Integrated system for quantitative real-time monitoring of hydrogen-induced cracking in simulated sour environment

• US 10,458,960 B2
• Filed: 12/03/2018
• Issued: 10/29/2019
• Est. Priority Date: 01/06/2016
• Status: Active Grant

• Current Assignee: Saudi Arabian Oil Company (Government of Saudi Arabia)
• Original Assignee: Saudi Arabian Oil Company (Government of Saudi Arabia)
• Inventors: Traidia, Abderrazak, Sherik, Abdelmounam, Lewis, Arnold
• Primary Examiner(s): Woodward, Nathaniel T
• Application Number:
  US16/207,906
• Publication Number:
  US 20190113482A1
• Time in Patent Office: 330 Days
• Field of Search: 73 182
• CPC Class Codes: G01N 17/006 of metals
• CPC Class Codes: G01N 2291/0234 Metals, e.g. steel
• CPC Class Codes: G01N 2291/0258 Structural degradation, e.g. fatigue of composites, ageing of oils
• CPC Class Codes: G01N 2291/0289 Internal structure, e.g. defects, grain size, texture
• CPC Class Codes: G01N 2291/101 one transducer
• CPC Class Codes: G01N 29/04 Analysing solids using acoustic emission techniques G01N29/14
• CPC Class Codes: G01N 29/043 in the interior, e.g. by shear waves
• CPC Class Codes: G01N 29/225 Supports, positioning or alignment in moving situation
• CPC Class Codes: G01N 29/30 Arrangements for calibrating or comparing, e.g. with standard objects

Abstract

The present disclosure is directed to a method and system for monitoring hydrogen-induced cracking in at least one test specimen. The method includes the steps of: saturating a test solution with a gas comprising H₂S and delivering the saturated test solution into a test cell, wherein the test cell comprises at least one specimen port and at least one test specimen. The specimen port is configured to receive the test specimen. The method also includes the step of exposing the at least one test specimen to the saturated test solution, wherein only one surface of each specimen is exposed to the saturated test solution and the step of scanning the test specimen with a ultrasonic transducer at two or more time points, wherein the ultrasonic transducer is operatively connected to the specimen port and configured to rotate completely around the symmetry axis of the test specimen to complete each scan.

Claims

1. A system for monitoring hydrogen-induced cracking in a laboratory environment, comprising:

a source of sour gas;

a test solution tank comprising a test solution and into which the sour gas is introduced such that the test solution becomes saturated with the sour gas;

a test cell defining a semi-open fluid vessel, the fluid vessel being in fluid communication with the test solution tank such that the fluid vessel receives the saturated test solution;

a test cell holder configured to rotate the test cell;

at least one specimen port operatively connected to the fluid vessel and configured to hold a test specimen such that one surface of each test specimen is exposed to the saturated test solution; and

an ultrasonic transducer operatively connected to the at least one specimen port and configured to rotate to scan HIC defects of the test specimen.

2. The system of claim 1, wherein the test cell holder is configured to rotate the test cell about −

45 degrees relative to the direction of gravity and lock the test cell at that position for a test duration.

3. The system of claim 1, wherein the test cell holder is configured to rotate the test cell about +45 degrees relative to the direction of gravity and lock test cell at that position for a test duration.

4. The system of claim 1, wherein the ultrasonic transducer is configured to rotate with respect to the symmetry axis of the test specimen.

5. The system of claim 1, wherein each specimen port comprises a wedge on top of which the ultrasonic transducer is attached, and wherein the wedge is configured to rotate with respect to the symmetry axis of the test specimen resulting in the rotation of the ultrasonic transducer.

6. The system of claim 5, wherein the ultrasonic transducer covers half of the top surface of the wedge.

7. The system of claim 6, wherein the wedge is rotated manually.

8. The system of claim 6, wherein the wedge is operatively connected to a motor such that the motor automates the rotation of the wedge and the ultrasonic transducer.

9. The system of claim 1, wherein the system comprises at least two specimen ports.

10. The system of claim 9, wherein the system comprises at least one specimen port configured to connect to a eudiometer device for measuring the hydrogen permeation rate through the test specimen.

11. The system of claim 1, wherein the at least one test specimen is comprised of a metal that is susceptible to hydrogen-induced cracking.

12. The system claim 11, wherein each test specimen is comprised of steel.

13. The system of claim 1, wherein the system further comprises a fluid conduit for transferring the saturated test solution from the test solution tank to the fluid vessel of the test cell, the fluid conduit being positioned such that it terminates in front of the each specimen port within the fluid vessel of the test cell.

14. The system of claim 13, wherein the system further comprises one or more screens attached to the end of fluid conduit 110 that terminates within the fluid vessel of the test cell, the screens being configured to agitate the test solution exposed to the test specimen.

15. The system of claim 1, further comprising an encoder operatively connected to the ultrasonic transducer and fixed to the specimen clamp, wherein the encoder is configured to be linearly displaced as the wedge rotates, resulting in a full scan of the test specimen.

16. The system of claim 15, wherein the encoder is a wheel encoder.

17. The system of claim 16, wherein the encoder is an optical encoder.