Systems and methods for ammonia recovery, acid gas separation, or combination thereof
First Claim
Patent Images
1. A process for separating or recovering basic gases comprising:
- (a) absorbing ammonia from an ammonia containing gas stream into an ammonia-lean, an ammonia-ultra-lean, or ammonia-free solution, to form an ammonia-rich solution;
(b) enriching said ammonia-rich solution with one or more acid gases to form an ammonia rich, acid gas rich solution; and
(c) concentrating said ammonia rich, acid gas rich solution using one or more membranes to form a retentate and a permeate wherein said permeate is suitable for use as at least a portion of the ammonia-ultra-lean or ammonia-free solution in step (a);
wherein one or more solutions comprise urea.
1 Assignment
0 Petitions
Accused Products
Abstract
The present invention relates to processes and systems for ammonia recovery and/or acid-gas separation. In some embodiments, a system for acid gas separation may be integrated with an ammonia abatement cycle employing a high temperature absorber. In some embodiments, a system for acid gas separation may employ a higher temperature absorber due to the lower energy consumption and cost of the integrated ammonia abatement cycle. Advantageously, heat may be recovered from the absorber to power at least a portion of any acid gas desorption in the process. Reverse osmosis or other membranes may be employed.
13 Citations
17 Claims
-
1. A process for separating or recovering basic gases comprising:
-
(a) absorbing ammonia from an ammonia containing gas stream into an ammonia-lean, an ammonia-ultra-lean, or ammonia-free solution, to form an ammonia-rich solution; (b) enriching said ammonia-rich solution with one or more acid gases to form an ammonia rich, acid gas rich solution; and (c) concentrating said ammonia rich, acid gas rich solution using one or more membranes to form a retentate and a permeate wherein said permeate is suitable for use as at least a portion of the ammonia-ultra-lean or ammonia-free solution in step (a); wherein one or more solutions comprise urea. - View Dependent Claims (2, 3, 4, 5, 6)
-
-
7. An integrated process for separating or recovering basic gases comprising:
-
(1) a first cycle comprising; absorbing ammonia from an ammonia containing gas stream into an ammonia-lean solution, forming an ammonia-rich solution; enriching said ammonia rich solution with one or more acid gases; precipitating one or more ammonia-acid gas salts wherein said precipitating occurs during enriching, after enriching, or a combination thereof; and separating at least a portion of said precipitate from any remaining liquid; and (2) a second cycle comprising; (a) absorbing ammonia from an ammonia containing gas stream into an ammonia-lean, an ammonia-ultra-lean, or ammonia-free solution, to form an ammonia-rich solution; (b) enriching said ammonia-rich solution with one or more acid gases to form an ammonia-rich, acid gas rich solution; and (c) concentrating said ammonia-rich, acid gas rich solution using one or more membranes to form a retentate and a permeate wherein said permeate is suitable for use as at least a portion of the ammonia-ultra-lean or ammonia-free solution in step (a) of the second cycle. - View Dependent Claims (8, 9, 10, 11, 12, 13, 14, 15, 16, 17)
-
Specification