Separator capable of selective ion migration, and secondary battery comprising same

• US 10,461,295 B2
• Filed: 05/09/2016
• Issued: 10/29/2019
• Est. Priority Date: 05/29/2015
• Status: Active Grant

• Current Assignee: Rekrix Co., Ltd.
• Original Assignee: Rekrix Co., Ltd.
• Inventors: Ryou, Byoung Hoon, Kong, Jae Kyung
• Primary Examiner(s): Crepeau, Jonathan
• Application Number:
  US15/573,553
• Publication Number:
  US 20180151861A1
• Time in Patent Office: 1,268 Days
• Field of Search: None
• CPC Class Codes: H01M 10/02 Details of electrodes H01M4/00; of non-active parts H01M50/00
• CPC Class Codes: H01M 10/05 Accumulators with non-aqueous electrolyte H01M10/39 takes precedence
• CPC Class Codes: H01M 10/24 Alkaline accumulators
• CPC Class Codes: H01M 12/06 with one metallic and one gaseous electrode
• CPC Class Codes: H01M 12/08 composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
• CPC Class Codes: H01M 50/403 Manufacturing processes of separators, membranes or diaphragms
• CPC Class Codes: H01M 50/414 Synthetic resins, e.g. thermoplastics or thermosetting resins
• CPC Class Codes: H01M 50/446 Composite material consisting of a mixture of organic and inorganic materials
• CPC Class Codes: H01M 50/451 comprising layers of only organic material and layers containing inorganic material
• CPC Class Codes: H01M 50/463 Separators, membranes or diaphragms characterised by their shape
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

A separator includes a support formed in a grid, and a porous ion migration inhibition layer with which the grid of the support is coated and which has a plurality of pores formed therein, wherein each of the plurality of pores of the porous ion migration inhibition layer is formed to have a size smaller than the size of an electromigration-promoting ion contained in an electrolyte, whereby the electromigration-promoting ion does not pass through the porous ion migration inhibition layer. In addition, potassium is prevented from migrating to the carbon layer, thereby preventing potassium hydroxide from being precipitated even when oxygen is moved to a positive electrode side during charging. Furthermore, when the separator is applied to a separator of an alkaline battery, potassium hydroxide may be prevented from being precipitated during charging, thereby achieving an effect that an alkaline primary battery can be used as a secondary battery.

Claims

1. A zinc-air battery, comprising:

a positive electrode comprising a carbon layer and a positive electrode current collector in a metal mesh form formed in the interior of the carbon layer;

a negative electrode;

a separator capable of selective ion migration, the separator interposed between the positive electrode and the negative electrode, the separator comprising;

a support formed in a grid; and

a porous ion migration inhibition layer with which the grid of the support is coated and which has a plurality of pores formed therein, wherein each of the plurality of pores of the porous ion migration inhibition layer is formed so as to have a size smaller than the size of an electromigration-promoting ion contained in an electrolyte, and thus the electromigration-promoting ion is prevented from passing through the porous ion migration inhibition layer; and

the electrolyte for impregnating the negative electrode, the separator, and a part of the positive electrode, the electrolyte comprising a slurry in which zinc (Zn), potassium hydroxide (KOH) and water (H₂O) are mixed; and

a gas-liquid interface formed by impregnating a part of the carbon layer with the electrolyte of which ions selectively passing through the separator due to the size of the pores,

wherein the zinc-air battery operates by a migration of electrons generated when zinc contained in the electrolyte reacts with oxygen in the air and is changed into zinc oxide.

2. The zinc-air battery according to claim 1, wherein the support is formed of polyvinyl alcohol (PVA), and the porous ion migration inhibition layer is formed of polyvinyl acetate (PVAc).

3. The zinc-air battery according to claim 2, wherein the porous ion migration inhibition layer is formed by an electrospinning process of electrically charging polyvinyl acetate (PVAc) and spinning the polyvinyl acetate (PVAc) onto the support.

4. The zinc-air battery according to claim 2, wherein the porous ion migration inhibition layer is formed by substituting a hydrogen of a methyl group connected to a backbone of polyvinyl acetate (PVAc) with at least one alkali metal or alkaline earth metal.

5. A zinc-air battery, comprising:

a positive electrode;

a negative electrode;

a separator interposed between the positive electrode and the negative electrode; and

an electrolyte including zinc for impregnating the negative electrode, the separator and a part of the positive electrode, the electrolyte comprising an electromigration-promoting ion,

wherein the separator is formed of a porous material having a plurality of pores formed therein, and each of the plurality of pores has a size smaller than the size of an electromigration-promoting ion contained in the electrolyte, and thus the electromigration-promoting ion does not pass through the plurality of pores such that the electromigration-promoting ion is prevented from migrating to the positive electrode side,

wherein the zinc-air battery operates by a migration of electrons generated when zinc contained in the electrolyte reacts with oxygen in the air and is changed into zinc oxide.

6. The zinc-air battery of claim 5, wherein the electrolyte comprises a slurry in which zinc (Zn), potassium hydroxide (KOH) and water (H₂O) are mixed, and said each of the plurality of pores of the porous ion migration inhibition layer has a size smaller than the size of a potassium ion.