Adsorbent-incorporated polymer fibers in packed bed and fabric contactors, and methods and devices using same

• US 10,464,009 B2
• Filed: 06/16/2017
• Issued: 11/05/2019
• Est. Priority Date: 12/10/2014
• Status: Active Grant

• Current Assignee: Exxonmobil Upstream Research Company (Exxon Mobil Corporation)
• Original Assignee: Exxonmobil Upstream Research Company (Exxon Mobil Corporation)
• Inventors: Owens, Tracie L., Leta, Daniel P.
• Primary Examiner(s): Lawrence, Jr., Frank M
• Application Number:
  US15/625,633
• Publication Number:
  US 20170282114A1
• Time in Patent Office: 872 Days
• Field of Search: 95 96, 95117, 95139, 95148, 95137, 95129, 95136, 96121, 96126, 96134, 96135, 96146, 96153, 96154
• CPC Class Codes: B01D 2253/108 Zeolites
• CPC Class Codes: B01D 2253/25 Coated, impregnated or composite adsorbents
• CPC Class Codes: B01D 2257/302 Sulfur oxides
• CPC Class Codes: B01D 2257/304 Hydrogen sulfide
• CPC Class Codes: B01D 2257/40 Nitrogen compounds
• CPC Class Codes: B01D 2257/404 Nitrogen oxides other than dinitrogen oxide
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2257/80 Water
• CPC Class Codes: B01D 2258/0283 Flue gases
• CPC Class Codes: B01D 2258/05 Biogas
• CPC Class Codes: B01D 2258/06 Polluted air
• CPC Class Codes: B01D 53/02 by adsorption, e.g. preparative gas chromatography solid sorbent compositions B01J20/00, preparation of inorganic compounds or elements C01
• CPC Class Codes: B01D 53/0462 Temperature swing adsorption
• CPC Class Codes: B01D 53/047 Pressure swing adsorption
• CPC Class Codes: B01D 53/0473 Rapid pressure swing adsorption
• CPC Class Codes: B01J 20/18 Synthetic zeolitic molecular sieves
• CPC Class Codes: B01J 20/20 comprising free carbon; comprising carbon obtained by carbonising processes
• CPC Class Codes: B01J 20/26 Synthetic macromolecular compounds
• CPC Class Codes: B01J 20/262 obtained otherwise than by reactions only involving carbon to carbon unsaturated bonds, e.g. obtained by polycondensation macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds per se C08G
• CPC Class Codes: B01J 20/28023 Fibres or filaments fibres or filaments in the form of membranes B01J20/28038; B01J20/28007 takes precedence
• CPC Class Codes: B01J 20/28026 : Particles within, immobilised, dispersed, entrapped in or on a matrix, e.g. a resin
• CPC Class Codes: B01J 20/28028 : Particles immobilised within fibres or filaments
• CPC Class Codes: B01J 20/28033 : Membrane, sheet, cloth, pad, lamellar or mat
• CPC Class Codes: B01J 20/28038 : Membranes or mats made from fibers or filaments
• CPC Class Codes: Y02C 20/40 : of CO2

Abstract

The embodiments of the disclosure relate generally to adsorbent beds, adsorbent contactors, and methods of using same. The disclosure includes polymer filaments that include an adsorbent particle, such as a zeolite, metal oxide, metal organic framework. A plurality of fibers composed of the polymer filaments can be formed into an adsorbent bed for use in pressure swing and/or temperature swing adsorption processes. The plurality of fibers can be packed into a bed randomly, spirally wound, or woven into a fabric that can be formed into a contacting structure. The adsorbent particle can be contained within the polymer filament and can interact with a medium having a component for adsorption by being in fluid communication with the medium via tortuous pathways within the polymer.

Claims

1. An adsorbent bed, the bed comprising,

a plurality of fibers, and

tortuous channels between fibers of the plurality of fibers;

wherein each of the fibers comprises a polymer filament and adsorbent particles dispersed within the polymer filament;

the polymer filament is porous with a void fraction of at least about 10% volume and is selected from the group consisting of polysulfones, polydimehtylsiloxanes, polyetherimides, and polyether ketones;

wherein the void fraction is comprised of pores wherein

     1) the pores are produced using a gaseous porogen, a diffusible porogen, or an extractable porogen, or

     2) the pores are produced during spinning of the polymer filament by phase inversion, wherein a solvent is removed causing pores to be formed in the polymer filament; and

wherein the plurality of fibers are randomly packed, spirally wound, or woven into a fabric.

2. The bed of claim 1, wherein the bed is a rapid cycle adsorbent bed.

3. The bed of claim 1, wherein the polymer filament comprises tortuous pathways within a porous polymer.

4. The bed of claim 1, wherein the adsorbent particles within the polymer are in fluid communication with at least a portion of the tortuous channels of the adsorbent bed.

5. The bed of claim 1, wherein the adsorbent content of the filaments is at least 10 wt %.

6. The bed of claim 1, wherein the average filament diameter is less than 500 micrometers.

7. The bed of claim 1, wherein the average size of the adsorbent particle is less than 30% of the average diameter of the filament.

8. The bed of claim 1, wherein the adsorbent bed comprises a pressure swing adsorption bed.

9. The bed of claim 1, wherein the plurality of fibers forms a non-woven bed of randomly packed filaments.

10. The bed of claim 1, wherein the plurality of fibers forms a bed of spirally wound filaments.

11. The bed of claim 1, wherein the plurality of fibers form a woven fabric of filaments, the fabric having a warp and a weft, and the woven fabric forming the tortuous channels in the spacing between filaments.

12. The bed of claim 11, wherein the woven fabric is packaged to form a contacting structure.

13. The bed of claim 12, wherein the contacting structure includes spacers of between about 50 micrometers and 500 micrometers.

14. An adsorbent contactor, the contactor comprising

a chamber comprising:

a gas feed stream inlet and a gas feed stream outlet;

a plurality of fibers; and

tortuous channels between fibers of the plurality of fibers;

wherein each of the fibers comprises a polymer filament and adsorbent particles dispersed within the filament, the adsorbent particles being in fluid communication with at least a portion of the tortuous channels of the adsorbent bed, and the polymer filament is porous with a void fraction of at least about 10% volume and is selected from the group consisting of polysulfones, polydimehtylsiloxanes, polyetherimides, and polyether ketones;

wherein the void fraction is comprised of pores wherein

     1) the pores are produced using a gaseous porogen, a diffusible porogen, or an extractable porogen, or

     2) the pores are produced during spinning of the polymer filament by phase inversion, wherein a solvent is removed causing pores to be formed in the polymer filament; and

wherein the plurality of fibers are randomly packed, spirally wound, or woven into a fabric.

15. The contactor of claim 14, wherein the adsorbent contactor is a rapid cycle adsorbent contactor.

16. The contactor of claim 14, wherein the polymer filament comprises a porous polymer having tortuous pathways within the porous polymer.

17. The contactor of claim 14, wherein the adsorbent bed is a pressure swing adsorption bed.

18. The contactor of claim 14, wherein the adsorbent content of the filaments is at least 10 wt %.

19. The contactor of claim 14, wherein the average filament diameter is less than 500 micrometers.

20. The contactor of claim 14, wherein the plurality of fibers forms a bed of non-woven randomly packed or spirally wound filaments, optionally supported on structural supports within the chamber, and the tortuous channels form between the randomly packed filaments.

21. The contactor of claim 14, wherein the plurality of fibers form a woven fabric of filaments, the fabric having a warp and a weft, and the woven fabric forming the tortuous channels in the spacing between filaments.

22. The contactor of claim 21, wherein the woven fabric is packaged to form a contacting structure.

23. The contactor of claim 22, wherein the contacting fabric includes spacers of between about 50 micrometers and 500 micrometers.

24. A method of adsorbing a component of a medium within an adsorbent bed, the method comprising:

contacting a medium with a plurality of fibers and tortuous channels between the fibers, each of the fibers comprising a polymer filament and adsorbent particles dispersed within the filament, the adsorbent particles in fluid communication with at least a portion of the tortuous channels of the adsorbent bed, and the plurality of fibers are randomly packed, spirally wound, or woven into a fabric; and

selectively adsorbing a component of the medium with the plurality of fibers;

wherein the polymer filament is porous with a void fraction of at least about 10% volume and is selected from the group consisting of polysulfones, polydimehtylsiloxanes, polyetherimides, and polyether ketones;

wherein the void fraction is comprised of pores wherein

     1) the pores are produced using a gaseous porogen, a diffusible porogen, or an extractable porogen, or

     2) the pores are produced during spinning of the polymer filament by phase inversion, wherein a solvent is removed causing pores to be formed in the polymer filament.

25. The method of adsorbing a component of a medium of claim 24, further comprising desorbing the component of the medium.

26. The method of adsorbing a component of a medium of claim 25, further comprising repeating the contacting and adsorbing.

27. The method of adsorbing a component of a medium of claim 24, wherein the medium comprises flue gas, natural gas, fuel gas, bio gas, town gas, waste gas, water, coal gas, air, or a carbon dioxide containing medium.

28. The method of adsorbing a component of a medium of claim 24, wherein the component is selected from CO₂, SO_x, NO_x, H₂S, and water.

29. The method of adsorbing a component of a medium of claim 24, wherein the plurality of fibers forms a bed of randomly packed or spirally wound filaments optionally supported on structural support.

30. The method of adsorbing a component of a medium of claim 24, wherein the plurality of fibers forms a woven fabric of filaments, the fabric having a warp and a weft, and the woven fabric forming the tortuous channels in the spacing between filaments.

31. The method of adsorbing a component of a medium of claim 24, wherein the method is a pressure swing adsorption process.

32. The method of adsorbing a component of a medium of claim 24, wherein the method is a rapid cycle adsorption process.

33. The method of adsorbing a component of a medium of claim 24, wherein the method is a rapid cycle adsorption process with kinetic separation.