Lubricants with calcium and magnesium-containing detergents and their use for improving low-speed pre-ignition and for corrosion resistance

• US 10,443,558 B2
• Filed: 01/18/2017
• Issued: 10/15/2019
• Est. Priority Date: 01/18/2017
• Status: Active Grant

• Current Assignee: Afton Chemical Corporation
• Original Assignee: Afton Chemical Corporation
• Inventors: Ransom, Paul, Carpentier, Guillaume, Fletcher, Kristin
• Primary Examiner(s): Toomer, Cephia D
• Application Number:
  US15/409,509
• Publication Number:
  US 20180201860A1
• Time in Patent Office: 1,000 Days
• CPC Class Codes: C10M 159/20 Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
• CPC Class Codes: C10M 159/22 containing phenol radicals
• CPC Class Codes: C10M 159/24 containing sulfonic radicals
• CPC Class Codes: C10M 2207/028 Overbased salts thereof
• CPC Class Codes: C10M 2215/28 Amides; Imides
• CPC Class Codes: C10M 2219/046 Overbasedsulfonic acid salts
• CPC Class Codes: C10M 2227/00 Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
• CPC Class Codes: C10N 2010/04 Groups 2 or 12
• CPC Class Codes: C10N 2010/12 Groups 6 or 16
• CPC Class Codes: C10N 2030/12 Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
• CPC Class Codes: C10N 2030/44 Boron free or low content boron compositions
• CPC Class Codes: C10N 2030/52 Base number [TBN]
• CPC Class Codes: C10N 2030/54 Fuel economy
• CPC Class Codes: C10N 2030/76 Reduction of noise, shudder, or vibrations
• CPC Class Codes: C10N 2040/25 Internal-combustion engines
• CPC Class Codes: C10N 2040/255 Gasoline engines
• CPC Class Codes: C10N 2060/14 by boron or a compound containing boron
• CPC Class Codes: F02P 5/02 non-automatically; dependent on position of personal controls of engine, e.g. throttle position

Abstract

A lubricating oil composition and method of operating a boosted internal combustion engine with reduced low-speed pre-ignition events and corrosion resistance. The oil composition includes a base oil, one or more overbased calcium sulfonate detergents, one or more overbased calcium phenate detergents, and one or more overbased magnesium-containing detergents. A ratio of ppm of calcium to TBN of the oil composition is less than 170; a ratio of ppm of magnesium to total soap content in wt. % is greater than 700; and there are limited amounts of boron and molybdenum, and all weight percentages and ppm values being based on the total weight of the oil composition. The compositions give low LSPI ratios and pass the Ball Rust test.

Claims

1. A lubricating oil composition comprising:

greater than 50 wt. % of a base oil of lubricating viscosity, based on a total weight of the lubricating oil composition;

one or more overbased calcium sulfonate detergents having a total base number of greater than 225 mg KOH/g, measured by the method of ASTM D-2896;

one or more overbased calcium phenate detergents having a total base number of greater than 170 mg KOH/g, measured by the method of ASTM D-2896; and

one or more overbased magnesium-containing detergents; and

;

wherein a ratio of the amount of calcium in ppm by weight, based on the total weight of the lubricating oil composition to a total base number of the lubricating oil composition measured by the method of ASTM D-2896, is less than 170;

a ratio of magnesium in ppm by weight, based on a total weight of the lubricating oil composition, to total soap content in wt. %, based on a total weight of the lubricating oil composition, is greater than 700;

an amount of boron in the lubricating oil composition is up to 75 ppm by weight, based on the total weight of the lubricating oil composition; and

an amount of molybdenum in the lubricating oil composition is less than 330 ppm by weight, based on the total weight of the lubricating oil composition.

2. The lubricating oil composition of claim 1, wherein the base oil is at least one selected from the group consisting of a Group II base oil, a Group III base oil, a Group IV base oil and a Group V base oil.

3. The lubricating oil composition of claim 1, wherein the lubricating oil composition is an engine oil composition and is effective to reduce a number of low-speed pre-ignition events in a boosted internal combustion engine lubricated with the engine oil composition relative to a number of low-speed pre-ignition events in the same engine lubricated with reference lubricating oil C-1.

4. The engine oil composition of claim 3, wherein the reduction in the number of low-speed pre-ignition events is greater than a 50% reduction and the low-speed pre-ignition events are low-speed pre-ignition counts during 25,000 engine cycles, wherein the engine is operated at 2000 revolutions per minute with a brake mean effective pressure of 1,800 kPa.

5. The engine oil composition of claim 3, wherein the reduction in the number of low-speed pre-ignition events is greater than an 85% reduction and the low-speed pre-ignition events are low-speed pre-ignition counts during 25,000 engine cycles, wherein the engine is operated at 2000 revolutions per minute with a brake mean effective pressure of 1,800 kPa.

6. The lubricating oil composition of claim 1, wherein the one or more overbased magnesium-containing detergents have a total base number of greater than 225 mg KOH/g and are selected from the group consisting of an overbased magnesium sulfonate detergent, an overbased magnesium phenate detergent, an overbased magnesium salicylate detergent and mixtures thereof.

7. The lubricating oil composition of claim 1, wherein the total magnesium provided to the lubricating oil composition by the overbased magnesium detergent is from 100 ppm to 1500 ppm, by weight, based on the total weight of the lubricating oil composition.

8. The lubricating oil composition of claim 1, wherein the total calcium provided to the lubricating oil composition by the combination of the one or more overbased calcium phenate and the one or more overbased calcium sulfonate detergents is from 800 ppm to 2400 ppm, by weight, based on the total weight of the lubricating oil composition.

9. The lubricating oil composition of claim 1, wherein the lubricating oil composition has a total base number of greater than 7.0 mg KOH/g of the lubricating oil composition.

10. The lubricating oil composition of claim 1, wherein the ratio of calcium in ppm to the total base number of the lubricating oil composition is 50 to 165.

11. The lubricating oil composition of claim 1, wherein the ratio of magnesium in ppm to total soap content in wt. % is 700 to 2500.

12. The lubricating oil composition of claim 1, wherein the amount of molybdenum in the lubricating oil composition is from 1 to 200 ppm by weight.

13. The lubricating oil composition of claim 1, wherein a total TBN contribution of all detergents to the lubricating oil composition is greater than 4.5 mg KOH/g of the lubricating oil composition.

14. The lubricating oil composition of claim 1, wherein the lubricating oil composition is an engine oil composition that passes the Ball Rust test, as determined by the method of ASTM D-6557.

15. A method for reducing a number of low-speed pre-ignition events in a boosted internal combustion engine comprising steps of:

lubricating a boosted internal combustion engine with a lubricating oil composition comprising;

greater than 50 wt. % of a base oil of lubricating viscosity, based on a total weight of the lubricating oil composition;

one or more overbased calcium sulfonate detergents having a total base number of greater than 225 mg KOH/g,

one or more overbased calcium phenate detergents having a total base number of greater than 170 mg KOH/g, and

one or more overbased magnesium-containing detergents; and

wherein a ratio of an amount of calcium in ppm to a total base number of the lubricating oil composition measured by the method of ASTM D-2896 is less than 170;

a ratio of magnesium in ppm by weight, based on a total weight of the lubricating oil composition to total soap content in wt. %, based on a total weight of the lubricating oil composition is greater than 700;

an amount of boron in the lubricating oil composition is up to 75 ppm by weight, based on a total weight of the lubricating oil composition; and

an amount of molybdenum in the lubricating oil composition is less than 330 ppm by weight, based on a total weight of the lubricating oil composition; and

operating the engine lubricated with the lubricating oil composition.

16. The method of claim 15, wherein the lubricating oil composition is an engine oil composition which passes a Ball Rust Test according to ASTM D6557 and the number of low-speed pre-ignition events in the boosted internal combustion engine lubricated with the engine oil composition are reduced relative to a number of low-speed pre-ignition events in the same engine lubricated with reference lubricating oil C-1.

17. The method of claim 15, wherein the lubricating oil composition is an engine oil composition and the number of low-speed pre-ignition events are based on low-speed pre-ignition counts during 25,000 engine cycles, wherein the engine is operated at 2000 revolutions per minute with a brake mean effective pressure of 1,800 kPa.

18. The method of claim 15, wherein an amount of the one or more magnesium-containing detergents is not more than 2 wt. %, based on the total weight of the lubricating oil composition.

19. The method of claim 15, wherein an amount of overbased calcium sulfonate and an amount of overbased calcium phenate combine to make up not more than 2.0 wt. % of the total weight of the lubricating oil composition.

20. The method of claim 15, wherein the lubricating step lubricates a combustion chamber or cylinder walls of a spark-ignited direct injection engine provided with a turbocharger or a supercharger or spark-ignited port fuel injection internal combustion engine provided with a turbocharger or a supercharger.

21. The method of claim 20, further comprising a step of measuring the number of low-speed pre-ignition events of the internal combustion engine lubricated with the lubricating oil composition.

22. The method of claim 15, wherein the lubricating oil composition has a total base number of greater than 7.0 mg KOH/g of the lubricating oil composition, as measured by the method of ASTM D-2896.