulator; and

wherein the mixture is processed using the slurry and the granulator such that the expanded lightweight aggregate has a maximum final aggregate size.

5. The extrudable lightweight thermal insulating cement-based material as recited in claim 1, the expanded glass or the expanded pumice formed from a mixture comprising:

a ground glass or pumice in the range of about 40 to 60% by weight percent for a slurry;

a water in the range of about 45 to 50% by weight percent for the slurry;

a sodium silicate in the range of about 6 to 7% by weight percent for the slurry;

a NaNO₃ in the range of about 0.9 to 1.1% for the slurry; and

wherein a granulator forms the expanded glass or the expanded pumice using a ratio of 1 part slurry to about 2.5 parts ground glass or pumice.

6. The extrudable lightweight thermal insulating cement-based material as recited in claim 1, the expanded glass or the expanded pumice having a diameter of about 0-8 mm, a bulk density in the range of about 0.10 to 0.5 g/cm³, a effective density in the range of about 0.10 to 0.8 g/cm³, a compressive strength in the range of about 0.5 MPa to 5 MPa, and a heat conductance in the range of about 0.04 to 0.15 W/mK.

7. The extrudable lightweight thermal insulating cement-based material as recited in claim 1, the lightweight expanded aggregate having a particle size comprising about 0-1 mm, 1-2 mm, 2-4 mm, 4-8 mm or a combination thereof.

8. The extrudable lightweight thermal insulating cement-based material as recited in claim 1, the secondary material comprising sand, gypsum, silica fume, fumed silica, fly ash, slag, rock, or a combination thereof.

9. The extrudable lightweight thermal insulating cement-based material as recited in claim 1, the reinforcement fiber comprising cellulose fiber, glass fiber, plastic fiber, polypropylene fiber, polyvinyl alcohol (PVA) fiber, homopolymer acrylic fiber, or a combination thereof.

10. The extrudable lightweight thermal insulating cement-based material as recited in claim 1, the rheology modifying agent comprising a polysaccharide, a polysaccharide derivative, a protein, a protein derivative, a synthetic organic material, a synthetic organic material derivative, or a combination thereof.

11. The extrudable lightweight thermal insulating cement-based material as recited in claim 10, the polysaccharide comprising a cellulose-based material, a cellulose-based material derivative, a starch-based material, a starch-based material derivative, or a combination thereof.

12. The extrudable lightweight thermal insulating cement-based material as recited in claim 11, the cellulose-based material is selected from the group consisting of methylhydroxyethylcellulose (MHEC), hydroxymethylethylcellulose (HMEC), carboxymethylcellulose (CMC), methylcellulose (MC), ethylcellulose (EC), hydroxyethylcellulose (HEC), hydroxyethylpropylcellulose (HEPC) and hydroxypropoylmethylcelluose (HPMC).

13. The extrudable lightweight thermal insulating cement-based material as recited in claim 11, the starch-based material is selected from the group consisting of wheat starch, pre-gelled wheat starch, potato starch, pre-gelled potato starch, amylopectin, amylose, seagel, starch acetates, starch hydroxyethyl ethers, ionic starches, long-chain alkylstarches, dextrins, amine starches, phosphate starches, or dialdehyde starches.

14. The extrudable lightweight thermal insulating cement-based material as recited in claim 1, the retarder comprising sodium citrate, or a mixture of Plaster of Paris, sodium citrate and crystalline silica.

15. The extrudable lightweight thermal insulating cement-based material as recited in claim 1, the extrudable lightweight thermal insulating cement-based material having a density in the range of about 0.2 to 1.0 g/cm³, a compressive strength in the range of about 0.5 MPa to 10 MPa, and a heat conductance in the range of about 0.05 to 0.3 W/mK.

16. An extrudable lightweight thermal insulating cement-based material formed from a mixture consisting essentially of:

a cement in the range of about 40 to 90% by wet weight percent;

a lightweight expanded aggregate comprising expanded glass, expanded pumice, or a combination thereof in the range of about 5 to 40% by wet weight percent;

a secondary material in the range of about 0.1 to 50% by wet weight percent;

a reinforcement fiber in the range of about 1 to 20% by wet weight percent;

a rheology modifying agent in the range of about 0.5 to 10% by wet weight percent;

a retarder in the range of about 0.1 to 8% by wet weight percent;

a water in the range of 10 to 60% of a total wet material weight; and

the mixture is extrudable.

17. A method for manufacturing an extrudable lightweight thermal insulating cement-based material comprising the steps of:

mixing a cement in the range of about 40 to 90% by wet weight percent, a lightweight expanded aggregate comprising expanded glass, expanded pumice, or a combination thereof in the range of about 5 to 40% by wet weight percent, a secondary material in the range of about 0.1 to 50% by wet weight percent, a reinforcement fiber in the range of about 1 to 20% by wet weight percent, a rheology modifying agent in the range of about 0.5 to 10% by wet weight percent and a retarder in the range of about 0.1 to 8% by wet weight percent with water in the range of 10 to 60% of a total wet material weight;

extruding the mixture through a die using an extruder; and

allowing the extruded mixture to set.

18. The method as recited in claim 17, the expanded glass or the expanded pumice formed from a mixture comprising:

a ground glass or pumice in the range of about 40 to 60% by weight percent for a slurry;

a water in the range of about 40 to 60% by weight percent for the slurry;

a sodium silicate in the range of about 3 to 15% by weight percent for the slurry;

a NaNO₃ in the range of about 0.1 to 5% for the slurry;

the ground glass or pumice in the range of about 50 to 80% by weight percent for a granulator;

the slurry in the range of about 15 to 50% by weight percent for the granulator; and

wherein the mixture is processed using the slurry and the granulator such that the expanded lightweight aggregate has a maximum final aggregate size.

19. The method as recited in claim 18, the granulator having a ratio of about 1 part slurry to about 2.5 parts ground glass or pumice.

20. The method as recited in claim 17, the expanded glass or the expanded pumice formed from a mixture consisting essentially of:

a ground glass or pumice in the range of about 40 to 60% by weight percent for a slurry;

a water in the range of about 40 to 60% by weight percent for the slurry;

a sodium silicate in the range of about 3 to 15% by weight percent for the slurry;

a NaNO₃ in the range of about 0.1 to 5% for the slurry;

the ground glass or pumice in the range of about 50 to 80% by weight percent for a granulator;

the slurry in the range of about 15 to 50% by weight percent for the granulator; and

wherein the mixture is processed using the slurry and the granulator such that the expanded lightweight aggregate has a maximum final aggregate size.

21. The method as recited in claim 17, the expanded glass or the expanded pumice formed from a mixture comprising:

a ground glass or pumice in the range of about 40 to 60% by weight percent for a slurry;

a water in the range of about 45 to 50% by weight percent for the slurry;

a sodium silicate in the range of about 6 to 7% by weight percent for the slurry;

a NaNO₃ in the range of about 0.9 to 1.1% for the slurry; and

wherein a granulator forms the expanded glass or the expanded pumice using having a ratio of 1 part slurry to about 2.5 parts ground glass or pumice.

22. The method as recited in claim 17, the expanded glass or the expanded pumice having a diameter of about 0-8 mm, a bulk density in the range of about 0.10 to 0.5 g/cm³, a effective density in the range of about 0.10 to 0.8 g/cm³, a compressive strength in the range of about 0.5 MPa to 5 MPa, and a heat conductance in the range of about 0.04 to 0.15 W/mK.

23. The method as recited in claim 17, further comprising, prior to mixing the cement, the step of making the lightweight expanded aggregate comprising the steps of:

mixing a ground glass or pumice in the range of about 40 to 60% by weight percent with water in the range of about 40 to 60% by weight percent to produce a slurry;

adding a sodium silicate in the range of about 3 to 15% by weight percent to the slurry;

adding a NaNO₃ in the range of about 0.1 to 5% to the slurry;

forming aggregates in a granulator by feeding the ground glass or pumice in the range of about 50 to 80% by weight percent with the slurry in the range of about 15 to 50% by weight percent;

drying the formed aggregates;

heating the dried aggregates together with about 30% finely ground kaolin to a temperature of about 800 to 1400 degrees Celsius; and

cooling the heated aggregates.

24. The method as recited in claim 17, the lightweight expanded aggregate having a particle size comprising about 0-1 mm, 1-2 mm, 2-4 mm, 4-8 mm or a combination thereof.

25. The method as recited in claim 17, the secondary material comprising sand, gypsum, silica fume, fumed silica, fly ash, slag, rock, or a combination thereof.

26. The method as recited in claim 17, the reinforcement fiber comprising cellulose fiber, glass fiber, plastic fiber, polypropylene fiber, polyvinyl alcohol (PVA) fiber, homopolymer acrylic fiber, or a combination thereof.

27. The method as recited in claim 17, the rheology modifying agent comprising a polysaccharide, a polysaccharide derivative, a protein, a protein derivative, a synthetic organic material, a synthetic organic material derivative, or a combination thereof.

28. The method as recited in claim 27, the polysaccharide comprising a cellulose-based material, a cellulose-based material derivative, a starch-based material, a starch-based material derivative, or a combination thereof.

29. The method as recited in claim 28, the cellulose-based material is selected from the group consisting of methylhydroxyethylcellulose (MHEC), hydroxymethylethylcellulose (HMEC), carboxymethylcellulose (CMC), methylcellulose (MC), ethylcellulose (EC), hydroxyethylcellulose (HEC), hydroxyethylpropylcellulose (HEPC) and hydroxypropoylmethylcelluose (HPMC).

30. The method as recited in claim 28, the starch-based material is selected from the group consisting of wheat starch, pre-gelled wheat starch, potato starch, pre-gelled potato starch, amylopectin, amylose, seagel, starch acetates, starch hydroxyethyl ethers, ionic starches, long-chain alkylstarches, dextrins, amine starches, phosphate starches, or dialdehyde starches.

31. The method as recited in claim 17, the retarder comprising sodium citrate, or a mixture of Plaster of Paris, sodium citrate and crystalline silica.

32. The method as recited in claim 17, the extruded mixture having a density in the range of about 0.2 to 1.0 g/cm³, a compressive strength in the range of about 0.5 MPa to 10 MPa, and a heat conductance in the range of about 0.05 to 0.3 W/mK after being set, cured or dried.

33. The method as recited in claim 17, wherein the extruded mixture is allowed to set for 2 to 3 hours.

34. The method as recited in claim 17, further comprising the step of curing the extruded mixture.

35. The method as recited in claim 17, further comprising the step of drying the extruded mixture.

36. The method as recited in claim 17, further comprising the step of molding, cutting, trimming, sanding or routing the extruded mixture into a specified shape.

37. The method as recited in claim 17, further comprising the step of spraying the extruded mixture with a water repellent.