Membrane cartridge system

• US 10,456,750 B2
• Filed: 05/20/2014
• Issued: 10/29/2019
• Est. Priority Date: 06/12/2013
• Status: Active Grant

• Current Assignee: Evonik Operations GmbH (Rag-Stiftung)
• Original Assignee: Evonik Fibres Gmbh (Rag-Stiftung)
• Inventors: Visser, Tymen, Pedersen, Steven K.
• Primary Examiner(s): Shumate, Anthony R
• Application Number:
  US14/898,093
• Publication Number:
  US 20160151744A1
• Time in Patent Office: 1,988 Days
• CPC Class Codes: B01D 2313/04 Specific sealing means
• CPC Class Codes: B01D 2313/041 Gaskets or O-rings
• CPC Class Codes: B01D 2313/042 Adhesives or glues
• CPC Class Codes: B01D 2313/21 Specific headers, end caps
• CPC Class Codes: B01D 2313/44 Cartridge types
• CPC Class Codes: B01D 63/022 Encapsulating hollow fibres
• CPC Class Codes: B01D 63/0221 using a mould
• CPC Class Codes: B01D 63/04 comprising multiple hollow fibre assemblies

Abstract

The present invention is related to a new membrane cartridge system comprising hollow fiber membranes, a special new end cap for the production of the new cartridge, membrane separation devices comprising the new membrane cartridges and a process for manufacture of the new cartridges.

Claims

1. A cartridge element comprising a bundle of hollow fiber type membranes aligned in a cylindrical cartridge tube, tube sheets at each end of the membrane bundle, and end caps at each end of the cartridge tube, wherein

the cartridge tube has a wall thickness of 0.5 to 10 mm and comprises at least one fluid inlet or fluid outlet opening arranged between the end caps,

the end caps are made of a polymeric material

the end caps are permanently fixed to the cartridge element,

the tube sheets comprise a potting resin and are permanently fixed to the cartridge element, and

at least one end cap is partially slid onto or into the cartridge tube, said end cap comprises a cylindrical section with an inner diameter which is wider than an outer diameter of the cartridge tube or a cylindrical section with an outer diameter which is narrower than an inner diameter of the cartridge tube, and said cylindrical section of the end cap comprises spacers that center the cap onto or into the cartridge tube and leave space between the cartridge tube and the cylindrical section of the end cap which can be filled with said potting resin.

2. The cartridge element according to claim 1, wherein at least one end cap is fixed to the cartridge element by building a multi-layer composite structure which comprises:

a cap layer which is formed by the end cap

a fixing layer between the end cap and the cartridge tube, preferably composed of the same resin also used to form the tube sheet

a tube layer, formed by the cartridge tube, and

a tube sheet layer, formed by the potting resin and the fiber bundle.

3. The cartridge element according to claim 2, wherein the cartridge tube comprises at least one opening, arranged in a region where the cartridge tube is covered by one of said end caps, which opening allows the potting resin to penetrate through the cartridge tube into a hollow space between the cartridge tube and the end cap.

4. The cartridge element according to claim 1, wherein

the at least one end cap comprises a first cylindrical section with an inner diameter which is wider than an outer diameter of the cartridge tube and a second cylindrical section with an inner diameter smaller than that of the first cylindrical section, so that the second cylindrical section cannot be slid onto the cartridge tube;

or

the end cap comprises a first cylindrical section with an outer diameter which is smaller than an inner diameter of the cartridge tube and a second cylindrical section with an outer diameter larger than that of the first cylindrical section, so that the second cylindrical section cannot be slid into the cartridge tube.

5. The cartridge element according to claim 1, wherein the at least one end cap comprises a cylindrical section which is slid onto the cartridge tube and an additional cylindrical section which is not slid over the cartridge tube and is slid over a part of the hollow fiber membrane bundle protruding from the cartridge tube.

6. The cartridge element according to claim 1, wherein the cartridge tube has at least one of the following properties:

the cartridge tube is made of a metal, preferably stainless steel or aluminum;

the cartridge tube has a wall thickness of 1 to 5 mm;

the cartridge tube has an inner diameter that is between 10 and 250 mm.

7. The cartridge element according to claim 1, wherein the potting resin is selected from the group consisting of epoxy resins and polyurethane resins, preferably of a resin having one, particular preferred at least one, most preferred all of the following properties:

A glass transition temperature >

80°

C.;

Flat sample bars (according to standard test ASTM D648-07) made from the potting resin have a flexural strength >

70 MPa at room temperature;

Flat sample bars (according to standard test ASTM D648-07) made from the potting resin have a elongation at break >

8%;

the potting resin starts curing at temperatures below 40°

C.;

a fully cured potting made in a mould having an inner diameter of 110 mm and filled with approximately 500 grams of resin and optional fibers has a shrinkage below 0.5%;

the potting resin has a gel time of >

1 hour;

the potting resin has a viscosity after mixing of resin and a hardener of <

2000 mPas;

if the resin comprises a filler, the filler does not segregate upon centrifuging with 20 to 40G.

8. The cartridge element according to claim 1 wherein the end caps of said cartridge element according to claim 1 is/are made of a polymer or polymer blend, which is optionally filled with up to 30% by weight of glass fibers or other reinforcing materials and which polymer or polymer blend is selected from polyphenylene sulfide or a blend of polyphenylene oxide and polystyrene.

9. A membrane separation device comprising a cartridge element according to claim 1.

10. The membrane separation device according to claim 9, comprising in addition

a single or multi cartridge housing, and

O-rings arranged between each end cap of the cartridge element and the cartridge housing to separate feed and permeate atmospheres.

14. The cartridge element according to claim 1 wherein the end caps of said cartridge element are made of a polymer or polymer blend or polymer mixture, which is optionally filled with up to 30% by weight of glass fibers or other reinforcing materials, said polymer or polymer blend or polymer mixture possessing one of the following properties:

it is injection mouldable;

its maximum thermal expansion coefficient is 1×

10<sup>−

4</sup> 1/K;

its heat deflection temperature up to which the material keeps it shape is at least 140°

C.;

end caps made of the polymer or polymer blend or polymer mixture have a shrinkage of less than 1%.

11. A process for manufacture of hollow fiber cartridge elements comprising the steps

a) providing a bundle of hollow fiber membranes and a cylindrical cartridge tube with at least one fluid inlet or fluid outlet opening

b) sliding the membrane bundle into the cartridge tube

c) mounting plastic end caps on both sides of the assembly of step b), partially sliding at least one end cap onto or into the cartridge tube;

said end cap comprising a cylindrical section with an inner diameter which is wider than an outer diameter of the cartridge tube or a cylindrical section with an outer diameter which is narrower than an inner diameter of the cartridge tube, and said cylindrical section of the end cap comprising spacers that center the cap onto or into the cartridge tube and leave space between the cartridge tube and the cylindrical section of the end cap,

d) placing the assembly obtained in step c) into a centrifuge in a manner that ensures that the assembly is held together

e) filling a potting resin into both end caps and curing during centrifugation

f) cutting off the end parts of both end caps to open the bores of the hollow fiber membranes.

12. The process according to claim 11, wherein it comprises at least one of the following additional steps

placing a porous material, preferably a mesh;

between the outer surface of the bundle of hollow fiber membranes and the inner surface of the cartridge tube;

closing off the ends of the fibers with wax or an epoxy or polyurethane resin before potting;

pre-treating at least those parts of the surface of the end cap that get into contact with the potting resin with a flame or chemically, preferably with an acid, or mechanically, preferably by sand blasting, to purify the surface and optionally to roughen it in order to improve its adhesion to the cartridge element;

pre-filling the end caps before centrifugation starts;

heating the cartridge before and during cutting off to a temperature above the glass transition temperature of the cured potting resin.

13. The process according to claim 11 wherein centrifugation is done at 200 to 350 rpm and at a temperature between 5 and 40°

C.