Processing routes for titanium and titanium alloys

• US 10,435,775 B2
• Filed: 09/17/2013
• Issued: 10/08/2019
• Est. Priority Date: 09/15/2010
• Status: Active Grant

• Current Assignee: ATI Properties LLC (CNH Industrial N.V.)
• Original Assignee: ATI Properties LLC (CNH Industrial N.V.)
• Inventors: Forbes Jones, Robin M., Mantione, John V., DeSouza, Urban J., Thomas, Jean-Philippe, Minisandram, Ramesh S., Kennedy, Richard L., Davis, R. Mark
• Primary Examiner(s): Yang, Jie
• Application Number:
  US14/028,588
• Publication Number:
  US 20140076471A1
• Time in Patent Office: 2,212 Days
• Field of Search: 148670
• CPC Class Codes: B21J 1/003 Selecting material
• CPC Class Codes: B21J 1/025 affecting grain orientation
• CPC Class Codes: B21J 1/06 Heating or cooling methods or arrangements specially adapted for performing forging or pressing operations B21J5/063 takes precedence
• CPC Class Codes: C22C 14/00 Alloys based on titanium
• CPC Class Codes: C22F 1/183 of titanium or alloys based thereon

Abstract

Methods of refining the grain size of titanium and titanium alloys include multiple upset and draw forging. Titanium and titanium alloy workpieces are heated to a workpiece forging temperature within a workpiece forging temperature range in the alpha+beta phase field. The workpiece may comprise a starting cross-sectional dimension. The workpiece is upset forged in the workpiece forging temperature range. After upsetting, the workpiece is multiple pass draw forged in the workpiece forging temperature range. Multiple pass draw forging may comprise incrementally rotating the workpiece in a rotational direction followed by draw forging the workpiece after each incremental rotation. Incrementally rotating and draw forging the workpiece is repeated until the workpiece comprises substantially the same starting cross-sectional dimension.

Claims

1. A method of refining grain size in a workpiece comprising a metallic material selected from titanium and a titanium alloy, the method comprising:

heating the workpiece to a beta soaking temperature;

holding the workpiece at the beta soaking temperature for a beta soaking time sufficient to form a 100% beta phase microstructure in the workpiece;

cooling the workpiece to room temperature;

heating the workpiece to a workpiece forging temperature in a workpiece forging temperature range within an alpha+beta phase field of the metallic material, wherein the workpiece comprises a starting cross-sectional dimension;

upset forging the workpiece within the workpiece forging temperature range; and

multiple pass draw forging the workpiece within the workpiece forging temperature range;

wherein multiple pass draw forging comprises incrementally rotating an entirety of the workpiece in a rotational direction followed by draw forging the workpiece after each incremental rotation;

wherein incrementally rotating and draw forging is repeated until a true strain of at least 3.5 is achieved in the workpiece; and

wherein the workpiece is not heated during the multiple pass draw forging.

2. The method of claim 1, wherein a strain rate used in upset forging and draw forging is the range of 0.001 s⁻

1 to 0.02 s<sup>−

1</sup>, inclusive.

3. The method of claim 1, wherein the workpiece comprises a cylindrical workpiece, and wherein incrementally rotating and draw forging further comprises rotating an entirety of the cylindrical workpiece in 15°

increments followed by draw forging after each rotation, until the cylindrical workpiece is rotated through 360°

.

4. The method of claim 1, wherein the workpiece comprises a right octagonal workpiece, and wherein incrementally rotating and draw forging further comprises rotating an entirety of the octagonal workpiece in 45°

increments followed by draw forging after each rotation, until the right octagonal workpiece is rotated through 360°

.

5. The method of claim 1, wherein the workpiece comprises a titanium alloy selected from the group consisting of an alpha titanium alloy, an alpha+beta titanium alloy, a metastable beta titanium alloy, and a beta titanium alloy.

6. The method of claim 1, wherein the workpiece comprises an alpha+beta titanium alloy.

7. The method of claim 1, wherein the workpiece comprises one of ASTM Grade 5, 6,12, 19, 20, 21, 23, 24, 25, 29, 32, 35, 36, and 38 titanium alloys.

8. The method of claim 1, wherein the beta soaking temperature is in a temperature range of the beta transus temperature of the metallic material up to 300°

F. (111°

C.) above the beta transus temperature of the metallic material, inclusive.

9. The method of claim 1, wherein the beta soaking time is from 5minutes to 24 hours.

10. The method of claim 1, further comprising plastically deforming the workpiece at a plastic deformation temperature in the beta phase field of the metallic material prior to cooling the workpiece to room temperature.

11. The method of claim 10, wherein plastically deforming the workpiece comprises at least one of drawing, upset forging, and high strain rate multi-axis forging the workpiece, and wherein high strain rate multi-axis forging the workpiece comprises multi-axis forging at a strain rate of 0.2 s⁻

to 0.8 s<sup>−

1</sup>.

12. The method of claim 10, wherein the plastic deformation temperature is in a plastic deformation temperature range of the beta transus temperature of the metallic material up to 300°

F. (111°

C.) above the beta transus temperature of the metallic material, inclusive.

13. The method of claim 10, wherein plastically deforming the workpiece comprises multiple upset and draw forging, and wherein cooling the workpiece to room temperature comprises air cooling the workpiece.

14. The method of claim 1, wherein the workpiece forging temperature range is 100°

F. (55.6°

C.) below a beta transus temperature of the metallic material to 700°

F. (388.9°

C.) below the beta transus temperature of the metallic material, inclusive.

15. The method of claim 1, further comprising repeating the heating, upset forging, and multiple pass draw forging until a true strain of at least 10 is achieved in the workpiece.

16. The method of claim 15, wherein on completion of the method a metallic material microstructure comprises ultra fine grain sized alpha grains having alpha grain sizes of 4 μ

m or less.

17. The method of claim 1, further comprising, subsequent to multiple pass draw forging the workpiece within the workpiece forging temperature range:

cooling the workpiece to a temperature within a second workpiece temperature range in the alpha+beta phase field of the metallic material;

upset forging the workpiece within the second workpiece forging temperature range;

multiple pass draw forging the workpiece within the second workpiece forging temperature range;

wherein multiple pass draw forging comprises incrementally rotating the entirety of the workpiece in a rotational direction followed by draw forging the titanium alloy workpiece after each rotation; and

wherein incrementally rotating and draw forging is repeated until the workpiece comprises the starting cross-sectional dimension; and

repeating the upset forging and the multiple pass draw forging within the second workpiece forging temperature range until a true strain of at least 10 is achieved in the workpiece.

18. The method of claim 17, wherein a strain rate used in upset forging and draw forging is the range of 0.001 s⁻

1 to 0.02 s<sup>−

1</sup>, inclusive.

19. A method of refining grain size in a workpiece comprising a metallic material selected from titanium and a titanium alloy, the method comprising:

heating the workpiece to a beta soaking temperature range from the beta transus temperature of the metallic material to 300°

F. (111°

C.) above the beta transus temperature of the metallic material;

holding the workpiece within the beta soaking temperature range for time sufficient to form a 100% beta phase microstructure in the workpiece;

cooling the workpiece;

heating the workpiece to a workpiece forging temperature range within an alpha+beta phase field of the metallic material, wherein the workpiece comprises a starting cross-sectional dimension;

upset forging the workpiece within the workpiece forging temperature range; and

multiple pass draw forging the workpiece within the workpiece forging temperature range;

wherein multiple pass draw forging comprises incrementally rotating an entirety of the workpiece in a rotational direction followed by draw forging the workpiece after each incremental rotation;

wherein incrementally rotating and draw forging is repeated until a true strain of at least 3.5 is achieved in the workpiece; and

wherein the workpiece is not heated during the multiple pass draw forging.

20. The method of claim 19, wherein a strain rate used in upset forging and draw forging is the range of 0.001 s⁻

1 to 0.02 s<sup>—

1</sup>, inclusive.

21. The method of claim 19, wherein the workpiece comprises a cylindrical workpiece, and wherein incrementally rotating and draw forging further comprises rotating an entirety of the cylindrical workpiece in 15°

increments followed by draw forging after each rotation, until the cylindrical workpiece is rotated through at least 360°

.

22. The method of claim 19, wherein the workpiece comprises a titanium alloy selected from the group consisting of an alpha titanium alloy, an alpha+beta titanium alloy, a metastable beta titanium alloy, and a beta titanium alloy.

23. The method of claim 19, wherein the workpiece comprises one of ASTM Grade 5, 6,12, 19, 20, 21, 23, 24, 25, 29, 32, 35, 36, and 38 titanium alloys.

24. The method of claim 19, wherein the workpiece is held within the beta soaking temperature range for 5 minutes to 24 hours.

25. The method of claim 19, wherein the workpiece forging temperature range is 100°

F. (55.6°

C.) below a beta transus temperature of the metallic material to 700°

F. (388.9°

C.) below the beta transus temperature of the metallic material, inclusive.

26. The method of claim 19, further comprising repeating the heating, upset forging, and multiple pass draw forging until a true strain of at least 10 is achieved in the workpiece.