Fuel-cell system and method of generating energy from crude fuel

• US 10,446,852 B2
• Filed: 03/14/2017
• Issued: 10/15/2019
• Est. Priority Date: 03/14/2016
• Status: Active Grant

• Current Assignee: Iowa State University Research Foundation Incorporated (Iowa State University)
• Original Assignee: Iowa State University Research Foundation Incorporated (Iowa State University)
• Inventors: Li, Wenzhen, Benipal, Neeva, Qi, Ji, Qiu, Yang
• Primary Examiner(s): Fraser, Stewart A
• Application Number:
  US15/458,202
• Publication Number:
  US 20170263945A1
• Time in Patent Office: 945 Days
• CPC Class Codes: H01M 4/9041 Metals or alloys H01M4/92 takes precedence
• CPC Class Codes: H01M 4/9083 on carbon or graphite
• CPC Class Codes: H01M 4/926 on carbon or graphite
• CPC Class Codes: H01M 4/96 Carbon-based electrodes
• CPC Class Codes: H01M 8/0239 Organic resins; Organic polymers
• CPC Class Codes: H01M 8/1009 with one of the reactants being liquid, solid or liquid-charged H01M8/12 takes precedence
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

The present invention relates to a fuel-cell system. This system includes an anode electrode; a cathode electrode; a separator positioned between the anode electrode and the cathode electrode, wherein the separator is not an ion exchange membrane; an anode catalyst; and a cathode catalyst, wherein the cathode catalyst is a non-precious metal catalyst or metal-free catalyst. The present invention also relates to a method of generating energy from crude fuel. This method involves providing a fuel-cell system and contacting the fuel-cell system with a crude fuel under conditions effective to generate energy from the crude fuel.

Claims

1. A fuel-cell system, comprising:

an anode electrode;

a cathode electrode;

a separator positioned between the anode electrode and the cathode electrode, wherein the separator is not an ion exchange membrane;

an anode catalyst; and

a cathode catalyst, wherein the cathode catalyst is a metal-free catalyst comprising a doped carbon material, wherein the carbon material is duel-doped with nitrogen and sulfur.

2. The fuel-cell system of claim 1, wherein the separator comprises perfluorinated hydrocarbon.

3. The fuel-cell system of claim 1, wherein the separator is porous, and wherein pores have an average diameter of less than 1.0 micrometer.

4. The fuel-cell system of claim 1, wherein the anode catalyst is a low-loading precious metal anode catalyst.

5. The fuel-cell system of claim 4, wherein the anode catalyst is selected from the group consisting of a noble metal alloy;

dealloyed Pt-M, wherein M is a transition metal;

nanoparticles supported on carbon nanotubes or carbon black; and

noble metal or a mixture of noble metals supported on carbon nanotubes or carbon black.

6. The fuel-cell system of claim 5, wherein the anode catalyst is a noble metal supported on carbon nanotubes or carbon black, and the noble metal is selected from the group consisting of Pd, Ag, Au, and Pt.

7. The fuel-cell system of claim 5, wherein the anode catalyst is a mixture of noble metals supported on carbon nanotubes or carbon black, and the mixture of noble metals is selected from the group consisting of Pd/Ag, Pd/Au, and Pd/Pt.

8. The fuel-cell system of claim 1 further comprising:

a fuel source comprising carbon fuel.

9. The system according to claim 8, wherein the fuel is a crude carbon fuel.

10. The system according to claim 9, wherein the crude fuel is selected from the group consisting of biomass/biorefinery/pyrolytic feedstock, wastes, and residuals;

biomass/biorefinery/pyrolytic streams;

bio-oils; and

unrefined biomass-derived feedstocks.

11. The system according to claim 9, wherein the crude fuel is crude glycerol, crude pyrolytic streams, or crude bio-ethanol.

12. A method of generating energy from crude fuel comprising:

providing a fuel-cell system according to claim 1 and

contacting the fuel-cell system with a crude fuel to generate energy from the crude fuel.

13. The method according to claim 12, wherein the crude fuel is selected from the group consisting of biomass/biorefinery/pyrolytic feedstock, wastes, and residuals;

biomass/biorefinery/pyrolytic streams;

bio-oils; and

unrefined biomass-derived feedstocks.

14. The method according to claim 12, wherein the crude fuel is crude glycerol, crude pyrolytic streams, or crude bio-ethanol.

15. The method according to claim 12, wherein the crude fuel is bio-oil derived from the pyrolysis of lignocellulosic biomass.

16. The method according to claim 12, wherein the separator comprises perfluorinated carbon.

17. The method according to claim 12, wherein the separator is porous, and wherein pores have an average diameter of less than 1.0 micrometer.

18. The method according to claim 12, wherein the anode catalyst is a low-loading precious metal anode catalyst.

19. The method according to claim 18, wherein the anode catalyst is selected from the group consisting of a noble metal alloy;

dealloyed Pt-M, wherein M is a transition metal;

nanoparticles supported on carbon nanotubes or carbon black; and

noble metal or a mixture of noble metals supported on carbon nanotubes or carbon black.

20. The method according to claim 19, wherein the anode catalyst is a noble metal supported on carbon nanotubes or carbon black, and the noble metal is selected from the group consisting of Pd, Ag, Au, and Pt.

21. The method according to claim 19, wherein the anode catalyst is a mixture of noble metals supported on carbon nanotubes or carbon black, and the mixture of noble metals is selected from the group consisting of Pd/Ag, Pd/Au, and Pd/Pt.