Method for controlling scale formation

• US 10,457,849 B2
• Filed: 01/16/2014
• Issued: 10/29/2019
• Est. Priority Date: 01/16/2014
• Status: Active Grant

• Current Assignee: Statoil Petroleum As (Asa Equinor)
• Original Assignee: Statoil Petroleum As (Asa Equinor)
• Inventors: Ghorbani, Nasser, Tjomsland, Tore, Wilhelms, Arnd
• Primary Examiner(s): DiTrani Leff, Angela M
• Assistant Examiner(s): Skaist, Avi T
• Application Number:
  US15/112,029
• Publication Number:
  US 20160333250A1
• Time in Patent Office: 2,112 Days
• CPC Class Codes: C09K 2208/10 Nanoparticle-containing well treatment fluids
• CPC Class Codes: C09K 8/528 inorganic depositions, e.g. sulfates or carbonates
• CPC Class Codes: C23F 14/02 by chemical means
• CPC Class Codes: E21B 33/12 Packers; Plugs used for cementing E21B33/134, E21B33/16
• CPC Class Codes: E21B 34/06 in wells
• CPC Class Codes: E21B 37/06 using chemical means for preventing or limiting , e.g. eliminating, the deposition of paraffins or like substances
• CPC Class Codes: E21B 43/35 specially adapted for separating solids down-hole drilling fluid separation systems E21B21/002; separating solids from drilling fluids E21B21/065

Abstract

The present invention provides, a method of controlling scale formation in a hydrocarbon producing system, comprising; (i) injecting nanoparticles into said system to function as nuclei for scale growth; (if) allowing scale growth to occur on said nanoparticles to produce nanoparticles comprising scale; and. (in) optionally recovering said nanoparticles comprising scale.

Claims

1. A method of controlling scale formation in a hydrocarbon producing system, comprising:

(i) injecting nanoparticles via a production well into said system to function as nuclei for scale growth, wherein said nanoparticles are nanoparticles comprising carbon functionalized with a polar group;

(ii) growing scale on said nanoparticles by attracting scaling ions to the polar group on the nanoparticle surface to produce nanoparticles comprising scale;

(iii) recovering production fluids comprising nanoparticles comprising scale;

(iv) washing said nanoparticles comprising scale with a scale dissolver to remove said scale; and

(v) reinjecting the descaled nanoparticles via said production well into said hydrocarbon producing system.

2. A method as claimed in claim 1, wherein said method prevents or reduces scale formation on hydrocarbon producing equipment present in said hydrocarbon producing system.

3. A method as claimed in claim 1, wherein said nanoparticles are nanotubes.

4. A method as claimed in claim 1, wherein said nanoparticles have an average diameter of 1 to 100 nm.

5. A method as claimed in claim 1, wherein the specific surface area of said nanoparticles is 100 to 5000 m²/g.

6. A method as claimed in claim 1, wherein said nanoparticles are injected continuously into said system.

7. A method as claimed in claim 1, wherein scale growth on said nanoparticles reduces the concentration of scale forming ions in a production fluid.

8. A method as claimed in claim 1, wherein the nanoparticles injected into the system reduce the concentration of scale forming ions in the production fluid to close to, or below, the saturation limit.

9. A method as claimed in claim 1, wherein said nanoparticles comprising scale have an average diameter of 10 to 1000 nm.

10. A method as claimed in claim 1, wherein said nanoparticles are applied as a dispersion in a liquid carrier.

11. A method as claimed in claim 10, wherein the concentration of nanoparticles in said liquid carrier is 0.5 to 50 wt%.

12. A method as claimed in claim 1 wherein production fluid is recovered via tubing in said production well.

13. A method as claimed in claim 1, wherein said nanoparticles comprising scale are separated from said mixture.

14. A system for producing hydrocarbon comprising:

(i) a hydrocarbon producing formation comprising a production well;

(ii) a chemical deployment system for injecting nanoparticles into said production well;

(iii) tubing for transporting production fluid and nanoparticles comprising scale out of said production well;

(iv) a filter for and/or chemical that causes aggregation for separating nanoparticles comprising scale from production fluids having an inlet connected to said tubing and having a first outlet for nanoparticles comprising scale and a second outlet for production fluid;

(v) a treatment tank for removing scale from nanoparticles comprising scale having an inlet connected to said first outlet of said means for separating nanoparticles and an outlet for descaled nanoparticles; and

(vi) a holding tank for descaled nanoparticles having an inlet connected to said outlet of said treatment tank and an outlet connected to said chemical deployment system for injecting nanoparticles into said production well.

15. A system as claimed in claim 14, wherein said filter for and/or chemical that causes aggregation is a filter.