Electrode-supported tubular solid-oxide electrochemical cell

• US 10,458,027 B2
• Filed: 10/08/2015
• Issued: 10/29/2019
• Est. Priority Date: 10/08/2015
• Status: Active Grant

• Current Assignee: Transformational Energy Limited
• Original Assignee: Low Emissions Resources Corporation
• Inventors: Alvarez, Fernando, Sammes, Lauren Beverly
• Primary Examiner(s): Mendez, Zulmariam
• Application Number:
  US14/878,544
• Publication Number:
  US 20170101719A1
• Time in Patent Office: 1,482 Days
• Field of Search: 204206, 205552
• CPC Class Codes: C25B 11/02 characterised by shape or form
• CPC Class Codes: C25B 11/031 Porous electrodes
• CPC Class Codes: C25B 13/02 characterised by shape or form
• CPC Class Codes: C25B 13/04 characterised by the material
• CPC Class Codes: C25B 9/19 with diaphragms
• CPC Class Codes: H01M 2300/0074 Ion conductive at high temperature
• CPC Class Codes: H01M 4/8864 Extrusion
• CPC Class Codes: H01M 4/8885 Sintering or firing
• CPC Class Codes: H01M 4/9025 Oxides specially used in fuel cell operating at high temperature, e.g. SOFC
• CPC Class Codes: H01M 8/1213 characterised by the electrode/electrolyte combination or the supporting material
• CPC Class Codes: H01M 8/124 characterised by the process of manufacturing or by the material of the electrolyte
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

Electrode-supported tubular solid-oxide electrochemical cells suitable for use in electrochemical chemical synthesis and processes for manufacturing such are provided.

Claims

1. A tubular solid-oxide electrochemical cell comprising:

a porous cathode configured in a tubular shape, the porous cathode comprising a first mixed ionically/electronically conductive composite material comprising a solid-oxide electrolyte substance having ionic conductivity and a first electrochemically active substance having electronic conductivity;

an electrolyte disposed as a thin-layer on at least part of a surface of the porous cathode, the electrolyte comprising the solid-oxide electrolyte substance; and

a porous anode disposed on at least part of a surface of the electrolyte, the porous anode comprising a second mixed ionically/electronically conductive composite material comprising the solid-oxide electrolyte substance and a second electrochemically active substance having electronic conductivity;

wherein the porous cathode and the porous anode are connected to a power source, such that the tubular solid-oxide electrochemical cell is adapted to perform catalytic electrochemical synthesis of ammonia.

2. The tubular solid-oxide electrochemical cell of claim 1, wherein the solid-oxide electrolyte substance comprises a proton conducting material.

3. The tubular solid-oxide electrochemical cell of claim 1, wherein the solid-oxide electrolyte substance comprises an oxygen ion conducting material.

4. The tubular solid-oxide electrochemical cell of claim 1, wherein the solid-oxide electrolyte substance comprises a material selected from the group consisting of a perovskite, a fluorite, a pyrochlore and a brownmillerite.

5. The tubular solid-oxide electrochemical cell of claim 1, wherein the solid-oxide electrolyte substance comprises a perovskite material having a general formula ABO₃,

wherein A is selected from the group consisting of monovalent, divalent and trivalent metal cations and combinations thereof;

and B is selected from the group consisting of pentavalent, tetravalent and trivalent metal cations and combinations thereof.

6. The tubular solid-oxide electrochemical cell of claim 1, wherein the solid-oxide electrolyte substance comprises a fluorite material having a general formula MO₂,

wherein M is selected from the group consisting of divalent and trivalent metal cations and combinations thereof.

7. The tubular solid-oxide electrochemical cell of claim 1, wherein the porous cathode comprises at least about 70% by weight of the solid-oxide electrolyte substance.

8. The tubular solid-oxide electrochemical cell of claim 1, wherein the first electrochemically active substance is selected from the group consisting of Sc, Ti, Zn, Sr, Y, Zr, Au, Bi, Pb, Co, Pt, Ru, Pd, Ni, Cu, Ag, W, Os, Rh, Ir, Cr, Fe, Mo, V, Re, Mn, Nb, Ta, and oxides, alloys and mixtures thereof.

9. The tubular solid-oxide electrochemical cell of claim 1, wherein the porous anode comprises at least about 70% by weight of the solid-oxide electrolyte substance.

10. The tubular solid-oxide electrochemical cell of claim 1, wherein the second electrochemically active substance is selected from the group consisting of Sc, Ti, Zn, Sr, Y, Zr, Au, Bi, Pb, Co, Pt, Ru, Pd, Ni, Cu, Ag, W, Os, Rh, Ir, Cr, Fe, Mo, V, Re, Mn, Nb, Ta, and oxides, alloys and mixtures thereof.

11. The tubular solid-oxide electrochemical cell of claim 1, wherein the first mixed ionically/electronically conductive composite material and the second mixed ionically/electronically conductive composite material are the same.

12. The tubular solid-oxide electrochemical cell of claim 1, wherein the porous cathode has an average thickness in a range of about 5 mm to about 50 mm.

13. The tubular solid-oxide electrochemical cell of claim 1, wherein the thin-layer of the electrolyte has an average thickness in a range of about 5 microns to about 100 microns.

14. The tubular solid-oxide electrochemical cell of claim 1, wherein the porous anode has an average thickness in a range of about 5 microns to about 100 microns.

15. The tubular solid-oxide electrochemical cell of claim 1, wherein the tubular shape has a cross-sectional shape selected from the group consisting of circular, semicircular, oval, square, rectangular, trapezoidal, triangular and star.

16. The tubular solid-oxide electrochemical cell of claim 1, wherein the first mixed ionically/electronically conductive composite material and the second mixed ionically/electronically conductive composite material each has a coefficient of thermal expansion within about 10% of that of the solid-oxide electrolyte substance.

17. The tubular solid-oxide electrochemical cell of claim 1, wherein a thickness of the porous cathode is in a range between about 5 mm to about 50 mm, a thickness of the electrolyte is in a range between about 5 microns to about 100 microns, and a thickness of the porous anode is in a range between about 5 microns to about 100 microns.

18. A tubular solid-oxide electrochemical cell comprising:

a first porous electrode configured in a tubular shape, the first porous electrode comprising a first mixed ionically/electronically conductive composite material comprising a solid-oxide electrolyte substance having ionic conductivity and a first electrochemically active metallic substance having electronic conductivity;

an electrolyte disposed as a thin-layer on at least part of a surface of the first porous electrode, the electrolyte comprising the solid-oxide electrolyte substance; and

a second porous electrode disposed on at least part of a surface of the electrolyte, the second porous electrode comprising a second mixed ionically/electronically conductive composite material comprising the solid-oxide electrolyte substance and a second electrochemically active metallic substance having electronic conductivity;

wherein the first porous electrode and the second porous electrode are connected to a power source, such that the tubular solid-oxide electrochemical cell is adapted to perform catalytic electrochemical synthesis of ammonia; and

wherein a thickness of the first porous electrode is in a range between about 5 mm to about 50 mm, a thickness of the electrolyte is in a range between about 5 microns to about 100 microns, and a thickness of the second porous electrode is in a range between about 5 microns to about 100 microns.