Densified biomass products containing pretreated biomass fibers

• US 10,457,810 B2
• Filed: 03/15/2013
• Issued: 10/29/2019
• Est. Priority Date: 08/24/2009
• Status: Active Grant

• Current Assignee: The Board of Trustees of Michigan State University (Michigan State University)
• Original Assignee: The Board of Trustees of Michigan State University (Michigan State University)
• Inventors: Dale, Bruce E., Ritchie, Bryan, Marshall, Derek
• Primary Examiner(s): Mcavoy, Ellen M
• Assistant Examiner(s): Po, Ming Cheung
• Application Number:
  US13/835,382
• Publication Number:
  US 20130247456A1
• Time in Patent Office: 2,419 Days
• CPC Class Codes: C08L 97/005 Lignin
• CPC Class Codes: C08L 97/02 Lignocellulosic material, e.g. wood, straw or bagasse manufacture of articles made from lignocellulosic material by dry processes B27N
• CPC Class Codes: C09D 197/005 Lignin
• CPC Class Codes: C10L 5/363 Pellets or granulates
• CPC Class Codes: C10L 5/445 Agricultural waste, e.g. corn crops, grass clippings, nut shells or oil pressing residues
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel
• CPC Class Codes: Y02E 50/30 Fuel from waste, e.g. synthetic alcohol or diesel

Abstract

A product is provided comprising at least one densified biomass particulate having a substantially smooth, non-flakey outer surface and containing no added binder, wherein said densified biomass particulate is comprised of a plurality of pretreated lignin-coated plant biomass fibers which contain a trace amount of base from pretreatment of said fibers. Methods for using and making the product are also described.

Claims

1. A product consisting essentially of:

at least one densified biomass particulate having a substantially smooth, non-flakey outer surface and containing no added binder, wherein said densified biomass particulate is comprised of a plurality of pretreated lignin-coated plant biomass fibers, wherein said particulate contains only inherent binders present in said plant biomass fibers, and a trace amount of ammonia from a liquid ammonia fiber expansion (AFEX) pretreatment, a gaseous AFEX pretreatment or an extractive AFEX pretreatment of said plant biomass fibers.

2. The product of claim 1 wherein the trace amount of ammonia comprises about 1% to about 2% of ammonia.

3. The product of claim 1 wherein water and/or steam is added prior to and/or during the pretreatment.

4. The product of claim 1 wherein the inherent binders include lignin or lignin and hemicellulose, further wherein said biomass fibers comprise reduced lignin or reduced lignin and hemicellulose levels in their interior and increased lignin levels or increased lignin and hemicellulose levels on their surfaces as compared with the lignin levels or the lignin and hemicellulose levels of said fibers prior to the pretreatment, wherein said surface lignin or surface lignin and hemicellulose provide a degree of tackiness thereon.

5. The product of claim 4 wherein the fiber interiors contain microscopic pores and a portion of the lignin or a portion of the lignin and hemicellulose is present within the microscopic pores.

6. The product of claim 1 wherein at least some of said pretreated lignin-coated plant biomass fibers are also coated with hemicellulose.

7. The product of claim 1 wherein said densified biomass particulate has an increased resistance to deformation, an increased hardness, an increased resistance to degradation, an improved shelf life, or a combination thereof, as compared with a densified biomass particulate containing added binder.

8. The product of claim 7 wherein said densified biomass particulate is at least 21% harder with at least 20% less variability in hardness as compared to the densified biomass particulate containing added binder.

9. The product of claim 8 wherein said densified biomass particulate has a substantially cubic shape, a substantially rectangular shape or a substantially cylindrical shape.

10. The product of claim 1 wherein said biomass fibers are corn stover fibers, switchgrass fibers, prairie cord grass fibers, or combinations thereof.

11. The product of claim 1 comprising a plurality of densified biomass particulates of a given mass having a higher bulk density than baled, loose or compressed plant biomass of the same given mass.

12. The product of claim 1 comprising a plurality of densified biomass particulates of a given number, wherein said densified biomass particulates have an increased flowability, a higher bulk density, or a combination thereof, as compared with a plurality of densified plant biomass particulates of the same given number containing added binder.

13. The product of claim 1 comprising a plurality of densified biomass particulates of a given mass having a bulk density up to 10 times greater than a bulk density of loose plant biomass of the same given mass.

14. The product of claim 1 comprising a plurality of densified biomass particulates of a given mass having a bulk density up to 5 times greater than baled plant biomass having the same given mass.

15. The product of claim 1 comprising a plurality of densified biomass particulates of a given mass having a bulk density about 2 to about 5 times greater than loose plant biomass of the same given mass which has been compressed to occupy a volume up to 50% less than an original volume.

16. The product of claim 1 wherein said densified biomass particulate has an increased gross caloric value as compared with a densified biomass particulate containing untreated plant biomass fibers.

17. The product of claim 1 wherein a given mass of a plurality of densified biomass particulates has a reduced amount of fines as compared with a plurality of densified biomass particulates of the same given mass containing untreated plant biomass fibers.

18. The product of claim 1 wherein said densified biomass particulate is subject to fermentation.

19. The product of claim 18 wherein said densified biomass particulate is configured to be fermented to produce a sugar-containing stream, wherein fermentation rates are improved as compared to fermentation rates achieved using non-densified plant biomass.

20. The product of claim 1 further comprising a container to store a plurality of said densified biomass particulates.

32. The product of claim 1 wherein the plant biomass is a monocot or dicot.

21. A solid material consisting essentially of:

at least one densified biomass particulate having a substantially smooth, non-flakey outer surface, wherein said densified biomass particulate is comprised of a plurality of pretreated lignin-coated plant biomass fibers, wherein said particulate contains only inherent binders present in said plant biomass fibers, and a trace amount of ammonia from a liquid ammonia fiber expansion (AFEX) pretreatment, a gaseous AFEX pretreatment or an extractive AFEX pretreatment of said plant biomass fibers, wherein said solid material is a component of a solid construction material.

22. The solid material of claim 21 wherein said densified biomass particulate has a substantially cubic shape, a substantially rectangular shape or a substantially cylindrical shape.

23. The solid material of claim 22 wherein said densified biomass particulate is at least 21% harder with at least 20% less variability in hardness as compared to a densified biomass particulate containing binder.

30. The solid material of claim 21 wherein the inherent binders include lignin or lignin and hemicellulose.

24. A product consisting essentially of:

a plurality of densified biomass particulates, each having a substantially smooth, non-flakey outer surface and containing a plurality of ammonia fiber expansion (AFEX) pretreated plant biomass fibers and a trace amount of ammonia, wherein said particulates contain only inherent binders present in said plant biomass fibers, including lignin, and, wherein said plant biomass fibers have an interior and an outer surface, wherein a portion of the lignin is visible on the outer surface.

25. The solid material of claim 24 wherein the AFEX pretreatment comprises a liquid ammonia fiber expansion (AFEX) pretreatment, a gaseous AFEX pretreatment or an extractive AFEX pretreatment.

26. The product of claim 25 wherein said densified biomass particulates have a bulk density from about 200 kg/m³ to about 800 kg/m³.

27. The product of claim 25 wherein said densified biomass particulates have a bulk density of at least 500 kg/m³.

28. The product of claim 25 wherein said densified biomass particulates have a bulk density from about 547.2 kg/m³ to about 765 kg/m³.

29. The product of claim 25 wherein said biomass fibers comprise corn stover fibers, switchgrass fibers, prairie cord grass fibers, or combinations thereof.

31. The product of claim 25 wherein the inherent binders further include hemicellulose.