Method and device for remelting and/or remelt-alloying metallic materials, in particular Nitinol

• US 10,422,018 B2
• Filed: 05/01/2014
• Issued: 09/24/2019
• Est. Priority Date: 05/17/2013
• Status: Active Grant

• Current Assignee: G. Rau GmbH & Co. KG
• Original Assignee: G. Rau GmbH & Co. KG
• Inventors: Sedlmayr, Gerhard
• Primary Examiner(s): McGuthry-Banks, Tima M.
• Application Number:
  US14/891,600
• Publication Number:
  US 20160151178A1
• Time in Patent Office: 1,972 Days
• CPC Class Codes: B23K 15/0046 Welding
• CPC Class Codes: B23K 15/0086 welding for purposes other than joining, e.g. built-up welding
• CPC Class Codes: B23K 26/703 Cooling arrangements by using a fluid stream B23K26/14
• CPC Class Codes: B23K 37/003 Cooling means
• CPC Class Codes: C21D 1/04 with simultaneous application of supersonic waves, magnetic or electric fields
• CPC Class Codes: C21D 1/09 by direct application of electrical or wave energy; by particle radiation
• CPC Class Codes: C21D 2201/01 Shape memory effect
• CPC Class Codes: C22B 9/223 by laser beams working by laser beam B23K26/00
• CPC Class Codes: C22B 9/226 by electric discharge, e.g. plasma C22B9/20 takes precedence; apparatus therefor H01J, H05B, H05H; chemical reactions with metals in a plasma C22B4/005
• CPC Class Codes: C22B 9/228 by particle radiation, e.g. electron beams
• CPC Class Codes: C22F 1/006 Resulting in heat recoverable alloys with a memory effect
• CPC Class Codes: C22F 3/00 Changing the physical structure of non-ferrous metals or alloys by special physical methods, e.g. treatment with neutrons
• CPC Class Codes: C22F 3/02 by solidifying a melt controlled by supersonic waves or electric or magnetic fields

Abstract

A method and an apparatus for producing metallic semi-finished products by means of remelting and/or remelt-alloying. Here, the material is melted selectively locally in a melting capillary in the material volume by means of high-energy, focused radiation, the melting capillary is moved through the material and the material is cooled down at a high cooling rate by means of a cooled heat sink, which is located close to the melting capillary and coupled to the material in a well heat-conductive manner.

Claims

1. A method for producing metallic semi-finished products by remelting and/or remelt-alloying of metallic materials, wherein solidification of the melt is effected by a cooling device, the method comprising:

selectively remelting a portion of a desired area of a material volume of an initial semi-finished product locally in a melting capillary via focused radiation;

dissipating heat from the melting capillary via a non-remelted portion of the desired area of the material volume that is adjacent to the melting capillary;

cooling the non-remelted portion of the desired area of the material volume, substantially simultaneously with the remelting of the portion of the desired area of the material volume by the focused radiation, via at least one heat sink in order to further dissipate the heat from the melting capillary to the non-remelted portion of the desired area of the material volume, the heat sink being cooled by a cooling liquid;

coupling the heat sink to at least one part of at least one surface of the desired area of the material volume in a heat-conductive manner, the at least one part of the at least one surface being located close to a focus of the focused radiation on the desired area of the material volume or close to the melting capillary in the desired area of the material volume, respectively; and

moving the focus of the focused radiation over the desired area of the material volume or moving the melting capillary through the desired area of the material volume, respectively, for successively remelting an entirety of the desired area of the material volume, wherein the focus of the focused radiation and the material volume are moved relative to one another such that the desired area of the material volume is swept over by the focus,

wherein the heat sink is a clamping device made of a heat-conductive material and that engages around the initial semi-finished product, the initial semi-finished product being clamped inside of the clamping device.

2. The method according to claim 1, wherein an electron beam, laser beam, ion beam or plasma beam is used as the focused radiation.

3. The method according to claim 1, wherein one of a plate-shaped material, a strip-shaped material, a rod-shaped material, a round rod-shaped material, a wire-shaped material, a bolt-shaped material or a tube-shaped material is remelted or remelt-alloyed as the initial semi-finished product.

4. The method according to claim 1, wherein a material made of Nitinol is remelted or remelt-alloyed.

5. The method according to claim 1, wherein the heat sink is configured as a gas cooling or a liquid cooling heat sink only.

6. The method according to claim 1, wherein the heat sink includes a heat-conductive material of copper or silver.

7. The method according to claim 1, wherein one of a rod-shaped material, a wire-shaped material, a bolt-shaped material or a tube-shaped material is processed as the initial semi-finished product.

8. The method according to claim 1, wherein the initial semi-finished product is pulled out or pushed out of the clamping device in an axial direction while being processed with the focused radiation.

9. The method according to claim 1, wherein the initial semi-finished product is rotated around a longitudinal axis of the initial semi-finished product while being processed with the focused radiation.

10. A method for producing metallic semi-finished products by remelting and/or remelt-alloying of metallic materials, wherein solidification of the melt is effected by a cooling device, the method comprising:

selectively remelting a portion of a desired area of a material volume of an initial semi-finished product locally in a melting capillary via focused radiation;

dissipating heat from the melting capillary via a non-remelted portion of the desired area of the material volume that is adjacent to the melting capillary;

cooling the non-remelted portion of the desired area of the material volume, substantially simultaneously with the remelting of the portion of the desired area of the material volume by the focused radiation, via at least one heat sink in order to further dissipate the heat from the melting capillary to the non-remelted portion of the desired area of the material volume, the heat sink being cooled by a cooling liquid;

coupling the heat sink to at least one part of at least one surface of the desired area of the material volume in a heat-conductive manner, the at least one part of the at least one surface being located close to a focus of the focused radiation on the desired area of the material volume or close to the melting capillary in the desired area of the material volume, respectively; and

moving the focus of the focused radiation over the desired area of the material volume or moving the melting capillary through the desired area of the material volume, respectively, for successively remelting an entirety of the desired area of the material volume, wherein the focus of the focused radiation and the material volume are moved relative to one another such that the desired area of the material volume is swept over by the focus,

wherein the heat sink includes a heat-conductive material of copper or silver, and

wherein the heat sink is formed to the material volume.

11. The method according to claim 10, wherein a cooling jacket made of a pipe or a cooling core made of a core or a pipe is used as the heat sink formed to the material volume.

12. A method for producing metallic semi-finished products by remelting and/or remelt-alloying of metallic materials, wherein solidification of the melt is effected by a cooling device, the method comprising:

selectively remelting a portion of a desired area of a material volume of an initial semi-finished product locally in a melting capillary via focused radiation;

dissipating heat from the melting capillary via a non-remelted portion of the desired area of the material volume that is adjacent to the melting capillary;

cooling the non-remelted portion of the desired area of the material volume, substantially simultaneously with the remelting of the portion of the desired area of the material volume by the focused radiation, via at least one heat sink in order to further dissipate the heat from the melting capillary to the non-remelted portion of the desired area of the material volume, the heat sink being cooled by a cooling liquid;

coupling the heat sink to at least one part of at least one surface of the desired area of the material volume in a heat-conductive manner, the at least one part of the at least one surface being located close to a focus of the focused radiation on the desired area of the material volume or close to the melting capillary in the desired area of the material volume, respectively; and

moving the focus of the focused radiation over the desired area of the material volume or moving the melting capillary through the desired area of the material volume, respectively, for successively remelting an entirety of the desired area of the material volume, wherein the focus of the focused radiation and the material volume are moved relative to one another such that the desired area of the material volume is swept over by the focus,

wherein a tube-shaped material is processed as the initial semi-finished product, and wherein a pipe formed of a heat-conductive material, which is flown-though by a cooling liquid, is used as the heat sink for the tube-shaped material.

13. A method for producing metallic semi-finished products by remelting and/or remelt-alloying of metallic materials, wherein solidification of the melt is effected by a cooling device, the method comprising:

selectively remelting a portion of a desired area of a material volume of an initial semi-finished product locally in a melting capillary via focused radiation;

dissipating heat from the melting capillary via a non-remelted portion of the desired area of the material volume that is adjacent to the melting capillary;

cooling the non-remelted portion of the desired area of the material volume, substantially simultaneously with the remelting of the portion of the desired area of the material volume by the focused radiation, via at least one heat sink in order to further dissipate the heat from the melting capillary to the non-remelted portion of the desired area of the material volume, the heat sink being cooled by a cooling liquid;

coupling the heat sink to at least one part of at least one surface of the desired area of the material volume in a heat-conductive manner, the at least one part of the at least one surface being located close to a focus of the focused radiation on the desired area of the material volume or close to the melting capillary in the desired area of the material volume, respectively; and

moving the focus of the focused radiation over the desired area of the material volume or moving the melting capillary through the desired area of the material volume, respectively, for melting successively remelting an entirety of the desired area of the material volume, wherein the focus of the focused radiation and the material volume are moved relative to one another such that the desired area of the material volume is swept over by the focus,

wherein a plate-shaped or a strip-shaped material is processed as the initial semi-finished product, and wherein opposed clamping plates made of a heat-conductive material of a holding device are used as the heat sink, between which clamping plates the initial semi-finished product is clamped-in or guided through under pressure, and the initial semi-finished product is processed by a melting capillary formed between the clamping plates, which melting capillary is moved through the initial semi-finished product in the longitudinal direction of the semi-finished product.

14. The method according to claim 13, wherein, after processing of the initial semi-finished product, a second semi-finished product made of the same material is clamped between the clamping plates next to the already-processed initial semi-finished product and a layer-type initial semi-finished product is formed and processed with a melting capillary.

15. The method according to claim 13, wherein the initial semi-finished product is clamped between the clamping plates and processed, which initial semi-finished product has an arrangement in layers of initial semi-finished products placed adjacent to one another made of different materials.

16. A method for producing metallic semi-finished products by remelting and/or remelt-alloying of metallic materials, wherein solidification of the melt is effected by a cooling device, the method comprising:

selectively remelting a portion of a desired area of a material volume of an initial semi-finished product locally in a melting capillary via focused radiation;

dissipating heat from the melting capillary via a non-remelted portion of the desired area of the material volume that is adjacent to the melting capillary;

cooling the non-remelted portion of the desired area of the material volume, substantially simultaneously with the remelting of the portion of the desired area of the material volume by the focused radiation, via at least one heat sink in order to further dissipate the heat from the melting capillary to the non-remelted portion of the desired area of the material volume, the heat sink being cooled by a cooling liquid;

coupling the heat sink to at least one part of at least one surface of the desired area of the material volume in a heat-conductive manner, the at least one part of the at least one surface being located close to a focus of the focused radiation on the desired area of the material volume or close to the melting capillary in the desired area of the material volume, respectively; and

moving the focus of the focused radiation over the desired area of the material volume or moving the melting capillary through the desired area of the material volume, respectively, for successively remelting an entirety of the desired area of the material volume, wherein the focus of the focused radiation and the material volume are moved relative to one another such that the desired area of the material volume is swept over by the focus,

wherein a bolt-shaped material is processed as an initial semi-finished product, wherein a cooling jacket made of a heat-conductive material and enclosing the bolt-shaped material on its shell surface is used as the heat sink and the focus of the focused radiation is moved over a face side of the initial semi-finished product.

17. An apparatus for producing metallic semi-finished products by remelting and/or remelt-alloying of metallic materials, wherein solidification of the melt is effected by a cooling device, the apparatus comprising:

a radiation device for generating a focused radiation which is configured to selectively locally remelt a portion of a desired area of a material volume of an initial semi-finished product in a melting capillary, wherein dissipation of heat from the melting capillary is effected via a non-remelted portion of the desired area of the material volume that is adjacent to the melting capillary;

a cooling device for cooling at least one heat sink, which is configured for further dissipating the heat from the melting capillary to the non-remelted portion of the desired area of the material volume by cooling the non-remelted portion of the desired area of the material volume down via the heat sink, while at the same time the portion of the desired area of the material volume is remelted by the focused radiation,

wherein the heat sink is adapted to be coupled to at least one part of at least one surface of the desired area of the material volume in a heat-conductive manner and the heat sink is adapted to be cooled by means of a cooling liquid,

wherein the at least one part of the at least one surface of the desired area of the material volume is located close to the focus of the focused radiation on the desired area of the material volume or close to the melting capillary in the desired area of the material volume, respectively,

wherein, for successively remelting an entirety of the desired area of the material volume, the focus of the focused radiation is movable over the desired area of the material volume or the melting capillary is movable through the desired area of the material volume, respectively,

wherein the focus of the focused radiation and the material volume are moveable relative to one another such that the desired area of the material volume is swept over by the focus, and

wherein the heat sink is a clamping device made of a heat-conductive material and that engages around the initial semi-finished product, the initial semi-finished product being clamped inside of the clamping device.