Damping thermoplastic elastomers

• US 10,457,805 B2
• Filed: 02/10/2016
• Issued: 10/29/2019
• Est. Priority Date: 02/11/2015
• Status: Active Grant

• Current Assignee: Avient Corp.
• Original Assignee: Polyone Corporation (Avient Corp.)
• Inventors: Gu, Jiren
• Primary Examiner(s): Higgins, Gerard
• Application Number:
  US15/040,151
• Publication Number:
  US 20160230000A1
• Time in Patent Office: 1,357 Days
• CPC Class Codes: B32B 2250/02 2 layers
• CPC Class Codes: B32B 2250/24 All layers being polymeric
• CPC Class Codes: B32B 2270/00 Resin or rubber layer containing a blend of at least two different polymers
• CPC Class Codes: B32B 2274/00 Thermoplastic elastomer material thermoplastic elastomer fibres B32B2262/0215, thermoplastic elastomer particles B32B2264/0221, thermoplastic elastomer foam B32B2266/0292
• CPC Class Codes: B32B 2307/10 having particular acoustical properties
• CPC Class Codes: B32B 2307/102 Insulating
• CPC Class Codes: B32B 2307/308 Heat stability dimensional stability B32B2307/734
• CPC Class Codes: B32B 2307/51 Elastic
• CPC Class Codes: B32B 2307/558 Impact strength, toughness
• CPC Class Codes: B32B 2307/56 Damping, energy absorption
• CPC Class Codes: B32B 2307/71 Resistive to light or to UV
• CPC Class Codes: B32B 2419/00 Buildings or parts thereof walls, panels B32B2607/00
• CPC Class Codes: B32B 2457/00 Electrical equipment
• CPC Class Codes: B32B 25/042 of natural rubber or synthetic rubber
• CPC Class Codes: B32B 25/08 of synthetic resin
• CPC Class Codes: B32B 2509/00 Household appliances
• CPC Class Codes: B32B 2535/00 Medical equipment, e.g. bandage, prostheses, catheter medical patches B32B2556/00
• CPC Class Codes: B32B 2571/00 Protective equipment
• CPC Class Codes: B32B 2605/00 Vehicles
• CPC Class Codes: B32B 27/302 comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
• CPC Class Codes: B32B 27/308 : comprising acrylic (co)polymers
• CPC Class Codes: B32B 27/32 : comprising polyolefins comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30
• CPC Class Codes: B32B 27/34 : comprising polyamides
• CPC Class Codes: B32B 27/36 : comprising polyesters
• CPC Class Codes: B32B 27/365 : comprising polycarbonates
• CPC Class Codes: B32B 27/40 : comprising polyurethanes
• CPC Class Codes: C08L 2205/02 : containing two or more polymers of the same C08L -group
• CPC Class Codes: C08L 2205/035 : containing four or more polymers in a blend
• CPC Class Codes: C08L 2207/04 : Thermoplastic elastomer
• CPC Class Codes: C08L 53/025 : modified
• CPC Class Codes: C08L 91/00 : Compositions of oils, fats or waxes; Compositions of derivatives thereof

Abstract

A thermoplastic elastomer compound includes styrenic block copolymer and high softening point tackifier. The styrenic block copolymer has a Copolymer Tan Delta Peak Temperature and the thermoplastic elastomer compound has a Compound Tan Delta Peak Temperature. The Compound Tan Delta Peak Temperature is greater than the Copolymer Tan Delta Peak Temperature. The thermoplastic elastomer compound exhibits useful damping properties at or above room temperature while also advantageously possessing improved stability for processing and/or applications at high temperatures and upon exposure to weathering.

Claims

1. A multi-component plastic article comprising at least two components formed from different thermoplastic materials, wherein at least one of the different thermoplastic materials is a thermoplastic elastomer compound and at least one other of the at least two components is a thermoplastic substrate onto which the thermoplastic elastomer compound is overmolded;

wherein the thermoplastic elastomer compound consists of;

(a) 100 parts by weight of styrenic block copolymer having a Copolymer Tan Delta Peak Temperature, wherein the styrenic block copolymer is hydrogenated;

(b) from about 50 to about 200 parts by weight of tackifier having a softening point of at least about 120°

C. according to ASTM 6493;

(c) from 0 to about 200 parts by weight of plasticizer;

(d) from 0 to about 150 parts by weight of filler;

(e) from 0 to about 300 parts by weight of secondary polymer selected from polyethylene, polypropylene, butyl rubber, ethylene propylene diene monomer (EPDM) rubber, thermoplastic vulcanizate, and combinations thereof;

(f) from 0 to 300 parts by weight of bonding agent; and

(g) from 0 to about 100 parts by weight of at least one additive selected from anti-fogging agents;

anti-static agents;

blowing and foaming agents;

dispersants;

flame retardants and smoke suppressants;

initiators;

pigments, colorants and dyes;

silanes, titanates and zirconates;

stabilizers and antioxidants;

stearates;

ultraviolet light absorbers;

waxes; and

combinations thereof; and

wherein the thermoplastic elastomer compound has a Compound Tan Delta Peak Temperature, and the Compound Tan Delta Peak Temperature is greater than the Copolymer Tan Delta Peak Temperature; and

wherein either;

(x) the thermoplastic substrate comprises polyamide, and wherein the bonding agent is present in the thermoplastic elastomer compound and the bonding agent is selected from the group consisting of maleic anhydride functionalized polyolefin, maleic anhydride functionalized styrenic block copolymer, and combinations thereof;

or

(y) the thermoplastic substrate comprises polyolefin, and wherein the bonding agent is present in the thermoplastic elastomer compound and the bonding agent is selected from polyethylene, polypropylene, and combinations thereof;

or

(z) the thermoplastic substrate comprises a thermoplastic material selected from the group consisting of thermoplastic polyurethane, polycarbonate, polycarbonate/acrylonitrile butadiene styrene, and polybutylene terephthalate/polycarbonate, and wherein the bonding agent is present in the thermoplastic elastomer compound and the bonding agent is selected from thermoplastic polyurethane, copolyester elastomer, and blends of thermoplastic polyurethane and copolyester elastomer.

2. The multi-component plastic article of claim 1, wherein the filler is selected from calcium carbonate, talc, and combinations thereof.

3. The multi-component plastic article of claim 1, wherein the compound is essentially free of styrene-(ethylene-ethylene/propylene)-styrene block copolymer and low vinyl styrene-(ethylene/butylene)-styrene block copolymer.

4. The multi-component plastic article of claim 1, wherein the styrenic block copolymer is selected from at least one of hydrogenated styrene-isoprene-styrene block copolymer with hydrogenated vinylic isoprene midblock and high vinyl styrene-(ethyl ene/butyl ene)-styrene block copolymer.

5. The multi-component plastic article of claim 1, wherein the Copolymer Tan Delta Peak Temperature is greater than −

40°

C. but less than −

10°

C.

6. The multi-component plastic article of claim 1, wherein the Compound Tan Delta Peak Temperature is at least −

10°

C.

7. The multi-component plastic article of claim 1, wherein the tackifier has a weight average molecular weight ranging from about 400 to about 3,500.

8. The multi-component plastic article of claim 1, wherein the tackifier comprises a saturated cyclo-aliphatic amorphous hydrocarbon resin.