Composite lithium borates and/or phosphates and polymer coatings for active material particles

• US 10,461,323 B2
• Filed: 01/23/2019
• Issued: 10/29/2019
• Est. Priority Date: 04/07/2016
• Status: Active Grant

• Current Assignee: StoreDot Ltd.
• Original Assignee: StoreDot Ltd.
• Inventors: Burshtain, Doron, Kedem, Nir, Sella, Eran, Aronov, Daniel
• Primary Examiner(s): Walls, Cynthia K
• Application Number:
  US16/254,644
• Publication Number:
  US 20190157669A1
• Time in Patent Office: 279 Days
• CPC Class Codes: H01M 10/0525 Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• CPC Class Codes: H01M 2004/021 Physical characteristics, e.g. porosity, surface area
• CPC Class Codes: H01M 4/134 Electrodes based on metals, Si or alloys
• CPC Class Codes: H01M 4/1395 of electrodes based on metals, Si or alloys
• CPC Class Codes: H01M 4/366 as layered products
• CPC Class Codes: H01M 4/386 Silicon or alloys based on silicon
• CPC Class Codes: H01M 4/387 Tin or alloys based on tin
• CPC Class Codes: H01M 4/624 Electric conductive fillers
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

Improved anodes and cells are provided, which enable fast charging rates with enhanced safety due to much reduced probability of metallization of lithium on the anode, preventing dendrite growth and related risks of fire or explosion. Anodes and/or electrolytes have buffering zones for partly reducing and gradually introducing lithium ions into the anode for lithiation, to prevent lithium ion accumulation at the anode electrolyte interface and consequent metallization and dendrite growth. Various anode active materials and combinations, modifications through nanoparticles and a range of coatings which implement the improved anodes are provided.

Claims

1. Anode active material particles comprising:

metalloid cores comprising at least one of Si, Ge and Sn, having diameter in a range of 20-500 nm, and

a composite coating on said metalloid cores, said composite coating comprising lithium borates and/or lithium phosphates and polymer molecules,

wherein the lithium borates and/or lithium phosphates alternate with polymer molecules within the composite coating, with the lithium borates and/or lithium phosphates interconnecting the polymer molecules, and

wherein the polymer molecules are anchored by the lithium borates and/or lithium phosphates to the metalloid cores.

2. The anode active material particles of claim 1, wherein the composite coating has a thickness in a range of 2-200 nm.

3. The anode active material particles of claim 1, wherein the polymer molecules comprise electron-donating groups that are at least partly negatively charged, comprising at least one of:

atoms having a lone pair of electrons, aromatic groups and/or conjugated systems.

4. The anode active material particles of claim 1, wherein the polymer molecules are pre-lithiated.

5. The anode active material particles of claim 1, wherein the composite coating comprises a plurality of layers of the polymer molecules, wherein the layers are anchored to each other and to the metalloid cores by the lithium borates and/or lithium phosphates.

6. The anode active material particles of claim 1, wherein the composite coating is configured to provide a buffering zone that receives lithium ions from an interface of the composite anode active material particles with an electrolyte, partially reduces the received lithium ions, and enables the partially reduced lithium ions to move into an inner zone of the composite anode active material particles for lithiation therein.

7. The anode material particles of claim 1, further comprising at least one polymer coating and/or lithiated coating.

8. An anode made of the anode active material particles of claim 1.

9. A lithium-ion cell comprising the anode of claim 8.