Method for forming a layer of coloured glass on a glass substrate by flame pyrolysis

• US 10,450,222 B2
• Filed: 10/08/2014
• Issued: 10/22/2019
• Est. Priority Date: 10/09/2013
• Status: Active Grant

• Current Assignee: Saint-Gobain Glass France (Compagnie De Saint-Gobain)
• Original Assignee: Saint-Gobain Glass France (Compagnie De Saint-Gobain)
• Inventors: Aguiar, Rosiana
• Primary Examiner(s): Del Sole, Joseph S
• Assistant Examiner(s): Ahmed Ali, Mohamed K
• Application Number:
  US15/023,261
• Publication Number:
  US 20160236976A1
• Time in Patent Office: 1,840 Days
• CPC Class Codes: C03C 1/008 for the production of films or coatings
• CPC Class Codes: C03C 17/02 with glass C03C17/34, C03C17/44 take precedence
• CPC Class Codes: C03C 2217/72 Decorative coatings
• CPC Class Codes: C03C 2218/15 from the vapour phase
• CPC Class Codes: C03C 3/078 containing an oxide of a divalent metal, e.g. an oxide of zinc
• CPC Class Codes: C03C 3/089 containing boron
• CPC Class Codes: C03C 4/02 for coloured glass

Abstract

A process includes the formation of a colored glass layer on a glass substrate by flame pyrolysis of a solution including at least one precursor of a cobalt, iron, manganese, chromium, silver, copper, gold or selenium oxide, alone or as a mixture of several of them. Moreover, a glass substrate is coated with a layer of colored glass obtained by such a process.

Claims

1. A process comprising depositing a colored glass layer on a surface of a glass substrate by flame pyrolysis of a solution comprising at least one first precursor of a cobalt, iron, manganese, chromium, silver, copper, gold or selenium oxide, alone or as a mixture of several of them, said solution further comprising a second precursor of SiO₂ and at least one third precursor selected from the group consisting of B₂O₃, Na₂O, LiO, CaO and any combination thereof, wherein the depositing includes

introducing said solution including the first, second and third precursors into a burner and then decomposing the first, second and third precursors in solution in the burner to form silicate glass nanoparticles including SiO₂ and at least one material selected from the group consisting of B₂O₃, Na₂O, LiO, CaO and any combination thereof and then depositing the silicate glass nanoparticles on said glass substrate at a temperature between ambient temperature and 500°

C. to form the colored glass layer on the surface of the glass substrate, said colored glass layer consisting of said glass nanoparticles.

2. The process as claimed in claim 1, wherein said first precursors consist of organometallic compounds and/or salts.

3. The process as claimed in claim 1, wherein said first precursors are soluble in alcoholic solution.

4. The process as claimed in claim 1, wherein a distance from the burner to the glass substrate is at most equal to 10 mm.

5. A glass substrate coated with a layer of colored glass obtained by a process as claimed in claim 1, wherein a thickness of the layer of colored glass is between 50 and 10 000 nm.

6. The process as claimed in claim 1, wherein the solution including the first, second and third precursors introduced into the burner includes tetraethoxysilane (TEOS), aluminum tri(sec-butoxide), triethoxyborane, magnesium methoxyethoxide, calcium methoxyethoxide, potassium t-butoxide and cobalt acetyl acetonate.

7. The process as claimed in claim 1, wherein the solution including the first, second and third precursors introduced into the burner includes tetraethoxysilane (TEOS), triethoxyborane, sodium nitrate, lithium ethoxide and cobalt acetylacetonate.

8. The process as claimed in claim 1, wherein the solution including the first, second and third precursors introduced into the burner includes tetraethoxysilane (TEOS), triethoxyborane, sodium nitrate, lithium ethoxide, cobalt acetylacetonate and calcium methoxyethoxide.