Nonaqueous electrolyte secondary battery

• US 10,446,824 B2
• Filed: 11/15/2011
• Issued: 10/15/2019
• Est. Priority Date: 11/15/2011
• Status: Active Grant

• Current Assignee: Toyota Jidosha Kabushiki Kaisha (Toyota Motor Corporation)
• Original Assignee: Toyota Jidosha Kabushiki Kaisha (Toyota Motor Corporation)
• Inventors: Morita, Masahiro, Fukumoto, Yusuke
• Primary Examiner(s): Carrico, Robert S
• Application Number:
  US14/358,163
• Publication Number:
  US 20140322600A1
• Time in Patent Office: 2,891 Days
• CPC Class Codes: H01M 10/0525 Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• CPC Class Codes: H01M 10/4235 Safety or regulating additives or arrangements in electrodes, separators or electrolyte H01M10/4242 takes precedence
• CPC Class Codes: H01M 2200/10 Temperature sensitive devices
• CPC Class Codes: H01M 2220/20 Batteries in motive systems, e.g. vehicle, ship, plane
• CPC Class Codes: H01M 4/13 Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
• CPC Class Codes: H01M 4/622 being polymers
• CPC Class Codes: H01M 50/581 in response to temperature
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product
• CPC Class Codes: Y02T 10/70 Energy storage systems for electromobility, e.g. batteries

Abstract

A nonaqueous electrolyte secondary battery in accordance with the present invention is provided with an electrode body 20 including a positive electrode 30 and a negative electrode 50, and a nonaqueous electrode. The electrode body 20 is constituted by a plurality of different constituent members. At least two constituent members among the plurality of constituent members constituting the electrode body 20 include respective particulate polymers 38, 28 having a melting point within a temperature range from 80° C. to 120° C., with these two members being different from each other. The electrode body 20 is provided with the positive electrode 30 including a positive electrode active material layer 34 on a positive electrode collector 32, the negative electrode 50 including a negative electrode active material layer 54 on a negative electrode collector 52, separators 70A, 70B interposed between the positive electrode 30 and the negative electrode 50, and nonaqueous electrolyte. It is preferred that two or all of the positive electrode 30, the negative electrode 50, and the separators 70A, 70B include the particulate polymers 38, 78.

Claims

1. A nonaqueous electrolyte secondary battery, comprising:

an electrode body including a positive electrode, a negative electrode, and a separator interposed between the positive electrode and the negative electrode; and

a nonaqueous electrolyte;

wherein

the electrode body has a band-shape and is wound to form a wound electrode body,

the positive electrode comprises a positive electrode collector, a positive electrode active material layer, and a conductive intermediate layer between the positive electrode collector and the positive electrode active material layer, the conductive intermediate layer including an electrically insulating first particulate polymer, a conductive material separate from the electrically insulating first particulate polymer, and a first binder, the conductive intermediate layer having a thickness of less than or equal to 2 μ

m, and the electrically insulating first particulate polymer having an average particle diameter in a range from 0.1 μ

m to 3.0 μ

m,

the negative electrode comprises a negative electrode collector and a negative electrode active material layer on the negative electrode collector,

the separator includes a separator main body made of a polyolefin resin having a shutdown function, and a heat resistance layer including an inorganic filler, a second particulate polymer and a second binder on at least one surface of the separator main body,

a ratio of the electrically insulating first particulate polymer is in the range of from 10% by mass to 30% by mass when the total content ratio of the conductive intermediate layer is 100% by mass,

a ratio of the second particulate polymer is in the range of from 10% by mass to 40% by mass when the total content ratio of the heat resistance layer is 100% by mass, a melting point of the electrically insulating first particulate polymer and the second particulate polymer is within a temperature range from 80°

C. to 120°

C. respectively,

the melting point of the electrically insulating first particulate polymer and the melting point of the second particulate polymer differ from each other, and the melting point of the first particulate polymer is lower than the melting point of the second particulate polymer,

a melting point of the separator main body is higher than that of the melting point of the second particulate polymer, and

at least one of the positive electrode active material layer and the negative electrode also includes the electrically insulating first particulate polymer.

2. The nonaqueous electrolyte secondary battery according to claim 1, wherein a D₅₀ particle diameter of the inorganic filler contained in the heat resistance layer is 0.5 μ

m to 5.0 μ

m, and a D₅₀ particle diameter of the electrically insulating first particulate polymer contained in the heat resistance layer is 0.1 μ

m to 3.0 μ

m.

3. The nonaqueous electrolyte secondary battery according to claim 1, wherein a porosity of the entire separator is 30% to 70%.

4. A vehicle provided with the nonaqueous electrolyte secondary battery according to claim 1.