Fuel additive composition and related methods and compositions

• US 10,457,880 B2
• Filed: 11/04/2016
• Issued: 10/29/2019
• Est. Priority Date: 11/04/2015
• Status: Active Grant

• Current Assignee: Purify Fuels, Inc.
• Original Assignee: Purify Founders, LLC
• Inventors: Remondini, Stephen J., Carroll, John, Allen, Jr., Harold H.
• Primary Examiner(s): McAvoy, Ellen M
• Application Number:
  US15/343,698
• Publication Number:
  US 20170121618A1
• Time in Patent Office: 1,089 Days
• Field of Search: 208 19, 585 14
• CPC Class Codes: C10L 1/04 essentially based on blends of hydrocarbons
• CPC Class Codes: C10L 1/1233 oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
• CPC Class Codes: C10L 1/1616 fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
• CPC Class Codes: C10L 1/231 nitro compounds; nitrates; nitrites C10L1/221 takes precedence
• CPC Class Codes: C10L 10/02 for reducing smoke development
• CPC Class Codes: C10L 10/04 for minimising corrosion or incrustation
• CPC Class Codes: C10L 2200/0423 Gasoline
• CPC Class Codes: C10L 2200/043 Kerosene, jet fuel
• CPC Class Codes: C10L 2200/0438 Middle or heavy distillates, heating oil, gasoil, marine fuels, residua
• CPC Class Codes: C10L 2200/0446 Diesel
• CPC Class Codes: C10L 2230/04 Catalyst added to fuel stream to improve a reaction
• CPC Class Codes: C10L 2270/026 for diesel engines, e.g. automobiles, stationary, marine
• CPC Class Codes: C10L 2270/04 for turbines, planes, power generation
• CPC Class Codes: C10L 5/04 Raw material of mineral origin to be used; Pretreatment thereof pretreatment of fuels of non-mineral origin C10L5/40

Abstract

The disclosure relates to fuel additive compositions including heavy paraffinic distillates and lighter petroleum distillates, in particular with the heavy paraffinic distillates including a mixture of hydrotreated and/or saturated components and solvent-dewaxed and/or branched components. The disclosure further relates to fuel compositions including the fuel additive composition and a liquid or solid combustible fuel. Related methods include methods of making the fuel compositions and methods of burning the fuel compositions. The resulting fuel compositions have several improved combustion properties such as improved combustion efficiency, improved combustion energy/calorie content, reduced sulfur generation, and reduced ash generation.

Claims

1. A fuel additive composition comprising:

(a) hydrotreated heavy paraffinic distillates present in amount ranging from 20 wt. % to 50 wt. % based on the fuel additive composition;

(b) solvent-dewaxed heavy paraffinic distillates present in amount ranging from 25 wt. % to 50 wt. % based on the fuel additive composition; and

(c) petroleum distillates comprising hydrocarbons having from 5 to 16 carbon atoms and present in an amount ranging from 20 wt. % to 50 wt. % based on the fuel additive composition.

2. The fuel additive composition of claim 1, wherein:

(i) the hydrotreated heavy paraffinic distillates are present in amount ranging from 28 wt. % to 34 wt. %;

(ii) the solvent-dewaxed heavy paraffinic distillates are present in amount ranging from 34 wt. % to 40 wt. %; and

(iii) the petroleum distillates are present in amount ranging from 29 wt. % to 35 wt. %.

15. The fuel additive composition of claim 1, wherein the hydrotreated heavy paraffinic distillates or the saturated heavy paraffinic distillates have a viscosity as measured at 40°

C. ranging from 15 cSt to 60 cSt.

16. The fuel additive composition of claim 15, wherein the hydrotreated heavy paraffinic distillates or the saturated heavy paraffinic distillates comprises a blend of (i) low-viscosity hydrotreated or saturated heavy paraffinic distillates having a viscosity as measured at 40°

C. ranging from 15 cSt to 30 cSt and (ii) high-viscosity hydrotreated or saturated heavy paraffinic distillates having a viscosity as measured at 40°

C. ranging from 30 cSt to 60 cSt.

17. The fuel additive composition of claim 1, wherein the hydrotreated heavy paraffinic distillates or the saturated heavy paraffinic distillates have a viscosity as measured at 100°

C. ranging from 3 cSt to 10 cSt.

18. The fuel additive composition of claim 1, wherein the hydrotreated heavy paraffinic distillates or the saturated heavy paraffinic distillates have a density ranging from 0.845 kg/L to 0.870 kg/L.

19. The fuel additive composition of claim 1, wherein the solvent-dewaxed heavy paraffinic distillates or the branched heavy paraffinic distillates have a viscosity as measured at 40°

C. ranging from 200 cSt to 600 cSt.

20. The fuel additive composition of claim 1, wherein the solvent-dewaxed heavy paraffinic distillates or the branched heavy paraffinic distillates have a viscosity as measured at 100°

C. ranging from 15 cSt to 50 cSt.

21. The fuel additive composition of claim 1, wherein the petroleum distillates comprise hydrocarbons having from 7 to 12 carbon atoms.

22. The fuel additive composition of claim 1, wherein the petroleum distillates are selected from the group consisting of mineral spirits, mineral turpentine, petroleum spirits, naphtha, Stoddard solvent, kerosene, and combinations thereof.

23. The fuel additive composition of claim 1, wherein:

(i) a weight ratio of the hydrotreated or saturated heavy paraffinic distillates relative to the petroleum distillates ranges from 0.90 to 1.05; and

(ii) a weight ratio of the solvent-dewaxed or branched heavy paraffinic distillates relative to the petroleum distillates ranges from 1.00 to 1.30.

24. The fuel additive composition of claim 1, further comprising one or more additives selected from the group consisting of combustion catalysts, antioxidants, antimicrobial agents, anti-static agents, and combinations thereof.

25. The fuel additive composition of claim 1, wherein the fuel additive composition is substantially free from alcohols.

26. The fuel additive composition of claim 1, wherein the fuel additive composition is substantially free from components other than the hydrotreated heavy paraffinic distillates or the saturated heavy paraffinic distillates, the solvent-dewaxed heavy paraffinic distillates or the branched heavy paraffinic distillates, and the petroleum distillates.

27. A fuel composition comprising:

(a) the fuel additive composition of claim 1, and

(b) a combustible fuel;

wherein a weight ratio of the combustible fuel to the fuel additive composition ranges from 2 to 1000.

28. The fuel composition of claim 27, wherein the liquid fuel comprises one or more of fuel oil #1, fuel oil #2, fuel oil #3, fuel oil #4, fuel oil #5, fuel oil #6, kerosene, jet fuel, gasoline, diesel fuel, biodiesel fuel, liquefied natural gas, and mixtures thereof.

31. A method for burning a fuel composition, the method comprising:

burning a fuel composition according to claim 27.

32. The method of claim 31, comprising burning the fuel composition in a vehicle engine.

33. The method of claim 31, comprising burning the fuel composition in a generator.

34. The method of claim 31, comprising burning the fuel composition in a ship engine.

35. A method for making a fuel composition, the method comprising:

mixing a fuel additive composition of claim 1 with a combustible fuel to form the fuel composition;

wherein a weight ratio of the combustible fuel to the fuel additive composition ranges from 2 to 1000.

3. A fuel additive composition comprising:

(a) saturated heavy paraffinic distillates comprising saturated hydrocarbons having from 20 to 50 carbon atoms or a sub-range thereof and present in amount ranging from 20 wt. % to 50 wt. % based on the fuel additive composition;

(b) branched heavy paraffinic distillates comprising branched hydrocarbons having from 20 to 50 carbon atoms or a sub-range thereof and present in amount ranging from 25 wt. % to 50 wt. % based on the fuel additive composition; and

(c) petroleum distillates comprising hydrocarbons having from 5 to 16 carbon atoms and present in an amount ranging from 20 wt. % to 50 wt. % based on the fuel additive composition.

4. The fuel additive composition of claim 3, wherein:

(i) the saturated heavy paraffinic distillates are present in amount ranging from 28 wt. % to 34 wt. %;

(ii) the branched heavy paraffinic distillates are present in amount ranging from 34 wt. % to 40 wt. %; and

(iii) the petroleum distillates are present in amount ranging from 29 wt. % to 35 wt. %.

5. A fuel additive composition comprising:

(a) hydrotreated heavy paraffinic distillates;

(b) solvent-dewaxed heavy paraffinic distillates;

(c) petroleum distillates comprising hydrocarbons having from 5 to 16 carbon atoms;

(d) a combustion catalyst; and

(e) a cetane improver;

wherein the fuel additive composition contains less than 5 wt. % alcohol based on the fuel additive composition.

7. The fuel additive composition of claim 5, wherein:

(i) a weight ratio of the hydrotreated or saturated heavy paraffinic distillates relative to the petroleum distillates ranges from 0.90 to 1.05; and

(ii) a weight ratio of the solvent-dewaxed or branched heavy paraffinic distillates relative to the petroleum distillates ranges from 1.00 to 1.30.

8. The fuel additive composition of claim 5, wherein components (a), (b), and (c) are collectively present in a combined amount ranging from 5 wt. % to 40 wt. % based on the fuel additive composition.

9. The fuel additive composition of claim 5, wherein the combustion catalyst is present in an amount ranging from 0.2 wt. % to 5 wt. % based on the fuel additive composition.

10. The fuel additive composition of claim 5, wherein the cetane improver is present in an amount ranging from 30 wt. % to 90 wt. % based on the fuel additive composition.

11. The fuel additive composition of claim 5, wherein a weight ratio of component (e) relative to components (a), (b), and (c) combined ranges from 1 to 8.

12. The fuel additive composition of claim 5, wherein the combustion catalyst comprises cerium oxide.

13. The fuel additive composition of claim 5, wherein the combustion catalyst is in the form of nanoparticles having an average size ranging from 2 nm to 50 nm.

14. The fuel additive composition of claim 5, wherein the cetane improver comprises 2-ethylhexyl nitrate.

29. A fuel composition comprising:

the fuel additive composition of claim 5; and

a combustible fuel;

wherein;

(i) a weight ratio of the combustible fuel to the fuel additive composition ranges from 2 to 1000;

(ii) components (a), (b), and (c) of the fuel additive composition are collectively present in a combined amount ranging from 10 ppm to 5000 ppm by weight based on the fuel composition;

(iii) the combustion catalyst is present in an amount ranging from 2 ppm to 100 ppm by weight based on the fuel composition; and

(iv) the cetane improver is present in an amount ranging from 100 ppm to 10000 ppm by weight based on the fuel composition.

30. The fuel composition of claim 29, wherein the cetane number of the fuel composition is at least 50.

6. A fuel additive composition comprising:

(a) saturated heavy paraffinic distillates comprising saturated hydrocarbons having from 20 to 50 carbon atoms or a sub-range thereof;

(b) branched heavy paraffinic distillates comprising branched hydrocarbons having from 20 to 50 carbon atoms or a sub-range thereof;

(c) petroleum distillates comprising hydrocarbons having from 5 to 16 carbon atoms;

(d) a combustion catalyst; and

(e) a cetane improver;

wherein the fuel additive composition contains less than 5 wt. % alcohol based on the fuel additive composition.