Reactor and reaction system based on supercritcal water oxidation, and phenolic wastewater treatment method

• US 10,457,579 B2
• Filed: 03/06/2019
• Issued: 10/29/2019
• Est. Priority Date: 09/06/2016
• Status: Active Grant

• Current Assignee: Guangzhou Institute of Advanced Technology
• Original Assignee: Guangzhou Institute of Advanced Technology
• Inventors: Zhang, Fengming, Su, Chuangjian, Chen, Jiulin, Yang, Jie, Jia, Cuijie, Chen, Shunquan, Huang, Zhenfei
• Primary Examiner(s): Stelling, Lucas A
• Application Number:
  US16/293,703
• Publication Number:
  US 20190248685A1
• Time in Patent Office: 237 Days
• CPC Class Codes: B01J 19/0073 Sealings sealings for pressure vessels per se F16J15/00
• CPC Class Codes: B01J 19/26 Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
• CPC Class Codes: B01J 3/008 Processes carried out under supercritical conditions
• CPC Class Codes: C02F 1/02 by heating methods of steam generation F22B; preheating boiler feed-water or accumulating preheated boiler feed-water F22D
• CPC Class Codes: C02F 1/04 by distillation or evaporation
• CPC Class Codes: C02F 1/441 by reverse osmosis
• CPC Class Codes: C02F 1/58 by removing specified dissolved compounds using ion-exchange C02F1/42; softening water C02F5/00
• CPC Class Codes: C02F 1/72 by oxidation C02F1/4672 takes precedence
• CPC Class Codes: C02F 1/727 using pure oxygen or oxygen rich gas
• CPC Class Codes: C02F 11/086 in the supercritical state
• CPC Class Codes: C02F 2101/345 Phenols
• CPC Class Codes: C02F 2201/003 Coaxial constructions, e.g. a cartridge located coaxially within another
• CPC Class Codes: C02F 2201/004 Seals, connections
• CPC Class Codes: C02F 2201/005 Valves
• CPC Class Codes: C02F 2209/02 Temperature
• CPC Class Codes: C02F 2301/066 Overpressure, high pressure
• CPC Class Codes: Y02P 20/54 using solvents, e.g. supercritical solvents or ionic liquids

Abstract

The present invention relates to the technical field of wastewater treatment. In the present invention, the reactor is provided with a double-shell reactor, a coaxial nozzle, an inner shell structure, evaporated water injection pipes and the like, so it is assured that the wastewater is inject into the reactor at a room temperature and is degraded thoroughly; moreover, with the evaporated water, the corrosion, salt deposition and local overheating in the reactor are prevented, so that the reaction process is guaranteed to be stable and reliable. and through a fuel system, a hydrothermal flame is formed in the reactor, so that the concentrated waste liquid injected into the reactor at the room temperature can be preheated to a supercritical reaction temperature, and the waste liquid is prevented from coking, scaling and the like in a preheating stage.

Claims

1. A reactor based on supercritical water oxidation, comprising an inner shell and an outer shell, wherein the inner shell is coaxially disposed in the outer shell;

the inner shell is divided into two portions, namely an upper cylinder and a lower cone;

the cylinder comprises an upper segment of imporous pipe (1411) and a lower segment of straight porous pipe (1404); and

the cone is a conical porous wall (1407);

the outer shell comprises an upper connection flange, a middle straight pressure-bearing wall (1403) and a lower conical pressure-bearing wall (1409);

a first annular space is formed between the cylindrical portion of the inner shell and the straight pressure-bearing wall (1403) and the connection flange;

a second annular space is formed between the conical porous wall (1407) and the conical pressure-bearing wall (1409);

a separation ring (1405) is disposed between the first annular space and the second annular space;

high-temperature evaporated water injection pipes (1402) are disposed on an upper portion of the straight pressure-bearing wall;

low-temperature evaporated water injection pipes (1406) are disposed on an upper portion of the conical pressure-bearing wall (1409); and

an outlet pipe (1408) is disposed at a bottom of the conical pressure-bearing wall (1409);

a nozzle pipe (1401) is coaxially disposed on the connection flange, and the nozzle pipe (1401) passes through a top center of the inner shell.

2. The reactor based on the supercritical water oxidation as claimed in claim 1, wherein water outlets of the high-temperature evaporated water injection pipes (1402) are directly faced to a middle-upper portion of the imporous pipe (1411);

and water outlets of the low-temperature evaporated water injection pipes (1406) are directly faced to the separation ring (1405).

3. The reactor based on the supercritical water oxidation as claimed in claim 1, wherein the nozzle pipe (1401) comprises an outer pipe (03) and an inner pipe (01);

and a length that the outer pipe (03) is stretched into a reaction zone is 20-200 mm longer than the inner pipe (01).

4. The reactor based on the supercritical water oxidation as claimed in claim 3, wherein the nozzle pipe (1401) further comprises a middle pipe (02);

and the outer pipe (03) and the middle pipe (02) are stretched into the reaction zone in a flush manner.

5. The reactor based on the supercritical water oxidation as claimed in claim 3, wherein the imporous pipe (1411) extends downward along an outlet of the nozzle pipe (1401) and the extending distance is 2-6 times of an inner diameter of the outer pipe (03).

6. The reactor based on the supercritical water oxidation as claimed in claim 1, wherein an elastic support frame (1410) is disposed at a lower end of the straight porous pipe (1404);

and the elastic support frame (1410) is supported by the separation ring (1405).