Refractory coating material containing low biopersistent fibers and method for making the same

• US 10,487,224 B2
• Filed: 05/23/2017
• Issued: 11/26/2019
• Est. Priority Date: 06/06/2016
• Status: Active Grant

• Current Assignee: Unifrax I LLC (ASP Unifrax Holdings, Inc.)
• Original Assignee: Unifrax I LLC (ASP Unifrax Holdings, Inc.)
• Inventors: Geise, Matthew R., De Souza, Mauricio Munhoz
• Primary Examiner(s): Yoon, Tae H
• Application Number:
  US15/602,574
• Publication Number:
  US 20170349769A1
• Time in Patent Office: 917 Days
• Field of Search: 523179
• CPC Class Codes: C08K 7/02 Fibres or whiskers
• CPC Class Codes: C09D 133/26 Homopolymers or copolymers of acrylamide or methacrylamide
• CPC Class Codes: C09D 5/00 Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced electrically insulating plastics, resins or waxes H01B3/30; Filling pastes
• CPC Class Codes: C09D 7/00 Features of coating compositions, not provided for in group C09D5/00 driers C09F9/00; Processes for incorporating ingredients in coating compositions
• CPC Class Codes: C09D 7/43 Thickening agents
• CPC Class Codes: C09D 7/61 inorganic
• CPC Class Codes: C09D 7/70 characterised by shape, e.g. fibres, flakes or microspheres
• CPC Class Codes: C23C 14/12 Organic material

Abstract

A refractory coating material that can be used to coat a wide variety of surfaces or substrates to provide thermal and mechanical protection. The refractory coating material can withstand exposure to use temperatures of about 1500° C. and greater, yet the fibers contained therein exhibit low biopersistence in physiological fluids such as simulated lung fluid. Also disclosed are methods for making and utilizing the refractory coating material.

Claims

1. A refractory coating material consisting of:

low biopersistent inorganic fibers;

an organic binder;

a colloidal inorganic oxide;

a silica-containing compound comprising silicon dioxide powder, quartz, rice hull ash, oat bran ash, wheat chaff ash, or a combination thereof; and

a gelling agent.

2. The refractory coating material of claim 1, wherein the low biopersistent inorganic fibers are present in an amount of about 5 to about 70 weight percent, the organic binder is present in an amount of about 0.1 to about 7.5 weight percent organic binder, the colloidal inorganic oxide is present in an amount of about 2 to about 50 weight percent, and the silica-containing compound is present in an amount of about 30 to about 85 weight percent.

3. The refractory coating material of claim 2, wherein the low biopersistent inorganic fibers are present in an amount of about 27 to about 42 weight percent, the organic binder is present in an amount of about 1.0 to about 3.5 weight percent, the colloidal inorganic oxide is present in an amount of about 7 to about 25 weight percent, and the silica-containing compound is present in an amount of about 40 to about 55 weight percent.

4. The refractory coating material of claim 1, wherein the low biopersistent inorganic fibers comprise magnesia-silicate fibers comprising the fiberization product of at least from about 60 to about 90 weight percent silica, and from greater than 0 to about 35 weight percent magnesia.

5. The refractory coating material of claim 1, wherein the low biopersistent inorganic fibers comprise calcia-magnesia-silicate fibers comprising the fiberization product of at least from about 45 to about 90 weight percent silica, from greater than 0 to about 45 weight percent calcia, and from greater than 0 to about 35 weight percent magnesia.

6. The refractory coating material of claim 1, wherein the colloidal inorganic oxide comprises colloidal silica, colloidal zirconia, colloidal titania, colloidal ceria, colloidal yttria and/or combinations thereof.

7. The refractory coating material of claim 1, wherein the colloidal inorganic oxide comprises colloidal silica.

9. The refractory coating material of claim 1, wherein the organic binder comprises natural resins, synthetic resins, starch and/or combinations thereof.

10. The refractory coating material of claim 9, wherein the organic binder comprises a polyacrylamide-containing polymer.

12. A method of utilizing the refractory coating material of claim 1, comprising coating a surface or substrate with the refractory coating material of claim 1.

16. The refractory coating material of claim 1, wherein the gelling agent comprises ammonium acetate, calcium chloride, magnesium chloride, magnesium oxide, acetic acid, hydrochloric acid, phosphoric acid, or a combination thereof.

17. The refractory coating material of claim 1, wherein the gelling agent comprises magnesium chloride.

8. A refractory coating material consisting of:

low biopersistent inorganic fibers;

an organic binder;

a colloidal inorganic oxide;

a silica-containing compound comprising silicon dioxide powder, quartz, rice hull ash, oat bran ash, wheat chaff ash, or a combination thereof;

a gelling agent; and

water.

11. A process for producing the refractory coating material of claim 8, comprising preparing an aqueous slurry by mixing the water with the composition consisting of the low biopersistent inorganic fibers, the organic binder, the colloidal inorganic oxide, the silica-containing compound, and the gelling agent.

13. The refractory coating material of claim 8, wherein the colloidal inorganic oxide comprises colloidal silica, colloidal zirconia, colloidal titania, colloidal ceria, colloidal yttria and/or combinations thereof.

14. The refractory coating material of claim 8, wherein the colloidal inorganic oxide comprises colloidal silica.

15. The refractory coating material of claim 8, wherein the low biopersistent inorganic fibers comprise calcia-magnesia-silicate fibers, magnesia-silicate fibers, calcia-aluminate fibers, potassia-calcia-aluminate fibers, potassia-alumina-silicate fibers, sodia-alumina-silicate fibers, or a combination thereof.

18. The refractory coating material of claim 8, wherein the gelling agent comprises ammonium acetate, calcium chloride, magnesium chloride, magnesium oxide, acetic acid, hydrochloric acid, phosphoric acid, or a combination thereof.

19. The refractory coating material of claim 8, wherein the gelling agent comprises magnesium chloride.

20. The refractory coating material of claim 8, wherein the organic binder comprises natural resins, synthetic resins, starch and/or combinations thereof.

21. The refractory coating material of claim 20, wherein the organic binder comprises a polyacrylamide-containing polymer.